ENHANCEMENT IN UV SENSING PROPERTIES OF Zno:Ag NANOSTRUCTURED FILMS BY SURFACE FUNCTIONALIZATION WITH NOBLE METALIC AND BIMETALLIC NANOPARTICLES

In this study, Ag-doped ZnO (ZnO:Ag) nanostructured films were functionalized with silver nanoparticles (Ag NPs), silver-platinum bimetallic nanoparticles (AgPt NPs) and silver-gold bimetallic NPs (AgAu NPs) using a gas phase PVD process based on a Haberland type gas aggregatio...

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Main Authors: Vasile Postica, Alexander Vahl, Nicolae Magariu, Maik-Ivo Terasa, Mathias Hoppe, Bruno Viana, Patrick Aschehoug, Thierry Pauporté, Ion Tiginyanu, Oleksandr Polonskyi, Victor Sontea, Lee Chow, Lorenz Kienle, Rainer Adelung, Franz Faupel, Oleg Lupan
Format: Article
Language:English
Published: Technical University of Moldova 2018-09-01
Series:Journal of Engineering Science (Chişinău)
Subjects:
Online Access:https://jes.utm.md/wp-content/uploads/sites/20/2019/02/JES-2018-3_41-51.pdf
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author Vasile Postica
Alexander Vahl
Nicolae Magariu
Maik-Ivo Terasa
Mathias Hoppe
Bruno Viana
Patrick Aschehoug
Thierry Pauporté
Ion Tiginyanu
Oleksandr Polonskyi
Victor Sontea
Lee Chow
Lorenz Kienle
Rainer Adelung
Franz Faupel
Oleg Lupan
author_facet Vasile Postica
Alexander Vahl
Nicolae Magariu
Maik-Ivo Terasa
Mathias Hoppe
Bruno Viana
Patrick Aschehoug
Thierry Pauporté
Ion Tiginyanu
Oleksandr Polonskyi
Victor Sontea
Lee Chow
Lorenz Kienle
Rainer Adelung
Franz Faupel
Oleg Lupan
author_sort Vasile Postica
collection DOAJ
description In this study, Ag-doped ZnO (ZnO:Ag) nanostructured films were functionalized with silver nanoparticles (Ag NPs), silver-platinum bimetallic nanoparticles (AgPt NPs) and silver-gold bimetallic NPs (AgAu NPs) using a gas phase PVD process based on a Haberland type gas aggregation cluster source and unipolar DC planar magnetron sputtering. Ultraviolet (UV) sensing investigations showed arespectable time constants reduction for rising and decaying photocurrents, as well as an increase for the UV response. Compared to a pristine nanostructured film the surface functionalization with Ag, AgPt and AgAu increased the UV response by factors of 2.7, 3.5 and 4, respectively. The increased performances of the here presented ZnO:Ag nanostructured films functionalized with monometallic and bimetallic NPs based photodetectors are explained by the increased lifetime of photogenerated electron –hole pairs, as well as the formation of nanoscale Schottky barriers at the interface of Au/ZnO:Ag and Pt/ZnO:Ag.
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spelling doaj.art-1a691e40568d45339522116616ff19a82022-12-22T01:36:10ZengTechnical University of MoldovaJournal of Engineering Science (Chişinău)2587-34742587-34822018-09-01XXV3415110.5281/zenodo.2557280ENHANCEMENT IN UV SENSING PROPERTIES OF Zno:Ag NANOSTRUCTURED FILMS BY SURFACE FUNCTIONALIZATION WITH NOBLE METALIC AND BIMETALLIC NANOPARTICLESVasile Postica0Alexander Vahl1Nicolae Magariu2Maik-Ivo Terasa3Mathias Hoppe4Bruno Viana5Patrick Aschehoug6Thierry Pauporté7Ion Tiginyanu8Oleksandr Polonskyi9Victor Sontea10Lee Chow11Lorenz Kienle12Rainer Adelung13Franz Faupel14Oleg Lupan15Technical University of MoldovaInstitute for Materials Science, Kiel University, GermanyTechnical University of MoldovaInstitute for Materials Science, Kiel University, GermanyInstitute for Materials Science, Kiel University, Germany Institut de Recherche de Chimie Paris, France Institut de Recherche de Chimie Paris, France Institut de Recherche de Chimie Paris, FranceInstituteof Electronic Engineering and Nanotechnology, Chisinau, Republic of MoldovaInstitute for Materials Science, Kiel University, GermanyTechnical University of MoldovaUniversity of Central Florida, Orlando, FL 32816USAInstitute for Materials Science, Kiel University, GermanyInstitute for Materials Science, Kiel University, GermanyInstitute for Materials Science, Kiel University, GermanyTechnical University of MoldovaIn this study, Ag-doped ZnO (ZnO:Ag) nanostructured films were functionalized with silver nanoparticles (Ag NPs), silver-platinum bimetallic nanoparticles (AgPt NPs) and silver-gold bimetallic NPs (AgAu NPs) using a gas phase PVD process based on a Haberland type gas aggregation cluster source and unipolar DC planar magnetron sputtering. Ultraviolet (UV) sensing investigations showed arespectable time constants reduction for rising and decaying photocurrents, as well as an increase for the UV response. Compared to a pristine nanostructured film the surface functionalization with Ag, AgPt and AgAu increased the UV response by factors of 2.7, 3.5 and 4, respectively. The increased performances of the here presented ZnO:Ag nanostructured films functionalized with monometallic and bimetallic NPs based photodetectors are explained by the increased lifetime of photogenerated electron –hole pairs, as well as the formation of nanoscale Schottky barriers at the interface of Au/ZnO:Ag and Pt/ZnO:Ag.https://jes.utm.md/wp-content/uploads/sites/20/2019/02/JES-2018-3_41-51.pdfUV photodetectorzinc oxidesilver nanoparticlesnanostructured films
spellingShingle Vasile Postica
Alexander Vahl
Nicolae Magariu
Maik-Ivo Terasa
Mathias Hoppe
Bruno Viana
Patrick Aschehoug
Thierry Pauporté
Ion Tiginyanu
Oleksandr Polonskyi
Victor Sontea
Lee Chow
Lorenz Kienle
Rainer Adelung
Franz Faupel
Oleg Lupan
ENHANCEMENT IN UV SENSING PROPERTIES OF Zno:Ag NANOSTRUCTURED FILMS BY SURFACE FUNCTIONALIZATION WITH NOBLE METALIC AND BIMETALLIC NANOPARTICLES
Journal of Engineering Science (Chişinău)
UV photodetector
zinc oxide
silver nanoparticles
nanostructured films
title ENHANCEMENT IN UV SENSING PROPERTIES OF Zno:Ag NANOSTRUCTURED FILMS BY SURFACE FUNCTIONALIZATION WITH NOBLE METALIC AND BIMETALLIC NANOPARTICLES
title_full ENHANCEMENT IN UV SENSING PROPERTIES OF Zno:Ag NANOSTRUCTURED FILMS BY SURFACE FUNCTIONALIZATION WITH NOBLE METALIC AND BIMETALLIC NANOPARTICLES
title_fullStr ENHANCEMENT IN UV SENSING PROPERTIES OF Zno:Ag NANOSTRUCTURED FILMS BY SURFACE FUNCTIONALIZATION WITH NOBLE METALIC AND BIMETALLIC NANOPARTICLES
title_full_unstemmed ENHANCEMENT IN UV SENSING PROPERTIES OF Zno:Ag NANOSTRUCTURED FILMS BY SURFACE FUNCTIONALIZATION WITH NOBLE METALIC AND BIMETALLIC NANOPARTICLES
title_short ENHANCEMENT IN UV SENSING PROPERTIES OF Zno:Ag NANOSTRUCTURED FILMS BY SURFACE FUNCTIONALIZATION WITH NOBLE METALIC AND BIMETALLIC NANOPARTICLES
title_sort enhancement in uv sensing properties of zno ag nanostructured films by surface functionalization with noble metalic and bimetallic nanoparticles
topic UV photodetector
zinc oxide
silver nanoparticles
nanostructured films
url https://jes.utm.md/wp-content/uploads/sites/20/2019/02/JES-2018-3_41-51.pdf
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