Gold(III) Complexation in the Presence of the Macropolyhedral Hydridoborate Cluster [B<sub>20</sub>H<sub>18</sub>]<sup>2−</sup>
Gold(III) complexation with the octadecahydrido-eicosaborate anion [B<sub>20</sub>H<sub>18</sub>]<sup>2−</sup> was studied for the first time. It was found that when gold(III) complexes [Au(L)Cl<sub>2</sub>]BF<sub>4</sub> (L = bipy, phen) r...
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MDPI AG
2022-07-01
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| Series: | Inorganics |
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| Online Access: | https://www.mdpi.com/2304-6740/10/7/99 |
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| author | Varvara V. Avdeeva Anna V. Vologzhanina Alexey S. Kubasov Nailya S. Akhmadullina Oleg N. Shishilov Elena A. Malinina Nikolay T. Kuznetsov |
| author_facet | Varvara V. Avdeeva Anna V. Vologzhanina Alexey S. Kubasov Nailya S. Akhmadullina Oleg N. Shishilov Elena A. Malinina Nikolay T. Kuznetsov |
| author_sort | Varvara V. Avdeeva |
| collection | DOAJ |
| description | Gold(III) complexation with the octadecahydrido-eicosaborate anion [B<sub>20</sub>H<sub>18</sub>]<sup>2−</sup> was studied for the first time. It was found that when gold(III) complexes [Au(L)Cl<sub>2</sub>]BF<sub>4</sub> (L = bipy, phen) reacted with [B<sub>20</sub>H<sub>18</sub>]<sup>2−</sup>, complexes [Au(L)Cl<sub>2</sub>]<sub>2</sub>[B<sub>20</sub>H<sub>18</sub>] were isolated. The compounds consisted of a cationic gold(III) complex [Au(L)Cl<sub>2</sub>]<sup>+</sup> and the hydridoborate cluster as a counterion. X-ray diffraction studies revealed weak B–H...Au interactions for both compounds. Note that more reactive anions [B<i><sub>n</sub></i>H<i><sub>n</sub></i>]<sup>2−</sup> (<i>n</i> = 10, 12) in similar reactions with gold(III) complexes resulted in gold mirror reactions. |
| first_indexed | 2024-03-09T03:20:04Z |
| format | Article |
| id | doaj.art-1a6bd17935864316849ac4faa84c2582 |
| institution | Directory Open Access Journal |
| issn | 2304-6740 |
| language | English |
| last_indexed | 2024-03-09T03:20:04Z |
| publishDate | 2022-07-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Inorganics |
| spelling | doaj.art-1a6bd17935864316849ac4faa84c25822023-12-03T15:11:27ZengMDPI AGInorganics2304-67402022-07-011079910.3390/inorganics10070099Gold(III) Complexation in the Presence of the Macropolyhedral Hydridoborate Cluster [B<sub>20</sub>H<sub>18</sub>]<sup>2−</sup>Varvara V. Avdeeva0Anna V. Vologzhanina1Alexey S. Kubasov2Nailya S. Akhmadullina3Oleg N. Shishilov4Elena A. Malinina5Nikolay T. Kuznetsov6Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991 Moscow, RussiaA.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova Str. 28, 119991 Moscow, RussiaKurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991 Moscow, RussiaBaikov Institute of Metallurgy and Material Science, Russian Academy of Sciences, Leninskii pr. 49, 119334 Moscow, RussiaPhysical Chemistry Department, Lomonosov Institute of Fine Chemical Technologies, MIREA—Russian Technological University, pr. Vernadskogo 86, 119571 Moscow, RussiaKurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991 Moscow, RussiaKurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991 Moscow, RussiaGold(III) complexation with the octadecahydrido-eicosaborate anion [B<sub>20</sub>H<sub>18</sub>]<sup>2−</sup> was studied for the first time. It was found that when gold(III) complexes [Au(L)Cl<sub>2</sub>]BF<sub>4</sub> (L = bipy, phen) reacted with [B<sub>20</sub>H<sub>18</sub>]<sup>2−</sup>, complexes [Au(L)Cl<sub>2</sub>]<sub>2</sub>[B<sub>20</sub>H<sub>18</sub>] were isolated. The compounds consisted of a cationic gold(III) complex [Au(L)Cl<sub>2</sub>]<sup>+</sup> and the hydridoborate cluster as a counterion. X-ray diffraction studies revealed weak B–H...Au interactions for both compounds. Note that more reactive anions [B<i><sub>n</sub></i>H<i><sub>n</sub></i>]<sup>2−</sup> (<i>n</i> = 10, 12) in similar reactions with gold(III) complexes resulted in gold mirror reactions.https://www.mdpi.com/2304-6740/10/7/99hydridoboratesboron clustersmixed-ligand complexesX-ray diffractiongold |
| spellingShingle | Varvara V. Avdeeva Anna V. Vologzhanina Alexey S. Kubasov Nailya S. Akhmadullina Oleg N. Shishilov Elena A. Malinina Nikolay T. Kuznetsov Gold(III) Complexation in the Presence of the Macropolyhedral Hydridoborate Cluster [B<sub>20</sub>H<sub>18</sub>]<sup>2−</sup> Inorganics hydridoborates boron clusters mixed-ligand complexes X-ray diffraction gold |
| title | Gold(III) Complexation in the Presence of the Macropolyhedral Hydridoborate Cluster [B<sub>20</sub>H<sub>18</sub>]<sup>2−</sup> |
| title_full | Gold(III) Complexation in the Presence of the Macropolyhedral Hydridoborate Cluster [B<sub>20</sub>H<sub>18</sub>]<sup>2−</sup> |
| title_fullStr | Gold(III) Complexation in the Presence of the Macropolyhedral Hydridoborate Cluster [B<sub>20</sub>H<sub>18</sub>]<sup>2−</sup> |
| title_full_unstemmed | Gold(III) Complexation in the Presence of the Macropolyhedral Hydridoborate Cluster [B<sub>20</sub>H<sub>18</sub>]<sup>2−</sup> |
| title_short | Gold(III) Complexation in the Presence of the Macropolyhedral Hydridoborate Cluster [B<sub>20</sub>H<sub>18</sub>]<sup>2−</sup> |
| title_sort | gold iii complexation in the presence of the macropolyhedral hydridoborate cluster b sub 20 sub h sub 18 sub sup 2 sup |
| topic | hydridoborates boron clusters mixed-ligand complexes X-ray diffraction gold |
| url | https://www.mdpi.com/2304-6740/10/7/99 |
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