Deep eutectic solvents as sustainable solvents for industrial separation problems: A recent update
Deep eutectic solvents (DESs) are ionic liquid analogues that consist of Lewis or Brønsted acids and bases. These systems are characterized by a substantial decrease in melting points as compared to those of the neat constituents. Activity coefficients at infinite dilution of organic solutes is used...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2023-12-01
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| Series: | Journal of Ionic Liquids |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2772422023000174 |
| _version_ | 1827635969708261376 |
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| author | Ncomeka Mgxadeni Bakusele Kabane Indra Bahadur Rajender S. Varma Shailendra Kumar Singh |
| author_facet | Ncomeka Mgxadeni Bakusele Kabane Indra Bahadur Rajender S. Varma Shailendra Kumar Singh |
| author_sort | Ncomeka Mgxadeni |
| collection | DOAJ |
| description | Deep eutectic solvents (DESs) are ionic liquid analogues that consist of Lewis or Brønsted acids and bases. These systems are characterized by a substantial decrease in melting points as compared to those of the neat constituents. Activity coefficients at infinite dilution of organic solutes is used as a screening tool for extracting solvents, an approach that is useful for identifying acceptable precursors and assessing separation performance in practical applications. This review assesses the effectiveness of DESs as solvents for chemical separations wherein the data is presented for the activity coefficients at infinite dilution for 33 solutes in different DESs at various temperatures. Additionally, the selectivities and capacities for various solute extraction problems are also appraised from the activity coefficients at infinite dilution at T = 323.15 K; capacity represents the solvent's ability to extract the component. |
| first_indexed | 2024-03-09T15:34:44Z |
| format | Article |
| id | doaj.art-1ba74600e0c14188904ac505881d5621 |
| institution | Directory Open Access Journal |
| issn | 2772-4220 |
| language | English |
| last_indexed | 2024-03-09T15:34:44Z |
| publishDate | 2023-12-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Journal of Ionic Liquids |
| spelling | doaj.art-1ba74600e0c14188904ac505881d56212023-11-26T05:14:34ZengElsevierJournal of Ionic Liquids2772-42202023-12-0132100065Deep eutectic solvents as sustainable solvents for industrial separation problems: A recent updateNcomeka Mgxadeni0Bakusele Kabane1Indra Bahadur2Rajender S. Varma3Shailendra Kumar Singh4Department of Chemistry and Materials Science Innovation & Modelling Research Focus Area, School of Physical and Chemical Sciences, Faculty of Natural and Agricultural Sciences, North-West University (Mafikeng Campus), Private Bag X2046, Mmabatho 2735, South AfricaPhysical Chemistry Laboratories, Department of Chemistry, Durban University of Technology (ML-Sultan Campus), Durban 4000, South AfricaDepartment of Chemistry and Materials Science Innovation & Modelling Research Focus Area, School of Physical and Chemical Sciences, Faculty of Natural and Agricultural Sciences, North-West University (Mafikeng Campus), Private Bag X2046, Mmabatho 2735, South Africa; Corresponding author.Institute for Nanomaterials, Advanced Technologies, and Innovation (CxI), Technical University of Liberec (TUL), Studentská 1402/2, Liberec 146117, Czech RepublicDepartment of Chemistry, Hansraj College, University of Delhi, Delhi 110007 IndiaDeep eutectic solvents (DESs) are ionic liquid analogues that consist of Lewis or Brønsted acids and bases. These systems are characterized by a substantial decrease in melting points as compared to those of the neat constituents. Activity coefficients at infinite dilution of organic solutes is used as a screening tool for extracting solvents, an approach that is useful for identifying acceptable precursors and assessing separation performance in practical applications. This review assesses the effectiveness of DESs as solvents for chemical separations wherein the data is presented for the activity coefficients at infinite dilution for 33 solutes in different DESs at various temperatures. Additionally, the selectivities and capacities for various solute extraction problems are also appraised from the activity coefficients at infinite dilution at T = 323.15 K; capacity represents the solvent's ability to extract the component.http://www.sciencedirect.com/science/article/pii/S2772422023000174Deep eutectic solventsActivity coefficientSelectivityCapacitySeparation |
| spellingShingle | Ncomeka Mgxadeni Bakusele Kabane Indra Bahadur Rajender S. Varma Shailendra Kumar Singh Deep eutectic solvents as sustainable solvents for industrial separation problems: A recent update Journal of Ionic Liquids Deep eutectic solvents Activity coefficient Selectivity Capacity Separation |
| title | Deep eutectic solvents as sustainable solvents for industrial separation problems: A recent update |
| title_full | Deep eutectic solvents as sustainable solvents for industrial separation problems: A recent update |
| title_fullStr | Deep eutectic solvents as sustainable solvents for industrial separation problems: A recent update |
| title_full_unstemmed | Deep eutectic solvents as sustainable solvents for industrial separation problems: A recent update |
| title_short | Deep eutectic solvents as sustainable solvents for industrial separation problems: A recent update |
| title_sort | deep eutectic solvents as sustainable solvents for industrial separation problems a recent update |
| topic | Deep eutectic solvents Activity coefficient Selectivity Capacity Separation |
| url | http://www.sciencedirect.com/science/article/pii/S2772422023000174 |
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