tert-Butyl 2-{[5-(4-cyanophenyl)pyridin-3-yl]sulfonyl}acetate

In the title compound, C18H18N2O4S, the dihedral angle between the aromatic rings is 33.71 (9)° and an intramolecular C—H...O hydrogen bond closes an S(6) ring. In the crystal, molecules are linked by C—H...O and C—H...N hydrogen bonds to generate a three-dimensional network. A very weak aromatic π–...

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Main Authors: H. C. Devarajegowda, B. S. Palakshamurthy, K. E. Manojkumar, S. Sreenivasa
Format: Article
Language:English
Published: International Union of Crystallography 2014-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681400511X
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author H. C. Devarajegowda
B. S. Palakshamurthy
K. E. Manojkumar
S. Sreenivasa
author_facet H. C. Devarajegowda
B. S. Palakshamurthy
K. E. Manojkumar
S. Sreenivasa
author_sort H. C. Devarajegowda
collection DOAJ
description In the title compound, C18H18N2O4S, the dihedral angle between the aromatic rings is 33.71 (9)° and an intramolecular C—H...O hydrogen bond closes an S(6) ring. In the crystal, molecules are linked by C—H...O and C—H...N hydrogen bonds to generate a three-dimensional network. A very weak aromatic π–π stacking interction is also observed [centroid–centroid separation = 3.9524 (10) Å].
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spelling doaj.art-1b5a2ab4b12e438988b85827ec44501b2022-12-22T04:14:35ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-04-01704o415o41510.1107/S160053681400511Xhb7202tert-Butyl 2-{[5-(4-cyanophenyl)pyridin-3-yl]sulfonyl}acetateH. C. Devarajegowda0B. S. Palakshamurthy1K. E. Manojkumar2S. Sreenivasa3Department of Physics, Yuvaraja's College (Constituent College), University of Mysore, Karnataka, IndiaDepartment of Physics, Yuvaraja's College (Constituent College), University of Mysore, Karnataka, IndiaDepartment of Studies and Research in Chemistry, Tumkur University, Tumkur, Karnataka 572 103, IndiaDepartment of Studies and Research in Chemistry, Tumkur University, Tumkur, Karnataka 572 103, IndiaIn the title compound, C18H18N2O4S, the dihedral angle between the aromatic rings is 33.71 (9)° and an intramolecular C—H...O hydrogen bond closes an S(6) ring. In the crystal, molecules are linked by C—H...O and C—H...N hydrogen bonds to generate a three-dimensional network. A very weak aromatic π–π stacking interction is also observed [centroid–centroid separation = 3.9524 (10) Å].http://scripts.iucr.org/cgi-bin/paper?S160053681400511X
spellingShingle H. C. Devarajegowda
B. S. Palakshamurthy
K. E. Manojkumar
S. Sreenivasa
tert-Butyl 2-{[5-(4-cyanophenyl)pyridin-3-yl]sulfonyl}acetate
Acta Crystallographica Section E
title tert-Butyl 2-{[5-(4-cyanophenyl)pyridin-3-yl]sulfonyl}acetate
title_full tert-Butyl 2-{[5-(4-cyanophenyl)pyridin-3-yl]sulfonyl}acetate
title_fullStr tert-Butyl 2-{[5-(4-cyanophenyl)pyridin-3-yl]sulfonyl}acetate
title_full_unstemmed tert-Butyl 2-{[5-(4-cyanophenyl)pyridin-3-yl]sulfonyl}acetate
title_short tert-Butyl 2-{[5-(4-cyanophenyl)pyridin-3-yl]sulfonyl}acetate
title_sort tert butyl 2 5 4 cyanophenyl pyridin 3 yl sulfonyl acetate
url http://scripts.iucr.org/cgi-bin/paper?S160053681400511X
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AT bspalakshamurthy tertbutyl254cyanophenylpyridin3ylsulfonylacetate
AT kemanojkumar tertbutyl254cyanophenylpyridin3ylsulfonylacetate
AT ssreenivasa tertbutyl254cyanophenylpyridin3ylsulfonylacetate