Molecular Electronics – Resonant Transport through Single Molecules
The mechanically controllable break-junction technique (MCBJ) enables us to investigate charge transport through an individually contacted and addressed molecule in ultra-high vacuum (UHV) environment at variable temperature ranging from room temperature down to 4 K. Using a statistical me...
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| Format: | Article |
| Language: | deu |
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Swiss Chemical Society
2010-06-01
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| Series: | CHIMIA |
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| Online Access: | https://www.chimia.ch/chimia/article/view/4865 |
| _version_ | 1818281910664691712 |
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| author | Emanuel Lörtscher Heike Riel |
| author_facet | Emanuel Lörtscher Heike Riel |
| author_sort | Emanuel Lörtscher |
| collection | DOAJ |
| description |
The mechanically controllable break-junction technique (MCBJ) enables us to investigate charge transport through an individually contacted and addressed molecule in ultra-high vacuum (UHV) environment at variable temperature ranging from room temperature down to 4 K. Using a statistical
measurement and analysis approach, we acquire current–voltage (I-V) characteristics during the repeated formation, manipulation, and breaking of a molecular junction. At low temperatures, voltages accessing the first molecular orbitals in resonance can be applied, providing spectroscopic
information about the junction's energy landscape, in particular about the molecular level alignment in respect to the Fermi energy of the electrodes. Thereby, we can investigate the non-linear transport properties of various types of functional molecules and explore their potential use as
functional building blocks for future nano-electronics. An example will be given by the reversible and controllable switching between two distinct conductive states of a single molecule. As a proof-of-principle for functional molecular devices, a single-molecule memory element will be demonstrated.
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| first_indexed | 2024-12-13T00:12:38Z |
| format | Article |
| id | doaj.art-1b333cb5a464409591b1f001b2382735 |
| institution | Directory Open Access Journal |
| issn | 0009-4293 2673-2424 |
| language | deu |
| last_indexed | 2024-12-13T00:12:38Z |
| publishDate | 2010-06-01 |
| publisher | Swiss Chemical Society |
| record_format | Article |
| series | CHIMIA |
| spelling | doaj.art-1b333cb5a464409591b1f001b23827352022-12-22T00:05:53ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24242010-06-0164610.2533/chimia.2010.376Molecular Electronics – Resonant Transport through Single MoleculesEmanuel Lörtscher0Heike Riel1IBM - Zurich, Science & Technology Department, Säumerstrasse 4, CH-8803 RüschlikonIBM - Zurich, Science & Technology Department, Säumerstrasse 4, CH-8803 Rüschlikon The mechanically controllable break-junction technique (MCBJ) enables us to investigate charge transport through an individually contacted and addressed molecule in ultra-high vacuum (UHV) environment at variable temperature ranging from room temperature down to 4 K. Using a statistical measurement and analysis approach, we acquire current–voltage (I-V) characteristics during the repeated formation, manipulation, and breaking of a molecular junction. At low temperatures, voltages accessing the first molecular orbitals in resonance can be applied, providing spectroscopic information about the junction's energy landscape, in particular about the molecular level alignment in respect to the Fermi energy of the electrodes. Thereby, we can investigate the non-linear transport properties of various types of functional molecules and explore their potential use as functional building blocks for future nano-electronics. An example will be given by the reversible and controllable switching between two distinct conductive states of a single molecule. As a proof-of-principle for functional molecular devices, a single-molecule memory element will be demonstrated. https://www.chimia.ch/chimia/article/view/4865Electron transportMechanically controllable break-junctionMolecular building blocksMolecular electronicsSingle molecules |
| spellingShingle | Emanuel Lörtscher Heike Riel Molecular Electronics – Resonant Transport through Single Molecules CHIMIA Electron transport Mechanically controllable break-junction Molecular building blocks Molecular electronics Single molecules |
| title | Molecular Electronics – Resonant Transport through Single Molecules |
| title_full | Molecular Electronics – Resonant Transport through Single Molecules |
| title_fullStr | Molecular Electronics – Resonant Transport through Single Molecules |
| title_full_unstemmed | Molecular Electronics – Resonant Transport through Single Molecules |
| title_short | Molecular Electronics – Resonant Transport through Single Molecules |
| title_sort | molecular electronics resonant transport through single molecules |
| topic | Electron transport Mechanically controllable break-junction Molecular building blocks Molecular electronics Single molecules |
| url | https://www.chimia.ch/chimia/article/view/4865 |
| work_keys_str_mv | AT emanuellortscher molecularelectronicsresonanttransportthroughsinglemolecules AT heikeriel molecularelectronicsresonanttransportthroughsinglemolecules |