The Properties of High-Performance Concrete with Manganese Slag under Salt Action

Manganese slag (MS) containing a certain amount of active hydration substances may be used as a kind of cementitious material. In the present study, we measured the mass, the relative dynamic modulus of elasticity (RDME), and the flexural and compressive strengths of MS high-performance concrete (MS...

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Main Authors: Junchao Yang, Hui Wang, Ling Peng, Fei Zhao
Format: Article
Language:English
Published: MDPI AG 2024-03-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/17/7/1483
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author Junchao Yang
Hui Wang
Ling Peng
Fei Zhao
author_facet Junchao Yang
Hui Wang
Ling Peng
Fei Zhao
author_sort Junchao Yang
collection DOAJ
description Manganese slag (MS) containing a certain amount of active hydration substances may be used as a kind of cementitious material. In the present study, we measured the mass, the relative dynamic modulus of elasticity (RDME), and the flexural and compressive strengths of MS high-performance concrete (MS-HPC) with added basalt fibers exposed to NaCl freeze–thaw cycles (N-FCs), NaCl dry–wet alternations (N-DAs), and Na<sub>2</sub>SO<sub>4</sub> dry–wet alternations (NS-DAs). Scanning electron microscope energy-dispersive spectrometer (SEM-EDS) spectra, thermogravimetric analysis (TG) curves, and X-ray diffraction spectroscopy (XRD) curves were obtained. The mass ratio of MS ranged from 0% to 40%. The volume ratio of basalt fibers varied from 0% to 2%. We found that, as a result of salt action, the mass loss rate (MLR) exhibited linear functions which were inversely correlated with the mass ratio of MS and the volume ratio of basalt fibers. After salt action, MLR increased by rates of 0~56.3%, but this increase was attenuated by the addition of MS and basalt fibers. Corresponding increases in RDME exhibited a linear function which was positively correlated with MS mass ratios in a range of 0~55.1%. The addition of MS and basalt fibers also led to decreased attenuation of mechanical strength, while the addition of MS led to increased levels of flocculent hydration products and the elements Mn, Mg, and Fe. CaClOH and CaSO<sub>4</sub> crystals were observed in XRD curves after N-DA and NS-DA actions, respectively. Finally, the addition of MS resulted in increased variation in TG values. However, the opposite result was obtained when dry–wet actions were exerted.
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spelling doaj.art-1aef223ddec641e1846ecb1cc9cd602c2024-04-12T13:21:47ZengMDPI AGMaterials1996-19442024-03-01177148310.3390/ma17071483The Properties of High-Performance Concrete with Manganese Slag under Salt ActionJunchao Yang0Hui Wang1Ling Peng2Fei Zhao3School of Civil Engineering, Hebei University of Architecture, Zhangjiakou 075000, ChinaSchool of Civil Engineering and Geographic Environment, Ningbo University, Ningbo 315000, ChinaDepartment of Mathematics and Physics, Hebei University of Architecture, Zhangjiakou 075000, ChinaSchool of Civil Engineering, Hebei University of Architecture, Zhangjiakou 075000, ChinaManganese slag (MS) containing a certain amount of active hydration substances may be used as a kind of cementitious material. In the present study, we measured the mass, the relative dynamic modulus of elasticity (RDME), and the flexural and compressive strengths of MS high-performance concrete (MS-HPC) with added basalt fibers exposed to NaCl freeze–thaw cycles (N-FCs), NaCl dry–wet alternations (N-DAs), and Na<sub>2</sub>SO<sub>4</sub> dry–wet alternations (NS-DAs). Scanning electron microscope energy-dispersive spectrometer (SEM-EDS) spectra, thermogravimetric analysis (TG) curves, and X-ray diffraction spectroscopy (XRD) curves were obtained. The mass ratio of MS ranged from 0% to 40%. The volume ratio of basalt fibers varied from 0% to 2%. We found that, as a result of salt action, the mass loss rate (MLR) exhibited linear functions which were inversely correlated with the mass ratio of MS and the volume ratio of basalt fibers. After salt action, MLR increased by rates of 0~56.3%, but this increase was attenuated by the addition of MS and basalt fibers. Corresponding increases in RDME exhibited a linear function which was positively correlated with MS mass ratios in a range of 0~55.1%. The addition of MS and basalt fibers also led to decreased attenuation of mechanical strength, while the addition of MS led to increased levels of flocculent hydration products and the elements Mn, Mg, and Fe. CaClOH and CaSO<sub>4</sub> crystals were observed in XRD curves after N-DA and NS-DA actions, respectively. Finally, the addition of MS resulted in increased variation in TG values. However, the opposite result was obtained when dry–wet actions were exerted.https://www.mdpi.com/1996-1944/17/7/1483manganese slagbasalt fibersmechanical strengthssalt actionX-ray diffraction spectroscopyscanning electron microscope
spellingShingle Junchao Yang
Hui Wang
Ling Peng
Fei Zhao
The Properties of High-Performance Concrete with Manganese Slag under Salt Action
Materials
manganese slag
basalt fibers
mechanical strengths
salt action
X-ray diffraction spectroscopy
scanning electron microscope
title The Properties of High-Performance Concrete with Manganese Slag under Salt Action
title_full The Properties of High-Performance Concrete with Manganese Slag under Salt Action
title_fullStr The Properties of High-Performance Concrete with Manganese Slag under Salt Action
title_full_unstemmed The Properties of High-Performance Concrete with Manganese Slag under Salt Action
title_short The Properties of High-Performance Concrete with Manganese Slag under Salt Action
title_sort properties of high performance concrete with manganese slag under salt action
topic manganese slag
basalt fibers
mechanical strengths
salt action
X-ray diffraction spectroscopy
scanning electron microscope
url https://www.mdpi.com/1996-1944/17/7/1483
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