Ordering Phase Transition with Symmetry-Breaking from Disorder over Non-Equivalent Sites: Calorimetric and Crystallographic Study of Crystalline <span style="font-variant: small-caps;">d</span>-Sorbose

Ordering Phase Transition with Symmetry-Breaking from Disorder over Non-Equivalent Sites: Calorimetric and Crystallographic Study of Crystalline <span style="font-variant: small-caps;">d</span>-Sorbose

Phase transitions in the crystalline state of chiral sorbose were examined using precise heat capacity calorimetry and X-ray crystallography. The calorimetry established heat capacity below room temperature. Besides the known transition (main transition) at 199.5 K, the calorimetry detected plural t...

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Bibliographic Details
Main Authors: Sakiko Iwagaki, Hiroki Kakuta, Yasuhisa Yamamura, Hideki Saitoh, Mafumi Hishida, Kazuhiro Fukada, Kazuya Saito
Format: Article
Language:English
Published: MDPI AG 2020-05-01
Series:Crystals
Subjects:
structural phase transition
order-disorder transition
symmetry-breaking
calorimetry
entropy of transition
Online Access:https://www.mdpi.com/2073-4352/10/5/361

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