2-Amino-4-ferrocenylthiazole
The title compound, [Fe(C5H5)(C8H7N2S)], was synthesized by the direct reaction of acetylferrocene, thiourea and resublimed iodine. The structure shows one molecule in the asymmetric unit. The aminothiazole ring makes an angle of 14.53 (13)° with the ferrocenyl ring to which it is attached. In the c...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2022-08-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989022007228 |
| _version_ | 1811322458351861760 |
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| author | Bertin Anzaldo Pankaj Sharma Claudia. P. Villamizar Rene Gutierrez Perez Rubén A. Toscano |
| author_facet | Bertin Anzaldo Pankaj Sharma Claudia. P. Villamizar Rene Gutierrez Perez Rubén A. Toscano |
| author_sort | Bertin Anzaldo |
| collection | DOAJ |
| description | The title compound, [Fe(C5H5)(C8H7N2S)], was synthesized by the direct reaction of acetylferrocene, thiourea and resublimed iodine. The structure shows one molecule in the asymmetric unit. The aminothiazole ring makes an angle of 14.53 (13)° with the ferrocenyl ring to which it is attached. In the crystal, pairs of complex molecules interact via intermolecular N—H...N hydrogen bonds, forming a cyclic dimer which then interacts with other dimers through C—H...π interactions. |
| first_indexed | 2024-04-13T13:36:34Z |
| format | Article |
| id | doaj.art-1bf0ac2682784e47b2ecde4e93f50b8b |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-04-13T13:36:34Z |
| publishDate | 2022-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-1bf0ac2682784e47b2ecde4e93f50b8b2022-12-22T02:44:46ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902022-08-0178881882010.1107/S2056989022007228dj20462-Amino-4-ferrocenylthiazoleBertin Anzaldo0Pankaj Sharma1Claudia. P. Villamizar2Rene Gutierrez Perez3Rubén A. Toscano4Instituto de Química, Circuito Exterior Cd. Universitaria, PO Box 04510, Ciudad de México, MexicoInstituto de Química, Circuito Exterior Cd. Universitaria, PO Box 04510, Ciudad de México, MexicoInstituto de Química, Circuito Exterior Cd. Universitaria, PO Box 04510, Ciudad de México, MexicoLab. Síntesis de Complejos, Fac. Cs. Quím.-BUAP, Ciudad Universitaria, PO Box 156, Puebla, MexicoInstituto de Química, Circuito Exterior Cd. Universitaria, PO Box 04510, Ciudad de México, MexicoThe title compound, [Fe(C5H5)(C8H7N2S)], was synthesized by the direct reaction of acetylferrocene, thiourea and resublimed iodine. The structure shows one molecule in the asymmetric unit. The aminothiazole ring makes an angle of 14.53 (13)° with the ferrocenyl ring to which it is attached. In the crystal, pairs of complex molecules interact via intermolecular N—H...N hydrogen bonds, forming a cyclic dimer which then interacts with other dimers through C—H...π interactions.http://scripts.iucr.org/cgi-bin/paper?S2056989022007228crystal structureferrocenethiazoleaminothiazole |
| spellingShingle | Bertin Anzaldo Pankaj Sharma Claudia. P. Villamizar Rene Gutierrez Perez Rubén A. Toscano 2-Amino-4-ferrocenylthiazole Acta Crystallographica Section E: Crystallographic Communications crystal structure ferrocene thiazole aminothiazole |
| title | 2-Amino-4-ferrocenylthiazole |
| title_full | 2-Amino-4-ferrocenylthiazole |
| title_fullStr | 2-Amino-4-ferrocenylthiazole |
| title_full_unstemmed | 2-Amino-4-ferrocenylthiazole |
| title_short | 2-Amino-4-ferrocenylthiazole |
| title_sort | 2 amino 4 ferrocenylthiazole |
| topic | crystal structure ferrocene thiazole aminothiazole |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989022007228 |
| work_keys_str_mv | AT bertinanzaldo 2amino4ferrocenylthiazole AT pankajsharma 2amino4ferrocenylthiazole AT claudiapvillamizar 2amino4ferrocenylthiazole AT renegutierrezperez 2amino4ferrocenylthiazole AT rubenatoscano 2amino4ferrocenylthiazole |