μ-1,2-Bis(diphenylphosphino)ethane-κ2P:P′-bis{[1,2-bis(diphenylphosphino)ethane-κ2P,P′]bromidocopper(I)} acetone disolvate
In the crystal structure of the title compound, [Cu2Br2(dppe)3]·2CH3COCH3 [dppe is 1,2-bis(diphenylphosphino)ethane, C26H24P2], the two Cu centers are bridged by a dppe ligand and each metal center carries one chelating dppe unit, with the fourth coordination site available for the Br&#...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808031000 |
| _version_ | 1798030773072166912 |
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| author | Wen-Juan Shi |
| author_facet | Wen-Juan Shi |
| author_sort | Wen-Juan Shi |
| collection | DOAJ |
| description | In the crystal structure of the title compound, [Cu2Br2(dppe)3]·2CH3COCH3 [dppe is 1,2-bis(diphenylphosphino)ethane, C26H24P2], the two Cu centers are bridged by a dppe ligand and each metal center carries one chelating dppe unit, with the fourth coordination site available for the Br− anion. The molecule is centrosymmetric, with the center of symmetry located between the methylene C atoms of the bridging dppe ligand. The crystal structure is stabilized by intramolecular C—H...Br hydrogen bonds and intermolecular π–π interactions, with a centroid-to-centroid distance of 3.2055 (1) Å. |
| first_indexed | 2024-04-11T19:45:41Z |
| format | Article |
| id | doaj.art-1a85d4c1261a4e3294e07e252bf5f644 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T19:45:41Z |
| publishDate | 2008-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-1a85d4c1261a4e3294e07e252bf5f6442022-12-22T04:06:28ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-10-016410m1346m134710.1107/S1600536808031000μ-1,2-Bis(diphenylphosphino)ethane-κ2P:P′-bis{[1,2-bis(diphenylphosphino)ethane-κ2P,P′]bromidocopper(I)} acetone disolvateWen-Juan ShiIn the crystal structure of the title compound, [Cu2Br2(dppe)3]·2CH3COCH3 [dppe is 1,2-bis(diphenylphosphino)ethane, C26H24P2], the two Cu centers are bridged by a dppe ligand and each metal center carries one chelating dppe unit, with the fourth coordination site available for the Br− anion. The molecule is centrosymmetric, with the center of symmetry located between the methylene C atoms of the bridging dppe ligand. The crystal structure is stabilized by intramolecular C—H...Br hydrogen bonds and intermolecular π–π interactions, with a centroid-to-centroid distance of 3.2055 (1) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536808031000 |
| spellingShingle | Wen-Juan Shi μ-1,2-Bis(diphenylphosphino)ethane-κ2P:P′-bis{[1,2-bis(diphenylphosphino)ethane-κ2P,P′]bromidocopper(I)} acetone disolvate Acta Crystallographica Section E |
| title | μ-1,2-Bis(diphenylphosphino)ethane-κ2P:P′-bis{[1,2-bis(diphenylphosphino)ethane-κ2P,P′]bromidocopper(I)} acetone disolvate |
| title_full | μ-1,2-Bis(diphenylphosphino)ethane-κ2P:P′-bis{[1,2-bis(diphenylphosphino)ethane-κ2P,P′]bromidocopper(I)} acetone disolvate |
| title_fullStr | μ-1,2-Bis(diphenylphosphino)ethane-κ2P:P′-bis{[1,2-bis(diphenylphosphino)ethane-κ2P,P′]bromidocopper(I)} acetone disolvate |
| title_full_unstemmed | μ-1,2-Bis(diphenylphosphino)ethane-κ2P:P′-bis{[1,2-bis(diphenylphosphino)ethane-κ2P,P′]bromidocopper(I)} acetone disolvate |
| title_short | μ-1,2-Bis(diphenylphosphino)ethane-κ2P:P′-bis{[1,2-bis(diphenylphosphino)ethane-κ2P,P′]bromidocopper(I)} acetone disolvate |
| title_sort | 956 1 2 bis diphenylphosphino ethane 954 2p p 8242 bis 1 2 bis diphenylphosphino ethane 954 2p p 8242 bromidocopper i acetone disolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808031000 |
| work_keys_str_mv | AT wenjuanshi 95612bisdiphenylphosphinoethane9542pp8242bis12bisdiphenylphosphinoethane9542pp8242bromidocopperiacetonedisolvate |