Poly[tetrakis(selenocyanato-κN)bis(methanol-κO)tris(μ-pyrimidine-κ2N:N′)dicobalt(II)]
In the title compound, [Co2(NCSe)4(C4H4N2)3(CH3OH)2]n, the CoII ion is coordinated by three N-bonded pyrimidine ligands, two N-bonded selenocyanate anions and one O-bonded methanol molecule in an octahedral coordination mode. The asymmetric unit consists of one CoII ion, one pyrimidine ligand, two s...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681002060X |
| Summary: | In the title compound, [Co2(NCSe)4(C4H4N2)3(CH3OH)2]n, the CoII ion is coordinated by three N-bonded pyrimidine ligands, two N-bonded selenocyanate anions and one O-bonded methanol molecule in an octahedral coordination mode. The asymmetric unit consists of one CoII ion, one pyrimidine ligand, two selenocyanate anions and one methanol molecule in general positions as well as one pyrimidine ligand located around a twofold rotation axis. In the crystal structure, the pyrimidine ligands bridge [Co(CNSe)2(CH3OH)] units into zigzag-like chains, which are further connected by pyrimidine ligands into layers parallel to (010). |
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| ISSN: | 1600-5368 |