Tetrakis(triethylenediamin-1-ium) dodeca-μ2-chlorido-hexakis(thiocyanato-κN)hexa-octahedro-niobate

Tetrakis(triethylenediamin-1-ium) dodeca-μ2-chlorido-hexakis(thiocyanato-κN)hexa-octahedro-niobate

The crystal structure of the cluster complex salt, (C6H13N2)4[Nb6(NCS)6Cl12] or (H-DABCO)4[Nb6Cl12(NCS)6] (DABCO = triethylenediamine or 1,4-diazabicyclo[2.2.2]octane), comprises octahedral Nb6 cluster cores, which are μ2-coordinated by 12 chloride ligands (bridging the octahedral edges, inner ligan...

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Bibliographic Details
Main Authors:	Eric Sperlich, Martin Köckerling
Format:	Article
Language:	English
Published:	International Union of Crystallography 2023-05-01
Series:	IUCrData
Subjects:	crystal structure niobium cluster chloride dabco
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S241431462300398X

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