| Summary: | Here, we present composites and materials that can be prepared starting with boron hydride cluster compounds (decaborane, decahydro-<i>closo</i>-decaborate and dodecahydro-<i>closo</i>-dodecaborate anions and carboranes). Recent examples of their utilization as boron protective coatings including using them to synthesize boron carbide, boron nitride, metal borides, metal-containing composites, and neutron shielding materials are discussed. The data are generalized demonstrate the versatile application of materials based on boron cluster anions and carboranes in various fields.
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