Macrokinetics of the deterioration of cement-based grouting material for predicting its service life under acid rain attack

Abstract Cement-based grouting material is widely used to reinforce the unsafe rock and control seepage of rock-carved relics although it is considered inappropriate in protection of ancient sites. As this approach is irreversible, a longer service life is desirable for the grouting material and met...

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Main Authors: Wenjing Hu, Shiqiang Fang, Lina Xie, Xueqiang Chen, Bingjian Zhang
Format: Article
Language:English
Published: SpringerOpen 2023-11-01
Series:Heritage Science
Subjects:
Online Access:https://doi.org/10.1186/s40494-023-01087-z
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author Wenjing Hu
Shiqiang Fang
Lina Xie
Xueqiang Chen
Bingjian Zhang
author_facet Wenjing Hu
Shiqiang Fang
Lina Xie
Xueqiang Chen
Bingjian Zhang
author_sort Wenjing Hu
collection DOAJ
description Abstract Cement-based grouting material is widely used to reinforce the unsafe rock and control seepage of rock-carved relics although it is considered inappropriate in protection of ancient sites. As this approach is irreversible, a longer service life is desirable for the grouting material and methods to predict the service life are needed. Here we propose a universal formula based on the dissolved amount of calcium ion to predict the deterioration rate of cement-based grout caused by acid deposition in the laboratory. The experimental results showed that the dissolved amount of calcium ion had a linear relationship with lnT and the pH value, with better accuracy when the pH value was greater than 3.0. This work maybe could provide a facile and quantitative method to help us predict the service life of cement-based grouting material under acid rain attack outdoors.
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spelling doaj.art-19bc654620744c809fb25275e2134b2f2023-11-20T10:31:25ZengSpringerOpenHeritage Science2050-74452023-11-0111111110.1186/s40494-023-01087-zMacrokinetics of the deterioration of cement-based grouting material for predicting its service life under acid rain attackWenjing Hu0Shiqiang Fang1Lina Xie2Xueqiang Chen3Bingjian Zhang4Centre for the Protection of Cultural Property and New Economic Research Institute, Ningbo University of Finance & EconomicsCentre for the Protection of Cultural Property and New Economic Research Institute, Ningbo University of Finance & EconomicsCentre for the Protection of Cultural Property and New Economic Research Institute, Ningbo University of Finance & EconomicsCentre for the Protection of Cultural Property and New Economic Research Institute, Ningbo University of Finance & EconomicsDepartment of Cultural Heritage and Museology, Zhejiang UniversityAbstract Cement-based grouting material is widely used to reinforce the unsafe rock and control seepage of rock-carved relics although it is considered inappropriate in protection of ancient sites. As this approach is irreversible, a longer service life is desirable for the grouting material and methods to predict the service life are needed. Here we propose a universal formula based on the dissolved amount of calcium ion to predict the deterioration rate of cement-based grout caused by acid deposition in the laboratory. The experimental results showed that the dissolved amount of calcium ion had a linear relationship with lnT and the pH value, with better accuracy when the pH value was greater than 3.0. This work maybe could provide a facile and quantitative method to help us predict the service life of cement-based grouting material under acid rain attack outdoors.https://doi.org/10.1186/s40494-023-01087-zCementMacrokineticsReaction rate constantAcid rainCa2+ ion
spellingShingle Wenjing Hu
Shiqiang Fang
Lina Xie
Xueqiang Chen
Bingjian Zhang
Macrokinetics of the deterioration of cement-based grouting material for predicting its service life under acid rain attack
Heritage Science
Cement
Macrokinetics
Reaction rate constant
Acid rain
Ca2+ ion
title Macrokinetics of the deterioration of cement-based grouting material for predicting its service life under acid rain attack
title_full Macrokinetics of the deterioration of cement-based grouting material for predicting its service life under acid rain attack
title_fullStr Macrokinetics of the deterioration of cement-based grouting material for predicting its service life under acid rain attack
title_full_unstemmed Macrokinetics of the deterioration of cement-based grouting material for predicting its service life under acid rain attack
title_short Macrokinetics of the deterioration of cement-based grouting material for predicting its service life under acid rain attack
title_sort macrokinetics of the deterioration of cement based grouting material for predicting its service life under acid rain attack
topic Cement
Macrokinetics
Reaction rate constant
Acid rain
Ca2+ ion
url https://doi.org/10.1186/s40494-023-01087-z
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