Nanocomposites Based on PCL and Halloysite Nanotubes Filled with Lysozyme: Effect of Draw Ratio on the Physical Properties and Release Analysis

Halloysite nanotubes (HNTs) were loaded with lsozyme, as antimicrobial molecule, at a HNTs/lysozyme ratio of 1:1. Such a nano-hybrid was incorporated into a poly (ε-caprolactone) (PCL) matrix at 10 wt % and films were obtained. The nano-composites were submitted to a cold drawn process at three diff...

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Main Authors: Valeria Bugatti, Gianluca Viscusi, Carlo Naddeo, Giuliana Gorrasi
Format: Article
Language:English
Published: MDPI AG 2017-08-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/7/8/213
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author Valeria Bugatti
Gianluca Viscusi
Carlo Naddeo
Giuliana Gorrasi
author_facet Valeria Bugatti
Gianluca Viscusi
Carlo Naddeo
Giuliana Gorrasi
author_sort Valeria Bugatti
collection DOAJ
description Halloysite nanotubes (HNTs) were loaded with lsozyme, as antimicrobial molecule, at a HNTs/lysozyme ratio of 1:1. Such a nano-hybrid was incorporated into a poly (ε-caprolactone) (PCL) matrix at 10 wt % and films were obtained. The nano-composites were submitted to a cold drawn process at three different draw ratios, λ = 3, 4, and 5, where λ is l(final length)/l0(initial length). Morphology, physical, and barrier properties of the starting nanocomposite and drawn samples were studied, and correlated to the release of the lysozyme molecule. It was demonstrated that with a simple mechanical treatment it is possible to obtain controlled release systems for specific active packaging requirements.
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spelling doaj.art-1bd46d43270742b0a2f5e5b14d377d582022-12-22T03:15:57ZengMDPI AGNanomaterials2079-49912017-08-017821310.3390/nano7080213nano7080213Nanocomposites Based on PCL and Halloysite Nanotubes Filled with Lysozyme: Effect of Draw Ratio on the Physical Properties and Release AnalysisValeria Bugatti0Gianluca Viscusi1Carlo Naddeo2Giuliana Gorrasi3Department of Industrial Engineering, University of Salerno, Via Giovanni Paolo II, 132, 84084 Fisciano (Salerno), ItalyDepartment of Industrial Engineering, University of Salerno, Via Giovanni Paolo II, 132, 84084 Fisciano (Salerno), ItalyDepartment of Industrial Engineering, University of Salerno, Via Giovanni Paolo II, 132, 84084 Fisciano (Salerno), ItalyDepartment of Industrial Engineering, University of Salerno, Via Giovanni Paolo II, 132, 84084 Fisciano (Salerno), ItalyHalloysite nanotubes (HNTs) were loaded with lsozyme, as antimicrobial molecule, at a HNTs/lysozyme ratio of 1:1. Such a nano-hybrid was incorporated into a poly (ε-caprolactone) (PCL) matrix at 10 wt % and films were obtained. The nano-composites were submitted to a cold drawn process at three different draw ratios, λ = 3, 4, and 5, where λ is l(final length)/l0(initial length). Morphology, physical, and barrier properties of the starting nanocomposite and drawn samples were studied, and correlated to the release of the lysozyme molecule. It was demonstrated that with a simple mechanical treatment it is possible to obtain controlled release systems for specific active packaging requirements.https://www.mdpi.com/2079-4991/7/8/213halloysite nanotubesPCLlysozymecontrolled releaseactive packaging
spellingShingle Valeria Bugatti
Gianluca Viscusi
Carlo Naddeo
Giuliana Gorrasi
Nanocomposites Based on PCL and Halloysite Nanotubes Filled with Lysozyme: Effect of Draw Ratio on the Physical Properties and Release Analysis
Nanomaterials
halloysite nanotubes
PCL
lysozyme
controlled release
active packaging
title Nanocomposites Based on PCL and Halloysite Nanotubes Filled with Lysozyme: Effect of Draw Ratio on the Physical Properties and Release Analysis
title_full Nanocomposites Based on PCL and Halloysite Nanotubes Filled with Lysozyme: Effect of Draw Ratio on the Physical Properties and Release Analysis
title_fullStr Nanocomposites Based on PCL and Halloysite Nanotubes Filled with Lysozyme: Effect of Draw Ratio on the Physical Properties and Release Analysis
title_full_unstemmed Nanocomposites Based on PCL and Halloysite Nanotubes Filled with Lysozyme: Effect of Draw Ratio on the Physical Properties and Release Analysis
title_short Nanocomposites Based on PCL and Halloysite Nanotubes Filled with Lysozyme: Effect of Draw Ratio on the Physical Properties and Release Analysis
title_sort nanocomposites based on pcl and halloysite nanotubes filled with lysozyme effect of draw ratio on the physical properties and release analysis
topic halloysite nanotubes
PCL
lysozyme
controlled release
active packaging
url https://www.mdpi.com/2079-4991/7/8/213
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AT gianlucaviscusi nanocompositesbasedonpclandhalloysitenanotubesfilledwithlysozymeeffectofdrawratioonthephysicalpropertiesandreleaseanalysis
AT carlonaddeo nanocompositesbasedonpclandhalloysitenanotubesfilledwithlysozymeeffectofdrawratioonthephysicalpropertiesandreleaseanalysis
AT giulianagorrasi nanocompositesbasedonpclandhalloysitenanotubesfilledwithlysozymeeffectofdrawratioonthephysicalpropertiesandreleaseanalysis