Modified Activated Graphene-Based Carbon Electrodes from Rice Husk for Supercapacitor Applications

The renewable biomass material obtained from rice husk, a low-cost agricultural waste, was used as a precursor to synthesize a highly porous graphene-based carbon as electrode material for supercapacitors. Activated graphene-based carbon (AGC) was obtained by a two-step chemical procedure and exhibi...

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Main Authors: Mukhtar Yeleuov, Christopher Seidl, Tolganay Temirgaliyeva, Azamat Taurbekov, Nicholay Prikhodko, Bakytzhan Lesbayev, Fail Sultanov, Chingis Daulbayev, Serik Kumekov
Format: Article
Language:English
Published: MDPI AG 2020-09-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/13/18/4943
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author Mukhtar Yeleuov
Christopher Seidl
Tolganay Temirgaliyeva
Azamat Taurbekov
Nicholay Prikhodko
Bakytzhan Lesbayev
Fail Sultanov
Chingis Daulbayev
Serik Kumekov
author_facet Mukhtar Yeleuov
Christopher Seidl
Tolganay Temirgaliyeva
Azamat Taurbekov
Nicholay Prikhodko
Bakytzhan Lesbayev
Fail Sultanov
Chingis Daulbayev
Serik Kumekov
author_sort Mukhtar Yeleuov
collection DOAJ
description The renewable biomass material obtained from rice husk, a low-cost agricultural waste, was used as a precursor to synthesize a highly porous graphene-based carbon as electrode material for supercapacitors. Activated graphene-based carbon (AGC) was obtained by a two-step chemical procedure and exhibited a very high specific surface area (SSA) of 3292 m<sup>2</sup> g<sup>−1</sup>. The surface morphology of the synthesized materials was studied using scanning and transmission electron microscopy (SEM, TEM). Furthermore, the AGC was modified with nickel hydroxide Ni(OH)<sub>2</sub> through a simple chemical precipitation method. It was found that the most significant increase in capacitance could be reached with Ni(OH)<sub>2</sub> loadings of around 9 wt.%. The measured specific capacitance of the pure AGC supercapacitor electrodes was 236 F g<sup>−1</sup>, whereas electrodes from the material modified with 9 wt.% Ni(OH)<sub>2</sub> showed a specific capacitance of up to 300 F g<sup>−1</sup> at a current density of 50 mA g<sup>−1</sup>. The increase in specific capacitance achieved due to chemical modification was, therefore 27%.
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spelling doaj.art-1b8e447f04cb4808ab7696af57fecbb82023-11-20T14:28:09ZengMDPI AGEnergies1996-10732020-09-011318494310.3390/en13184943Modified Activated Graphene-Based Carbon Electrodes from Rice Husk for Supercapacitor ApplicationsMukhtar Yeleuov0Christopher Seidl1Tolganay Temirgaliyeva2Azamat Taurbekov3Nicholay Prikhodko4Bakytzhan Lesbayev5Fail Sultanov6Chingis Daulbayev7Serik Kumekov8Department of Engineering Physics, Satbayev University, Almaty 050013, KazakhstanFaculty of Engineering & Natural Sciences, Johannes Kepler University Linz, 4040 Linz, AustriaLaboratory of Carbon Nanomaterials Synthesis in Flame, Institute of Combustion Problems, Almaty 050000, KazakhstanLaboratory of Carbon Nanomaterials Synthesis in Flame, Institute of Combustion Problems, Almaty 050000, KazakhstanLaboratory of Carbon Nanomaterials Synthesis in Flame, Institute of Combustion Problems, Almaty 050000, KazakhstanLaboratory of Carbon Nanomaterials Synthesis in Flame, Institute of Combustion Problems, Almaty 050000, KazakhstanLaboratory of Carbon Nanomaterials Synthesis in Flame, Institute of Combustion Problems, Almaty 050000, KazakhstanDepartment of Engineering Physics, Satbayev University, Almaty 050013, KazakhstanDepartment of Engineering Physics, Satbayev University, Almaty 050013, KazakhstanThe renewable biomass material obtained from rice husk, a low-cost agricultural waste, was used as a precursor to synthesize a highly porous graphene-based carbon as electrode material for supercapacitors. Activated graphene-based carbon (AGC) was obtained by a two-step chemical procedure and exhibited a very high specific surface area (SSA) of 3292 m<sup>2</sup> g<sup>−1</sup>. The surface morphology of the synthesized materials was studied using scanning and transmission electron microscopy (SEM, TEM). Furthermore, the AGC was modified with nickel hydroxide Ni(OH)<sub>2</sub> through a simple chemical precipitation method. It was found that the most significant increase in capacitance could be reached with Ni(OH)<sub>2</sub> loadings of around 9 wt.%. The measured specific capacitance of the pure AGC supercapacitor electrodes was 236 F g<sup>−1</sup>, whereas electrodes from the material modified with 9 wt.% Ni(OH)<sub>2</sub> showed a specific capacitance of up to 300 F g<sup>−1</sup> at a current density of 50 mA g<sup>−1</sup>. The increase in specific capacitance achieved due to chemical modification was, therefore 27%.https://www.mdpi.com/1996-1073/13/18/4943supercapacitor electrodeactivated rice huskfew-layer graphenenickel hydroxide
spellingShingle Mukhtar Yeleuov
Christopher Seidl
Tolganay Temirgaliyeva
Azamat Taurbekov
Nicholay Prikhodko
Bakytzhan Lesbayev
Fail Sultanov
Chingis Daulbayev
Serik Kumekov
Modified Activated Graphene-Based Carbon Electrodes from Rice Husk for Supercapacitor Applications
Energies
supercapacitor electrode
activated rice husk
few-layer graphene
nickel hydroxide
title Modified Activated Graphene-Based Carbon Electrodes from Rice Husk for Supercapacitor Applications
title_full Modified Activated Graphene-Based Carbon Electrodes from Rice Husk for Supercapacitor Applications
title_fullStr Modified Activated Graphene-Based Carbon Electrodes from Rice Husk for Supercapacitor Applications
title_full_unstemmed Modified Activated Graphene-Based Carbon Electrodes from Rice Husk for Supercapacitor Applications
title_short Modified Activated Graphene-Based Carbon Electrodes from Rice Husk for Supercapacitor Applications
title_sort modified activated graphene based carbon electrodes from rice husk for supercapacitor applications
topic supercapacitor electrode
activated rice husk
few-layer graphene
nickel hydroxide
url https://www.mdpi.com/1996-1073/13/18/4943
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AT azamattaurbekov modifiedactivatedgraphenebasedcarbonelectrodesfromricehuskforsupercapacitorapplications
AT nicholayprikhodko modifiedactivatedgraphenebasedcarbonelectrodesfromricehuskforsupercapacitorapplications
AT bakytzhanlesbayev modifiedactivatedgraphenebasedcarbonelectrodesfromricehuskforsupercapacitorapplications
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AT serikkumekov modifiedactivatedgraphenebasedcarbonelectrodesfromricehuskforsupercapacitorapplications