New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes
We have obtained a series of low-dimensional hybrid perovskitoids (often referred to as perovskites) based on lead bromide. As organic cations, the derivatives of polyaromatic and conjugated molecules, such as anthracene, pyrene and (E)-stilbene, were chosen to form charge-transfer complexes with va...
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| Format: | Article |
| Language: | English |
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MDPI AG
2021-11-01
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| Series: | Crystals |
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| Online Access: | https://www.mdpi.com/2073-4352/11/11/1424 |
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| author | Igor A. Nikovskiy Kseniya L. Isakovskaya Yulia V. Nelyubina |
| author_facet | Igor A. Nikovskiy Kseniya L. Isakovskaya Yulia V. Nelyubina |
| author_sort | Igor A. Nikovskiy |
| collection | DOAJ |
| description | We have obtained a series of low-dimensional hybrid perovskitoids (often referred to as perovskites) based on lead bromide. As organic cations, the derivatives of polyaromatic and conjugated molecules, such as anthracene, pyrene and (E)-stilbene, were chosen to form charge-transfer complexes with various organic acceptors for use as highly tunable components of hybrid perovskite solar cells. X-ray diffraction analysis showed these crystalline materials to be new 1D- and pseudo-layered 0D-perovskitoids with lead bromide octahedra featuring different sharing modes, such as in unusual mini-rods of four face- and edge-shared octahedra. Thanks to the low dimensionality, they can be of use in another type of optoelectronic device, photodetectors. |
| first_indexed | 2024-03-10T05:34:06Z |
| format | Article |
| id | doaj.art-19b5321975264443a94fb0cac09e7a56 |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-03-10T05:34:06Z |
| publishDate | 2021-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-19b5321975264443a94fb0cac09e7a562023-11-22T22:59:22ZengMDPI AGCrystals2073-43522021-11-011111142410.3390/cryst11111424New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer ComplexesIgor A. Nikovskiy0Kseniya L. Isakovskaya1Yulia V. Nelyubina2A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova Str., 28, 119991 Moscow, RussiaA.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova Str., 28, 119991 Moscow, RussiaA.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova Str., 28, 119991 Moscow, RussiaWe have obtained a series of low-dimensional hybrid perovskitoids (often referred to as perovskites) based on lead bromide. As organic cations, the derivatives of polyaromatic and conjugated molecules, such as anthracene, pyrene and (E)-stilbene, were chosen to form charge-transfer complexes with various organic acceptors for use as highly tunable components of hybrid perovskite solar cells. X-ray diffraction analysis showed these crystalline materials to be new 1D- and pseudo-layered 0D-perovskitoids with lead bromide octahedra featuring different sharing modes, such as in unusual mini-rods of four face- and edge-shared octahedra. Thanks to the low dimensionality, they can be of use in another type of optoelectronic device, photodetectors.https://www.mdpi.com/2073-4352/11/11/1424lead bromidelow-dimensional perovskiteshybrid perovskitescharge-transfer complexesperovskitoidssolar cells |
| spellingShingle | Igor A. Nikovskiy Kseniya L. Isakovskaya Yulia V. Nelyubina New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes Crystals lead bromide low-dimensional perovskites hybrid perovskites charge-transfer complexes perovskitoids solar cells |
| title | New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes |
| title_full | New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes |
| title_fullStr | New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes |
| title_full_unstemmed | New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes |
| title_short | New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes |
| title_sort | new low dimensional hybrid perovskitoids based on lead bromide with organic cations from charge transfer complexes |
| topic | lead bromide low-dimensional perovskites hybrid perovskites charge-transfer complexes perovskitoids solar cells |
| url | https://www.mdpi.com/2073-4352/11/11/1424 |
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