Diaquabis[4-(dimethylamino)benzoato-κO](isonicotinamide-κN1)manganese(II)
The title MnII complex, [Mn(C9H10NO2)2(C6H6N2O)(H2O)2], contains two 4-(dimethylamino)benzoate (DMAB) anions, one isonicotinamide (INA) ligand and two coordinated water molecules. One of the DMAB anions acts as a bidentate ligand, while the other is monodentate. The four O atoms in the equatorial pl...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809027093 |
| _version_ | 1818776241244733440 |
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| author | Tuncer Hökelek Hakan Dal Barış Tercan Özgür Aybirdi Hacali Necefoğlu |
| author_facet | Tuncer Hökelek Hakan Dal Barış Tercan Özgür Aybirdi Hacali Necefoğlu |
| author_sort | Tuncer Hökelek |
| collection | DOAJ |
| description | The title MnII complex, [Mn(C9H10NO2)2(C6H6N2O)(H2O)2], contains two 4-(dimethylamino)benzoate (DMAB) anions, one isonicotinamide (INA) ligand and two coordinated water molecules. One of the DMAB anions acts as a bidentate ligand, while the other is monodentate. The four O atoms in the equatorial plane around the Mn atom form a highly distorted square-planar arrangement, while the distorted octahedral coordination geometry is completed by the N atom of the INA ligand and the O atom of the second water molecule in the axial positions. In the crystal structure, strong intermolecular O—H...O, O—H...N and N—H...O hydrogen bonds link the molecules into a two-dimensional network parallel to (010). Two weak C—H...π interactions are also found. |
| first_indexed | 2024-12-18T11:09:48Z |
| format | Article |
| id | doaj.art-1b6ec6f88ac14e7ab28b9bfd247ddac9 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-18T11:09:48Z |
| publishDate | 2009-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-1b6ec6f88ac14e7ab28b9bfd247ddac92022-12-21T21:10:01ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-09-01659m1037m103810.1107/S1600536809027093Diaquabis[4-(dimethylamino)benzoato-κO](isonicotinamide-κN1)manganese(II)Tuncer HökelekHakan DalBarış TercanÖzgür AybirdiHacali NecefoğluThe title MnII complex, [Mn(C9H10NO2)2(C6H6N2O)(H2O)2], contains two 4-(dimethylamino)benzoate (DMAB) anions, one isonicotinamide (INA) ligand and two coordinated water molecules. One of the DMAB anions acts as a bidentate ligand, while the other is monodentate. The four O atoms in the equatorial plane around the Mn atom form a highly distorted square-planar arrangement, while the distorted octahedral coordination geometry is completed by the N atom of the INA ligand and the O atom of the second water molecule in the axial positions. In the crystal structure, strong intermolecular O—H...O, O—H...N and N—H...O hydrogen bonds link the molecules into a two-dimensional network parallel to (010). Two weak C—H...π interactions are also found.http://scripts.iucr.org/cgi-bin/paper?S1600536809027093 |
| spellingShingle | Tuncer Hökelek Hakan Dal Barış Tercan Özgür Aybirdi Hacali Necefoğlu Diaquabis[4-(dimethylamino)benzoato-κO](isonicotinamide-κN1)manganese(II) Acta Crystallographica Section E |
| title | Diaquabis[4-(dimethylamino)benzoato-κO](isonicotinamide-κN1)manganese(II) |
| title_full | Diaquabis[4-(dimethylamino)benzoato-κO](isonicotinamide-κN1)manganese(II) |
| title_fullStr | Diaquabis[4-(dimethylamino)benzoato-κO](isonicotinamide-κN1)manganese(II) |
| title_full_unstemmed | Diaquabis[4-(dimethylamino)benzoato-κO](isonicotinamide-κN1)manganese(II) |
| title_short | Diaquabis[4-(dimethylamino)benzoato-κO](isonicotinamide-κN1)manganese(II) |
| title_sort | diaquabis 4 dimethylamino benzoato amp 954 o isonicotinamide amp 954 n1 manganese ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809027093 |
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