(-)-SCLAREOL CONVERSION IN RITTER'S REACTION CONDITIONS

The main products of sclareol (1) Ritter’s reaction in mild conditions are (8R,13R)-Labd-14(15)-en-8,13-diacetamide (2) (8R,13S)-Labd-14(15)-en-8,13-diacetamide (3) stereoisomeric on C13 atom and having unrearranged native diol skeleton. We present in the current communication the results of sclareo...

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Main Authors: S. Kovalskaya, N. Kozlov, A. Aricu, V. Kulcitki, N. Ungur
Format: Article
Language:English
Published: Academy of Sciences of Moldova, Institute of Chemistry 2012-12-01
Series:Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
Subjects:
Online Access:http://www.cjm.asm.md/sites/default/files/article_files/Kovalskaia%20147-148.pdf
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author S. Kovalskaya
N. Kozlov
A. Aricu
V. Kulcitki
N. Ungur
author_facet S. Kovalskaya
N. Kozlov
A. Aricu
V. Kulcitki
N. Ungur
author_sort S. Kovalskaya
collection DOAJ
description The main products of sclareol (1) Ritter’s reaction in mild conditions are (8R,13R)-Labd-14(15)-en-8,13-diacetamide (2) (8R,13S)-Labd-14(15)-en-8,13-diacetamide (3) stereoisomeric on C13 atom and having unrearranged native diol skeleton. We present in the current communication the results of sclareol converting (1) into nitrogen-containing labdanes in the Ritter’s reaction conditions.
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spelling doaj.art-1b7a69356dca42cd8a8fcd11d027a5282022-12-21T18:23:25ZengAcademy of Sciences of Moldova, Institute of ChemistryChemistry Journal of Moldova: General, Industrial and Ecological Chemistry1857-17272345-16882012-12-0172147148(-)-SCLAREOL CONVERSION IN RITTER'S REACTION CONDITIONS S. Kovalskaya0N. Kozlov1A. Aricu2V. Kulcitki3N. Ungur4 Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus Institute of Physical Organic Chemistry, National Academy of Sciences of BelarusInstitute of Chemistry of Academy of Sciences of MoldovaInstitute of Chemistry of Academy of Sciences of MoldovaInstitute of Chemistry of Academy of Sciences of MoldovaThe main products of sclareol (1) Ritter’s reaction in mild conditions are (8R,13R)-Labd-14(15)-en-8,13-diacetamide (2) (8R,13S)-Labd-14(15)-en-8,13-diacetamide (3) stereoisomeric on C13 atom and having unrearranged native diol skeleton. We present in the current communication the results of sclareol converting (1) into nitrogen-containing labdanes in the Ritter’s reaction conditions.http://www.cjm.asm.md/sites/default/files/article_files/Kovalskaia%20147-148.pdfMALDI-ToFX-ray phase analysisalbuminimmunoglobulin Ghydroxyapatiteinteraction.
spellingShingle S. Kovalskaya
N. Kozlov
A. Aricu
V. Kulcitki
N. Ungur
(-)-SCLAREOL CONVERSION IN RITTER'S REACTION CONDITIONS
Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
MALDI-ToF
X-ray phase analysis
albumin
immunoglobulin G
hydroxyapatite
interaction.
title (-)-SCLAREOL CONVERSION IN RITTER'S REACTION CONDITIONS
title_full (-)-SCLAREOL CONVERSION IN RITTER'S REACTION CONDITIONS
title_fullStr (-)-SCLAREOL CONVERSION IN RITTER'S REACTION CONDITIONS
title_full_unstemmed (-)-SCLAREOL CONVERSION IN RITTER'S REACTION CONDITIONS
title_short (-)-SCLAREOL CONVERSION IN RITTER'S REACTION CONDITIONS
title_sort sclareol conversion in ritter s reaction conditions
topic MALDI-ToF
X-ray phase analysis
albumin
immunoglobulin G
hydroxyapatite
interaction.
url http://www.cjm.asm.md/sites/default/files/article_files/Kovalskaia%20147-148.pdf
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AT nkozlov sclareolconversioninrittersreactionconditions
AT aaricu sclareolconversioninrittersreactionconditions
AT vkulcitki sclareolconversioninrittersreactionconditions
AT nungur sclareolconversioninrittersreactionconditions