Iron complexes of tetramine ligands catalyse allylic hydroxyamination via a nitroso–ene mechanism

Iron complexes of tetramine ligands catalyse allylic hydroxyamination via a nitroso–ene mechanism

Iron(II) complexes of the tetradentate amines tris(2-pyridylmethyl)amine (TPA) and N,N′-bis(2-pyridylmethyl)-N,N′-dimethylethane-1,2-diamine (BPMEN) are established catalysts of C–O bond formation, oxidising hydrocarbon substrates via hydroxylation, epoxidation and dihydroxylation pathways. Herein w...

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Bibliographic Details
Main Authors: David Porter, Belinda M.-L. Poon, Peter J. Rutledge
Format: Article
Language:English
Published: Beilstein-Institut 2015-12-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
CH activation
hydroxyamination
iron catalysis
nitroso-ene
Online Access:https://doi.org/10.3762/bjoc.11.275

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