N-(2-{[7-(2-Anilinoethoxy)-3,6-dibromonaphthalen-2-yl]oxy}ethyl)aniline
In the title compound, C26H24Br2N2O2, the central naphthalene system carries two Br atoms and two –CH2CH2NHC6H5 substituents. The phenyl rings of the latter residues are inclined at 74.17 (17) and 51.4 (2)° with respect to the naphthalene ring s...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-05-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812014808 |
| _version_ | 1818320291555704832 |
|---|---|
| author | Qian-Shou Zong Jian-Yi Wu |
| author_facet | Qian-Shou Zong Jian-Yi Wu |
| author_sort | Qian-Shou Zong |
| collection | DOAJ |
| description | In the title compound, C26H24Br2N2O2, the central naphthalene system carries two Br atoms and two –CH2CH2NHC6H5 substituents. The phenyl rings of the latter residues are inclined at 74.17 (17) and 51.4 (2)° with respect to the naphthalene ring system. Each alkyl chain adopts a fully extended all-cis conformation with respect to the naphthalene and phenyl rings [N—C—C—O torsion angles = 68.6 (4) and 60.5 (4)°]. In the crystal, one of the N—H groups forms bifurcated N—H...(Br,O) hydrogen bonds, which link the molecules into inversion-related dimers. The centrosymmetric dimers are aggregated via pairs of C—H...π interactions into sheets parallel to (110). |
| first_indexed | 2024-12-13T10:22:41Z |
| format | Article |
| id | doaj.art-1a85d01aed544058bc99c37b76fefa20 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:22:41Z |
| publishDate | 2012-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-1a85d01aed544058bc99c37b76fefa202022-12-21T23:51:09ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685o1355o135510.1107/S1600536812014808N-(2-{[7-(2-Anilinoethoxy)-3,6-dibromonaphthalen-2-yl]oxy}ethyl)anilineQian-Shou ZongJian-Yi WuIn the title compound, C26H24Br2N2O2, the central naphthalene system carries two Br atoms and two –CH2CH2NHC6H5 substituents. The phenyl rings of the latter residues are inclined at 74.17 (17) and 51.4 (2)° with respect to the naphthalene ring system. Each alkyl chain adopts a fully extended all-cis conformation with respect to the naphthalene and phenyl rings [N—C—C—O torsion angles = 68.6 (4) and 60.5 (4)°]. In the crystal, one of the N—H groups forms bifurcated N—H...(Br,O) hydrogen bonds, which link the molecules into inversion-related dimers. The centrosymmetric dimers are aggregated via pairs of C—H...π interactions into sheets parallel to (110).http://scripts.iucr.org/cgi-bin/paper?S1600536812014808 |
| spellingShingle | Qian-Shou Zong Jian-Yi Wu N-(2-{[7-(2-Anilinoethoxy)-3,6-dibromonaphthalen-2-yl]oxy}ethyl)aniline Acta Crystallographica Section E |
| title | N-(2-{[7-(2-Anilinoethoxy)-3,6-dibromonaphthalen-2-yl]oxy}ethyl)aniline |
| title_full | N-(2-{[7-(2-Anilinoethoxy)-3,6-dibromonaphthalen-2-yl]oxy}ethyl)aniline |
| title_fullStr | N-(2-{[7-(2-Anilinoethoxy)-3,6-dibromonaphthalen-2-yl]oxy}ethyl)aniline |
| title_full_unstemmed | N-(2-{[7-(2-Anilinoethoxy)-3,6-dibromonaphthalen-2-yl]oxy}ethyl)aniline |
| title_short | N-(2-{[7-(2-Anilinoethoxy)-3,6-dibromonaphthalen-2-yl]oxy}ethyl)aniline |
| title_sort | n 2 7 2 anilinoethoxy 3 6 dibromonaphthalen 2 yl oxy ethyl aniline |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812014808 |
| work_keys_str_mv | AT qianshouzong n272anilinoethoxy36dibromonaphthalen2yloxyethylaniline AT jianyiwu n272anilinoethoxy36dibromonaphthalen2yloxyethylaniline |