Comparison of the effect of Si and Ge presence on phase formation process, the structural and magnetic properties of Co2FeX (X=Ge,Si) Heusler compounds
In this study, the Co2FeX (X=Ge, Si) Heusler compounds with 30 valence electrons, which are made by using mechanical alloying and arc melting methods were studied. The crystallization of samples was confirmed by XRD data in both manufacturing methods. The results showed that the presence of Si than...
Main Authors: | , |
---|---|
Format: | Article |
Language: | English |
Published: |
Isfahan University of Technology
2019-06-01
|
Series: | Iranian Journal of Physics Research |
Subjects: | |
Online Access: | http://ijpr.iut.ac.ir/browse.php?a_code=A-10-1459-2&slc_lang=en&sid=1 |
_version_ | 1818495330414493696 |
---|---|
author | M Safari M Hakimi |
author_facet | M Safari M Hakimi |
author_sort | M Safari |
collection | DOAJ |
description | In this study, the Co2FeX (X=Ge, Si) Heusler compounds with 30 valence electrons, which are made by using mechanical alloying and arc melting methods were studied. The crystallization of samples was confirmed by XRD data in both manufacturing methods. The results showed that the presence of Si than Ge in the compound played a more effective role to creation a large scale atomic ordering, and the maximum saturation magnetization is related to one of the Co2FeSi samples equal to 5.24 . However, the amount obtained is still less than the predicted value by the Slater-Pauling due to this fact that the sample isn’t single crystalline. The microstructure analysis showed that Ge has been working more effective than Si on the enhancement of crystalline nucleation in the milling process. Although the crystallite growth in the annealing process is more rapid in the presence of Ge due to the lower melting point of Ge than Si. The great coercivity observed in the milled sample of Co2FeSi compound was related to the significant anisotropy caused by the atomic ordering and also the large volume of crystallite boundary as barriers into wall movement of domains. |
first_indexed | 2024-12-10T18:19:13Z |
format | Article |
id | doaj.art-1abb990aaca74972b691baee9839a476 |
institution | Directory Open Access Journal |
issn | 1682-6957 2345-3664 |
language | English |
last_indexed | 2024-12-10T18:19:13Z |
publishDate | 2019-06-01 |
publisher | Isfahan University of Technology |
record_format | Article |
series | Iranian Journal of Physics Research |
spelling | doaj.art-1abb990aaca74972b691baee9839a4762022-12-22T01:38:15ZengIsfahan University of TechnologyIranian Journal of Physics Research1682-69572345-36642019-06-01191129137Comparison of the effect of Si and Ge presence on phase formation process, the structural and magnetic properties of Co2FeX (X=Ge,Si) Heusler compoundsM Safari0M Hakimi1 Research and Technology of Magnetism Lab, Physics Department, Yazd University, Yazd, Iran Research and Technology of Magnetism Lab, Physics Department, Yazd University, Yazd, Iran In this study, the Co2FeX (X=Ge, Si) Heusler compounds with 30 valence electrons, which are made by using mechanical alloying and arc melting methods were studied. The crystallization of samples was confirmed by XRD data in both manufacturing methods. The results showed that the presence of Si than Ge in the compound played a more effective role to creation a large scale atomic ordering, and the maximum saturation magnetization is related to one of the Co2FeSi samples equal to 5.24 . However, the amount obtained is still less than the predicted value by the Slater-Pauling due to this fact that the sample isn’t single crystalline. The microstructure analysis showed that Ge has been working more effective than Si on the enhancement of crystalline nucleation in the milling process. Although the crystallite growth in the annealing process is more rapid in the presence of Ge due to the lower melting point of Ge than Si. The great coercivity observed in the milled sample of Co2FeSi compound was related to the significant anisotropy caused by the atomic ordering and also the large volume of crystallite boundary as barriers into wall movement of domains.http://ijpr.iut.ac.ir/browse.php?a_code=A-10-1459-2&slc_lang=en&sid=1Heusler AlloysMagnetismHalf MetalMillingCoercivityMechanical alloyingArc melting |
spellingShingle | M Safari M Hakimi Comparison of the effect of Si and Ge presence on phase formation process, the structural and magnetic properties of Co2FeX (X=Ge,Si) Heusler compounds Iranian Journal of Physics Research Heusler Alloys Magnetism Half Metal Milling Coercivity Mechanical alloying Arc melting |
title | Comparison of the effect of Si and Ge presence on phase formation process, the structural and magnetic properties of Co2FeX (X=Ge,Si) Heusler compounds |
title_full | Comparison of the effect of Si and Ge presence on phase formation process, the structural and magnetic properties of Co2FeX (X=Ge,Si) Heusler compounds |
title_fullStr | Comparison of the effect of Si and Ge presence on phase formation process, the structural and magnetic properties of Co2FeX (X=Ge,Si) Heusler compounds |
title_full_unstemmed | Comparison of the effect of Si and Ge presence on phase formation process, the structural and magnetic properties of Co2FeX (X=Ge,Si) Heusler compounds |
title_short | Comparison of the effect of Si and Ge presence on phase formation process, the structural and magnetic properties of Co2FeX (X=Ge,Si) Heusler compounds |
title_sort | comparison of the effect of si and ge presence on phase formation process the structural and magnetic properties of co2fex x ge si heusler compounds |
topic | Heusler Alloys Magnetism Half Metal Milling Coercivity Mechanical alloying Arc melting |
url | http://ijpr.iut.ac.ir/browse.php?a_code=A-10-1459-2&slc_lang=en&sid=1 |
work_keys_str_mv | AT msafari comparisonoftheeffectofsiandgepresenceonphaseformationprocessthestructuralandmagneticpropertiesofco2fexxgesiheuslercompounds AT mhakimi comparisonoftheeffectofsiandgepresenceonphaseformationprocessthestructuralandmagneticpropertiesofco2fexxgesiheuslercompounds |