Design and Preparation a New Composite Hydrophilic/Hydrophobic Membrane for Desalination by Pervaporation

Herein, experimental and theoretical approaches were used to design a new composite membrane for desalination by pervaporation. The theoretical approaches demonstrate the possibility to reach high mass transfer coefficients quite close to those obtained with conventional porous membranes if two cond...

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Main Authors: Tarik Eljaddi, Eric Favre, Denis Roizard
Format: Article
Language:English
Published: MDPI AG 2023-06-01
Series:Membranes
Subjects:
Online Access:https://www.mdpi.com/2077-0375/13/6/599
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author Tarik Eljaddi
Eric Favre
Denis Roizard
author_facet Tarik Eljaddi
Eric Favre
Denis Roizard
author_sort Tarik Eljaddi
collection DOAJ
description Herein, experimental and theoretical approaches were used to design a new composite membrane for desalination by pervaporation. The theoretical approaches demonstrate the possibility to reach high mass transfer coefficients quite close to those obtained with conventional porous membranes if two conditions are verified: (i) a dense layer with a low thickness and (ii) a support with a high-water permeability. For this purpose, several membranes with a cellulose triacetate (CTA) polymer were prepared and compared with a hydrophobic membrane prepared in a previous study. The composite membranes were tested for several feed conditions, i.e., pure water, brine and saline water containing a surfactant. The results show that, whatever the tested feed, no wetting occurred during several hours of desalination tests. In addition, a steady flux was obtained together with a very high salt rejection (close to 100%) for the CTA membranes. Lastly, the CTA composite membrane was tested with real seawater without any pretreatment. It was shown that the salt rejection was still very high (close to 99.5%) and that no wetting could be detected for several hours. This investigation opens a new direction to prepare specific and sustainable membranes for desalination by pervaporation.
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spelling doaj.art-1a59edacd1054507afc227063365d84a2023-11-18T11:33:52ZengMDPI AGMembranes2077-03752023-06-0113659910.3390/membranes13060599Design and Preparation a New Composite Hydrophilic/Hydrophobic Membrane for Desalination by PervaporationTarik Eljaddi0Eric Favre1Denis Roizard2LRGP—Laboratoire Réactions et Génie des Procédés, UMR 7274, 54001 Nancy, FranceLRGP—Laboratoire Réactions et Génie des Procédés, UMR 7274, 54001 Nancy, FranceLRGP—Laboratoire Réactions et Génie des Procédés, UMR 7274, 54001 Nancy, FranceHerein, experimental and theoretical approaches were used to design a new composite membrane for desalination by pervaporation. The theoretical approaches demonstrate the possibility to reach high mass transfer coefficients quite close to those obtained with conventional porous membranes if two conditions are verified: (i) a dense layer with a low thickness and (ii) a support with a high-water permeability. For this purpose, several membranes with a cellulose triacetate (CTA) polymer were prepared and compared with a hydrophobic membrane prepared in a previous study. The composite membranes were tested for several feed conditions, i.e., pure water, brine and saline water containing a surfactant. The results show that, whatever the tested feed, no wetting occurred during several hours of desalination tests. In addition, a steady flux was obtained together with a very high salt rejection (close to 100%) for the CTA membranes. Lastly, the CTA composite membrane was tested with real seawater without any pretreatment. It was shown that the salt rejection was still very high (close to 99.5%) and that no wetting could be detected for several hours. This investigation opens a new direction to prepare specific and sustainable membranes for desalination by pervaporation.https://www.mdpi.com/2077-0375/13/6/599desalinationCTA composite membranesthermo-pervaporationmass transfer predictionseawater
spellingShingle Tarik Eljaddi
Eric Favre
Denis Roizard
Design and Preparation a New Composite Hydrophilic/Hydrophobic Membrane for Desalination by Pervaporation
Membranes
desalination
CTA composite membranes
thermo-pervaporation
mass transfer prediction
seawater
title Design and Preparation a New Composite Hydrophilic/Hydrophobic Membrane for Desalination by Pervaporation
title_full Design and Preparation a New Composite Hydrophilic/Hydrophobic Membrane for Desalination by Pervaporation
title_fullStr Design and Preparation a New Composite Hydrophilic/Hydrophobic Membrane for Desalination by Pervaporation
title_full_unstemmed Design and Preparation a New Composite Hydrophilic/Hydrophobic Membrane for Desalination by Pervaporation
title_short Design and Preparation a New Composite Hydrophilic/Hydrophobic Membrane for Desalination by Pervaporation
title_sort design and preparation a new composite hydrophilic hydrophobic membrane for desalination by pervaporation
topic desalination
CTA composite membranes
thermo-pervaporation
mass transfer prediction
seawater
url https://www.mdpi.com/2077-0375/13/6/599
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AT denisroizard designandpreparationanewcompositehydrophilichydrophobicmembranefordesalinationbypervaporation