The Effect of Sulphate Anions on the Ultrafine Titania Nucleation
Abstract The phenomenological model of sulphate anions effect on the nanodispersed titania synthesis during hydrolysis of titanium tetrachloride was studied. It was proposed that both chelating and bridging bidentate complexes formation between sulphate anions and octahedrally coordinated [Ti(OH)h(O...
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| Format: | Article |
| Language: | English |
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SpringerOpen
2017-05-01
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| Series: | Nanoscale Research Letters |
| Subjects: | |
| Online Access: | http://link.springer.com/article/10.1186/s11671-017-2144-3 |
| _version_ | 1797710818173779968 |
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| author | Volodymyr O. Kotsyubynsky Ivan F. Myronyuk Volodymyr L. Chelyadyn Andriy B. Hrubiak Volodymyr V. Moklyak Sofia V. Fedorchenko |
| author_facet | Volodymyr O. Kotsyubynsky Ivan F. Myronyuk Volodymyr L. Chelyadyn Andriy B. Hrubiak Volodymyr V. Moklyak Sofia V. Fedorchenko |
| author_sort | Volodymyr O. Kotsyubynsky |
| collection | DOAJ |
| description | Abstract The phenomenological model of sulphate anions effect on the nanodispersed titania synthesis during hydrolysis of titanium tetrachloride was studied. It was proposed that both chelating and bridging bidentate complexes formation between sulphate anions and octahedrally coordinated [Ti(OH)h(OH2)6−h](4−h)+ mononers is the determinative factor for anatase phase nucleation. |
| first_indexed | 2024-03-12T06:57:47Z |
| format | Article |
| id | doaj.art-1a612b71025f4d28997ed0115a1a4e6c |
| institution | Directory Open Access Journal |
| issn | 1931-7573 1556-276X |
| language | English |
| last_indexed | 2024-03-12T06:57:47Z |
| publishDate | 2017-05-01 |
| publisher | SpringerOpen |
| record_format | Article |
| series | Nanoscale Research Letters |
| spelling | doaj.art-1a612b71025f4d28997ed0115a1a4e6c2023-09-02T23:55:14ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2017-05-011211510.1186/s11671-017-2144-3The Effect of Sulphate Anions on the Ultrafine Titania NucleationVolodymyr O. Kotsyubynsky0Ivan F. Myronyuk1Volodymyr L. Chelyadyn2Andriy B. Hrubiak3Volodymyr V. Moklyak4Sofia V. Fedorchenko5Vasyl Stefanyk Precarpathian National UniversityVasyl Stefanyk Precarpathian National UniversityInstitute of Materials Science I.M. FrantsevichInstitute of Metal Physics, National Academy of ScienceInstitute of Metal Physics, National Academy of ScienceVasyl Stefanyk Precarpathian National UniversityAbstract The phenomenological model of sulphate anions effect on the nanodispersed titania synthesis during hydrolysis of titanium tetrachloride was studied. It was proposed that both chelating and bridging bidentate complexes formation between sulphate anions and octahedrally coordinated [Ti(OH)h(OH2)6−h](4−h)+ mononers is the determinative factor for anatase phase nucleation.http://link.springer.com/article/10.1186/s11671-017-2144-3HydrolysisPolycondensationNucleationAnataseSulphate anions |
| spellingShingle | Volodymyr O. Kotsyubynsky Ivan F. Myronyuk Volodymyr L. Chelyadyn Andriy B. Hrubiak Volodymyr V. Moklyak Sofia V. Fedorchenko The Effect of Sulphate Anions on the Ultrafine Titania Nucleation Nanoscale Research Letters Hydrolysis Polycondensation Nucleation Anatase Sulphate anions |
| title | The Effect of Sulphate Anions on the Ultrafine Titania Nucleation |
| title_full | The Effect of Sulphate Anions on the Ultrafine Titania Nucleation |
| title_fullStr | The Effect of Sulphate Anions on the Ultrafine Titania Nucleation |
| title_full_unstemmed | The Effect of Sulphate Anions on the Ultrafine Titania Nucleation |
| title_short | The Effect of Sulphate Anions on the Ultrafine Titania Nucleation |
| title_sort | effect of sulphate anions on the ultrafine titania nucleation |
| topic | Hydrolysis Polycondensation Nucleation Anatase Sulphate anions |
| url | http://link.springer.com/article/10.1186/s11671-017-2144-3 |
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