Trichlorido[4-methoxy-2,6-bis(2-pyrimidin-2-yl-κN)phenyl-κC1]platinum(IV) acetonitrile monosolvate
In the title complex, [Pt(C15H11N4O)Cl3]·CH3CN, the PtIV ion adopts a distorted octahedral coordination geometry defined by a tridentate cyclometalated NCN ligand and three Cl atoms. In the crystal, individual molecules are aggregated into a three-dimensional network by C—...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812036410 |
| _version_ | 1828438405666570240 |
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| author | Yang Wu Dahai Xie Dengqing Zhang Xianying Li Wusong Jin |
| author_facet | Yang Wu Dahai Xie Dengqing Zhang Xianying Li Wusong Jin |
| author_sort | Yang Wu |
| collection | DOAJ |
| description | In the title complex, [Pt(C15H11N4O)Cl3]·CH3CN, the PtIV ion adopts a distorted octahedral coordination geometry defined by a tridentate cyclometalated NCN ligand and three Cl atoms. In the crystal, individual molecules are aggregated into a three-dimensional network by C—H...Cl hydrogen-bonding interactions and π–π stacking interactions between the tridentate ligands, the shortest ring centroid–centroid distance being 3.613 Å. |
| first_indexed | 2024-12-10T20:04:22Z |
| format | Article |
| id | doaj.art-1ace648eb9ec4b599eb6de05361c0dff |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T20:04:22Z |
| publishDate | 2012-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-1ace648eb9ec4b599eb6de05361c0dff2022-12-22T01:35:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-09-01689m1210m121110.1107/S1600536812036410Trichlorido[4-methoxy-2,6-bis(2-pyrimidin-2-yl-κN)phenyl-κC1]platinum(IV) acetonitrile monosolvateYang WuDahai XieDengqing ZhangXianying LiWusong JinIn the title complex, [Pt(C15H11N4O)Cl3]·CH3CN, the PtIV ion adopts a distorted octahedral coordination geometry defined by a tridentate cyclometalated NCN ligand and three Cl atoms. In the crystal, individual molecules are aggregated into a three-dimensional network by C—H...Cl hydrogen-bonding interactions and π–π stacking interactions between the tridentate ligands, the shortest ring centroid–centroid distance being 3.613 Å.http://scripts.iucr.org/cgi-bin/paper?S1600536812036410 |
| spellingShingle | Yang Wu Dahai Xie Dengqing Zhang Xianying Li Wusong Jin Trichlorido[4-methoxy-2,6-bis(2-pyrimidin-2-yl-κN)phenyl-κC1]platinum(IV) acetonitrile monosolvate Acta Crystallographica Section E |
| title | Trichlorido[4-methoxy-2,6-bis(2-pyrimidin-2-yl-κN)phenyl-κC1]platinum(IV) acetonitrile monosolvate |
| title_full | Trichlorido[4-methoxy-2,6-bis(2-pyrimidin-2-yl-κN)phenyl-κC1]platinum(IV) acetonitrile monosolvate |
| title_fullStr | Trichlorido[4-methoxy-2,6-bis(2-pyrimidin-2-yl-κN)phenyl-κC1]platinum(IV) acetonitrile monosolvate |
| title_full_unstemmed | Trichlorido[4-methoxy-2,6-bis(2-pyrimidin-2-yl-κN)phenyl-κC1]platinum(IV) acetonitrile monosolvate |
| title_short | Trichlorido[4-methoxy-2,6-bis(2-pyrimidin-2-yl-κN)phenyl-κC1]platinum(IV) acetonitrile monosolvate |
| title_sort | trichlorido 4 methoxy 2 6 bis 2 pyrimidin 2 yl amp 954 n phenyl amp 954 c1 platinum iv acetonitrile monosolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812036410 |
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