Unexpected Formation of a Disulfide from 2-Mercaptopyridine and Co(II)

The reaction between the Co(II) ion and 2-mercaptopyridine in the presence of base yields a disulfide Co(II) complex, namely [CoCl2(2,2¢-dipyridyldisulfide)] 1. The structure has been determined by single crystal X-ray crystallography. The Co(II) ion coordinates to two chlorine atoms and two nitroge...

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Bibliographic Details
Main Authors: Phimphaka HARDING, David J. HARDING, Chaveng PAKAWATCHAI
Format: Article
Language:English
Published: Walailak University 2011-11-01
Series:Walailak Journal of Science and Technology
Subjects:
Online Access:http://wjst.wu.ac.th/index.php/wjst/article/view/150