Development and validation of a simple thin-layer chromatographic method for the analysis of p-chlorophenol in treated wastewater
A thin-layer chromatographic method with densitometric detection was established for quantification of p-chlorophenol in waste water. Degradation efficiency of p-chlorophenol was monitored after each treatment of the wastewater samples. Degradation of p-chlorophenol was performed with advanced o...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
2012-01-01
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| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2012/0352-51391200087N.pdf |
| _version_ | 1818117230671429632 |
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| author | Tešić Živoslav Roglić Goran Manojlović Dragan Dabić Dragana Milojković-Opsenica Dušanka Dojčinović Biljana Natić Maja |
| author_facet | Tešić Živoslav Roglić Goran Manojlović Dragan Dabić Dragana Milojković-Opsenica Dušanka Dojčinović Biljana Natić Maja |
| author_sort | Tešić Živoslav |
| collection | DOAJ |
| description | A thin-layer chromatographic method with densitometric detection was established for quantification of p-chlorophenol in waste water. Degradation efficiency of p-chlorophenol was monitored after each treatment of the wastewater samples. Degradation of p-chlorophenol was performed with advanced oxidation processes (AOPs), using UV, H2O2/UV, O3/H2O2/UV, O3 and O3/UV. Developed TLC procedure has been found to be simple, rapid and precise. The method was characterized by high sensitivity (limit of detection was 11 ng per band and limit of quantification 35 ng per band), linear range (from 75 to 500 ng per band, r = 0.9965), and high precision, accuracy (mean percentage recovery 98.6%), and specificity. Additionally, the efficiency of degradation was monitored using HPLC giving comparable results with RP TLC measurements. [Acknowledgement. This work was performed within the framework of the research project No. 172017 supported by the Ministry of Education and Science of Serbia.] |
| first_indexed | 2024-12-11T04:35:07Z |
| format | Article |
| id | doaj.art-1a473e22c96e4dbb817f561d96724ebe |
| institution | Directory Open Access Journal |
| issn | 0352-5139 |
| language | English |
| last_indexed | 2024-12-11T04:35:07Z |
| publishDate | 2012-01-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-1a473e22c96e4dbb817f561d96724ebe2022-12-22T01:20:45ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51392012-01-0177111649165910.2298/JSC120509087NDevelopment and validation of a simple thin-layer chromatographic method for the analysis of p-chlorophenol in treated wastewaterTešić ŽivoslavRoglić GoranManojlović DraganDabić DraganaMilojković-Opsenica DušankaDojčinović BiljanaNatić MajaA thin-layer chromatographic method with densitometric detection was established for quantification of p-chlorophenol in waste water. Degradation efficiency of p-chlorophenol was monitored after each treatment of the wastewater samples. Degradation of p-chlorophenol was performed with advanced oxidation processes (AOPs), using UV, H2O2/UV, O3/H2O2/UV, O3 and O3/UV. Developed TLC procedure has been found to be simple, rapid and precise. The method was characterized by high sensitivity (limit of detection was 11 ng per band and limit of quantification 35 ng per band), linear range (from 75 to 500 ng per band, r = 0.9965), and high precision, accuracy (mean percentage recovery 98.6%), and specificity. Additionally, the efficiency of degradation was monitored using HPLC giving comparable results with RP TLC measurements. [Acknowledgement. This work was performed within the framework of the research project No. 172017 supported by the Ministry of Education and Science of Serbia.]http://www.doiserbia.nb.rs/img/doi/0352-5139/2012/0352-51391200087N.pdfp-chlorophenolTLC-scannerHPLCAOPswastewater treatment |
| spellingShingle | Tešić Živoslav Roglić Goran Manojlović Dragan Dabić Dragana Milojković-Opsenica Dušanka Dojčinović Biljana Natić Maja Development and validation of a simple thin-layer chromatographic method for the analysis of p-chlorophenol in treated wastewater Journal of the Serbian Chemical Society p-chlorophenol TLC-scanner HPLC AOPs wastewater treatment |
| title | Development and validation of a simple thin-layer chromatographic method for the analysis of p-chlorophenol in treated wastewater |
| title_full | Development and validation of a simple thin-layer chromatographic method for the analysis of p-chlorophenol in treated wastewater |
| title_fullStr | Development and validation of a simple thin-layer chromatographic method for the analysis of p-chlorophenol in treated wastewater |
| title_full_unstemmed | Development and validation of a simple thin-layer chromatographic method for the analysis of p-chlorophenol in treated wastewater |
| title_short | Development and validation of a simple thin-layer chromatographic method for the analysis of p-chlorophenol in treated wastewater |
| title_sort | development and validation of a simple thin layer chromatographic method for the analysis of p chlorophenol in treated wastewater |
| topic | p-chlorophenol TLC-scanner HPLC AOPs wastewater treatment |
| url | http://www.doiserbia.nb.rs/img/doi/0352-5139/2012/0352-51391200087N.pdf |
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