High-Stability Hybrid Organic-Inorganic Perovskite (CH<sub>3</sub>NH<sub>3</sub>PbBr<sub>3</sub>) in SiO<sub>2</sub> Mesopores: Nonlinear Optics and Applications for Q-Switching Laser Operation

Hybrid organic-inorganic perovskite shows a great potential in the field of photoelectrics. Embedding methyl ammonium lead bromide (MAPbBr<sub>3</sub>) in a mesoporous silica (mSiO<sub>2</sub>) layer is an effective method for maintaining optical performance of MAPbBr<sub&...

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Main Authors: Siyu Dong, Cheng Zhang, Yuxiang Zhou, Xiaona Miao, Tiantian Zong, Manna Gu, Zijun Zhan, Duo Chen, Hong Ma, Weiling Gui, Jie Liu, Chen Cheng, Chuanfu Cheng
Format: Article
Language:English
Published: MDPI AG 2021-06-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/11/7/1648
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author Siyu Dong
Cheng Zhang
Yuxiang Zhou
Xiaona Miao
Tiantian Zong
Manna Gu
Zijun Zhan
Duo Chen
Hong Ma
Weiling Gui
Jie Liu
Chen Cheng
Chuanfu Cheng
author_facet Siyu Dong
Cheng Zhang
Yuxiang Zhou
Xiaona Miao
Tiantian Zong
Manna Gu
Zijun Zhan
Duo Chen
Hong Ma
Weiling Gui
Jie Liu
Chen Cheng
Chuanfu Cheng
author_sort Siyu Dong
collection DOAJ
description Hybrid organic-inorganic perovskite shows a great potential in the field of photoelectrics. Embedding methyl ammonium lead bromide (MAPbBr<sub>3</sub>) in a mesoporous silica (mSiO<sub>2</sub>) layer is an effective method for maintaining optical performance of MAPbBr<sub>3</sub> at room temperature. In this work, we synthesized MAPbBr<sub>3</sub> quantum dots, embedding them in the mSiO<sub>2</sub> layer. The nonlinear optical responses of this composite thin film have been investigated by using the Z-scan technique at a wavelength of 800 nm. The results show plural nonlinear responses in different intensities, corresponding to one- and two-photon processing. Our results support that composites possess saturation intensity of ~27.29 GW/cm<sup>2</sup> and varying nonlinear coefficients. The composite thin films show high stability under ultrafast laser irradiating. By employing the composite as a saturable absorber, a passively Q-switching laser has been achieved on a Nd:YVO<sub>4</sub> all-solid-state laser platform to generate a laser at ~1 μm.
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spelling doaj.art-1bc8479de413436ea72f4239c370b83d2023-11-22T01:21:28ZengMDPI AGNanomaterials2079-49912021-06-01117164810.3390/nano11071648High-Stability Hybrid Organic-Inorganic Perovskite (CH<sub>3</sub>NH<sub>3</sub>PbBr<sub>3</sub>) in SiO<sub>2</sub> Mesopores: Nonlinear Optics and Applications for Q-Switching Laser OperationSiyu Dong0Cheng Zhang1Yuxiang Zhou2Xiaona Miao3Tiantian Zong4Manna Gu5Zijun Zhan6Duo Chen7Hong Ma8Weiling Gui9Jie Liu10Chen Cheng11Chuanfu Cheng12College of Physics and Electronics, Shandong Normal University, Jinan 250014, ChinaCollege of Physics and Electronics, Shandong Normal University, Jinan 250014, ChinaCollege of Physics and Electronics, Shandong Normal University, Jinan 250014, ChinaCollege of Physics and Electronics, Shandong Normal University, Jinan 250014, ChinaCollege of Physics and Electronics, Shandong Normal University, Jinan 250014, ChinaCollege of Physics and Electronics, Shandong Normal University, Jinan 250014, ChinaCollege of Physics and Electronics, Shandong Normal University, Jinan 250014, ChinaInternational School for Optoelectronic Engineering, Qilu University of Technology (Shandong Academy of Science), Jinan 250353, ChinaCollege of Physics and Electronics, Shandong Normal University, Jinan 250014, ChinaCollege of Physics and Electronics, Shandong Normal University, Jinan 250014, ChinaCollege of Physics and Electronics, Shandong Normal University, Jinan 250014, ChinaCollege of Physics and Electronics, Shandong Normal University, Jinan 250014, ChinaCollege of Physics and Electronics, Shandong Normal University, Jinan 250014, ChinaHybrid organic-inorganic perovskite shows a great potential in the field of photoelectrics. Embedding methyl ammonium lead bromide (MAPbBr<sub>3</sub>) in a mesoporous silica (mSiO<sub>2</sub>) layer is an effective method for maintaining optical performance of MAPbBr<sub>3</sub> at room temperature. In this work, we synthesized MAPbBr<sub>3</sub> quantum dots, embedding them in the mSiO<sub>2</sub> layer. The nonlinear optical responses of this composite thin film have been investigated by using the Z-scan technique at a wavelength of 800 nm. The results show plural nonlinear responses in different intensities, corresponding to one- and two-photon processing. Our results support that composites possess saturation intensity of ~27.29 GW/cm<sup>2</sup> and varying nonlinear coefficients. The composite thin films show high stability under ultrafast laser irradiating. By employing the composite as a saturable absorber, a passively Q-switching laser has been achieved on a Nd:YVO<sub>4</sub> all-solid-state laser platform to generate a laser at ~1 μm.https://www.mdpi.com/2079-4991/11/7/1648perovskitemesostructureoptical nonlinearQ-switched laser
spellingShingle Siyu Dong
Cheng Zhang
Yuxiang Zhou
Xiaona Miao
Tiantian Zong
Manna Gu
Zijun Zhan
Duo Chen
Hong Ma
Weiling Gui
Jie Liu
Chen Cheng
Chuanfu Cheng
High-Stability Hybrid Organic-Inorganic Perovskite (CH<sub>3</sub>NH<sub>3</sub>PbBr<sub>3</sub>) in SiO<sub>2</sub> Mesopores: Nonlinear Optics and Applications for Q-Switching Laser Operation
Nanomaterials
perovskite
mesostructure
optical nonlinear
Q-switched laser
title High-Stability Hybrid Organic-Inorganic Perovskite (CH<sub>3</sub>NH<sub>3</sub>PbBr<sub>3</sub>) in SiO<sub>2</sub> Mesopores: Nonlinear Optics and Applications for Q-Switching Laser Operation
title_full High-Stability Hybrid Organic-Inorganic Perovskite (CH<sub>3</sub>NH<sub>3</sub>PbBr<sub>3</sub>) in SiO<sub>2</sub> Mesopores: Nonlinear Optics and Applications for Q-Switching Laser Operation
title_fullStr High-Stability Hybrid Organic-Inorganic Perovskite (CH<sub>3</sub>NH<sub>3</sub>PbBr<sub>3</sub>) in SiO<sub>2</sub> Mesopores: Nonlinear Optics and Applications for Q-Switching Laser Operation
title_full_unstemmed High-Stability Hybrid Organic-Inorganic Perovskite (CH<sub>3</sub>NH<sub>3</sub>PbBr<sub>3</sub>) in SiO<sub>2</sub> Mesopores: Nonlinear Optics and Applications for Q-Switching Laser Operation
title_short High-Stability Hybrid Organic-Inorganic Perovskite (CH<sub>3</sub>NH<sub>3</sub>PbBr<sub>3</sub>) in SiO<sub>2</sub> Mesopores: Nonlinear Optics and Applications for Q-Switching Laser Operation
title_sort high stability hybrid organic inorganic perovskite ch sub 3 sub nh sub 3 sub pbbr sub 3 sub in sio sub 2 sub mesopores nonlinear optics and applications for q switching laser operation
topic perovskite
mesostructure
optical nonlinear
Q-switched laser
url https://www.mdpi.com/2079-4991/11/7/1648
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