μ-1,2-Bis(diphenylphosphino)ethane-κ2P:P′-bis{[1,2-bis(diphenylphosphino)ethane-κ2P,P′]bromidocopper(I)} acetone disolvate
In the crystal structure of the title compound, [Cu2Br2(dppe)3]·2CH3COCH3 [dppe is 1,2-bis(diphenylphosphino)ethane, C26H24P2], the two Cu centers are bridged by a dppe ligand and each metal center carries one chelating dppe unit, with the fourth coordination site available for the Br&#...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808031000 |
| Summary: | In the crystal structure of the title compound, [Cu2Br2(dppe)3]·2CH3COCH3 [dppe is 1,2-bis(diphenylphosphino)ethane, C26H24P2], the two Cu centers are bridged by a dppe ligand and each metal center carries one chelating dppe unit, with the fourth coordination site available for the Br− anion. The molecule is centrosymmetric, with the center of symmetry located between the methylene C atoms of the bridging dppe ligand. The crystal structure is stabilized by intramolecular C—H...Br hydrogen bonds and intermolecular π–π interactions, with a centroid-to-centroid distance of 3.2055 (1) Å. |
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| ISSN: | 1600-5368 |