Gasoil Hydro-desulfurization using Catalyst synthesized from Iraqi Kaolin Clay: Optimization with Response Surface Methodology (RSM)

This search aim to study the feasibility of hydro-desulfurization (HDS) of gas oil in fixed bed reactor by using economic support catalyst alumina meta kaolin (AMK) under various operating condition, i.e. Temp. (240−320 ◦C), Press. (3–12 bar), WHSV (2–6 h−1) at H2/HC ratio (50 vol./vol.). The suppor...

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Main Authors: Khlood AlKhafaji, Zaidoon Shakor, Bashir Al-Zaidi, Sattar Hussein
Format: Article
Language:English
Published: Unviversity of Technology- Iraq 2021-05-01
Series:Engineering and Technology Journal
Subjects:
Online Access:https://etj.uotechnology.edu.iq/article_169349_31124338e8dd01e3c15b98ebeec05401.pdf
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author Khlood AlKhafaji
Zaidoon Shakor
Bashir Al-Zaidi
Sattar Hussein
author_facet Khlood AlKhafaji
Zaidoon Shakor
Bashir Al-Zaidi
Sattar Hussein
author_sort Khlood AlKhafaji
collection DOAJ
description This search aim to study the feasibility of hydro-desulfurization (HDS) of gas oil in fixed bed reactor by using economic support catalyst alumina meta kaolin (AMK) under various operating condition, i.e. Temp. (240−320 ◦C), Press. (3–12 bar), WHSV (2–6 h−1) at H2/HC ratio (50 vol./vol.). The support catalyst was prepared from Iraq kaolin and characterization by using scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDAX) and Fourier transform infrared (FTIR) spectroscopy.  Experimental design was used to determine which parameter (e.g. temperature, pressure and WHSV) has a greater influence on the obtained HDS and the optimum condition of process. The result shows that optimum condition given (Temp. 300 C, Press. 12 bar and WHSV 2 h-1) and all parameter have significant implication in the process.
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spelling doaj.art-19dc04edf84044c887940c29d5c151b92024-02-01T07:17:44ZengUnviversity of Technology- IraqEngineering and Technology Journal1681-69002412-07582021-05-01395A83684510.30684/etj.v39i5A.1977169349Gasoil Hydro-desulfurization using Catalyst synthesized from Iraqi Kaolin Clay: Optimization with Response Surface Methodology (RSM)Khlood AlKhafaji0Zaidoon Shakor1Bashir Al-Zaidi2Sattar Hussein3Chemical Engineering Department, University of Technology - IraqChemical Engineering Department, University of Technology - IraqChemical Engineering Department, University of Technology - IraqMinistry of Oil, Petroleum Research and Development Center(PRDC) - IraqThis search aim to study the feasibility of hydro-desulfurization (HDS) of gas oil in fixed bed reactor by using economic support catalyst alumina meta kaolin (AMK) under various operating condition, i.e. Temp. (240−320 ◦C), Press. (3–12 bar), WHSV (2–6 h−1) at H2/HC ratio (50 vol./vol.). The support catalyst was prepared from Iraq kaolin and characterization by using scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDAX) and Fourier transform infrared (FTIR) spectroscopy.  Experimental design was used to determine which parameter (e.g. temperature, pressure and WHSV) has a greater influence on the obtained HDS and the optimum condition of process. The result shows that optimum condition given (Temp. 300 C, Press. 12 bar and WHSV 2 h-1) and all parameter have significant implication in the process.https://etj.uotechnology.edu.iq/article_169349_31124338e8dd01e3c15b98ebeec05401.pdfhydro-desulfurizationkaolin claysexperimental designgasoil
spellingShingle Khlood AlKhafaji
Zaidoon Shakor
Bashir Al-Zaidi
Sattar Hussein
Gasoil Hydro-desulfurization using Catalyst synthesized from Iraqi Kaolin Clay: Optimization with Response Surface Methodology (RSM)
Engineering and Technology Journal
hydro-desulfurization
kaolin clays
experimental design
gasoil
title Gasoil Hydro-desulfurization using Catalyst synthesized from Iraqi Kaolin Clay: Optimization with Response Surface Methodology (RSM)
title_full Gasoil Hydro-desulfurization using Catalyst synthesized from Iraqi Kaolin Clay: Optimization with Response Surface Methodology (RSM)
title_fullStr Gasoil Hydro-desulfurization using Catalyst synthesized from Iraqi Kaolin Clay: Optimization with Response Surface Methodology (RSM)
title_full_unstemmed Gasoil Hydro-desulfurization using Catalyst synthesized from Iraqi Kaolin Clay: Optimization with Response Surface Methodology (RSM)
title_short Gasoil Hydro-desulfurization using Catalyst synthesized from Iraqi Kaolin Clay: Optimization with Response Surface Methodology (RSM)
title_sort gasoil hydro desulfurization using catalyst synthesized from iraqi kaolin clay optimization with response surface methodology rsm
topic hydro-desulfurization
kaolin clays
experimental design
gasoil
url https://etj.uotechnology.edu.iq/article_169349_31124338e8dd01e3c15b98ebeec05401.pdf
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