Sintering Behavior, Thermal Expansion, and Environmental Impacts Accompanying Materials of the Al<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub> System Fabricated via Slip Casting

This work focuses on research on obtaining and characterizing Al<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub> materials formed via slip casting method. The main emphasis in the research was placed on environmental aspects and those related to the practical use of cera...

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Main Authors: Justyna Zygmuntowicz, Magdalena Gizowska, Justyna Tomaszewska, Paulina Piotrkiewicz, Radosław Żurowski, Marcin Wachowski, Katarzyna Konopka
Format: Article
Language:English
Published: MDPI AG 2021-06-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/14/12/3365
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author Justyna Zygmuntowicz
Magdalena Gizowska
Justyna Tomaszewska
Paulina Piotrkiewicz
Radosław Żurowski
Marcin Wachowski
Katarzyna Konopka
author_facet Justyna Zygmuntowicz
Magdalena Gizowska
Justyna Tomaszewska
Paulina Piotrkiewicz
Radosław Żurowski
Marcin Wachowski
Katarzyna Konopka
author_sort Justyna Zygmuntowicz
collection DOAJ
description This work focuses on research on obtaining and characterizing Al<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub> materials formed via slip casting method. The main emphasis in the research was placed on environmental aspects and those related to the practical use of ceramic materials. The goal was to analyze the environmental loads associated with the manufacturing of Al<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub> composites, as well as to determine the coefficient of thermal expansion of the obtained materials, classified as technical ceramics. This parameter is crucial in terms of their practical applications in high-temperature working conditions, e.g., as parts of industrial machines. The study reports on the four series of Al<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub> materials differing in the volume content of ZrO<sub>2</sub>. The sintering process was preceded by thermogravimetric measurements. The fabricated and sintered materials were characterized by dilatometric study, scanning electron microscopy, X-ray diffraction, and stereological analysis. Further, life cycle assessment was supplied. Based on dilatometric tests, it was observed that Al<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub> composites show a higher coefficient of thermal expansion than that resulting from the content of individual phases. The results of the life cycle analysis showed that the environmental loads (carbon footprint) resulting from the acquisition and processing of raw materials necessary for the production of sinters from Al<sub>2</sub>O<sub>3</sub> and ZrO<sub>2</sub> are comparable to those associated with the production of plastic products such as polypropylene or polyvinyl chloride.
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spelling doaj.art-1c054dc5fa6945f7b6f42e4f90656a842023-11-22T00:34:39ZengMDPI AGMaterials1996-19442021-06-011412336510.3390/ma14123365Sintering Behavior, Thermal Expansion, and Environmental Impacts Accompanying Materials of the Al<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub> System Fabricated via Slip CastingJustyna Zygmuntowicz0Magdalena Gizowska1Justyna Tomaszewska2Paulina Piotrkiewicz3Radosław Żurowski4Marcin Wachowski5Katarzyna Konopka6Faculty of Materials Science and Engineering, Warsaw University of Technology, 141 Woloska Street, 02-507 Warsaw, PolandResearch Group of Special Ceramic Materials, Division of Ceramic and Concrete in Warsaw, Łukasiewicz Research Network—Institute of Ceramics and Building Materials, 9 Postępu Street, 02-676 Warsaw, PolandInstytut Techniki Budowlanej, Ksawerów 21, 02-656 Warsaw, PolandFaculty of Materials Science and Engineering, Warsaw University of Technology, 141 Woloska Street, 02-507 Warsaw, PolandFaculty of Chemistry, Warsaw University of Technology, 3 Noakowskiego Street, 00-664 Warsaw, PolandFaculty of Mechanical Engineering, Military University of Technology, 2 Gen. S. Kaliskiego Street, 00-908 Warsaw, PolandFaculty of Materials Science and Engineering, Warsaw University of Technology, 141 Woloska Street, 02-507 Warsaw, PolandThis work focuses on research on obtaining and characterizing Al<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub> materials formed via slip casting method. The main emphasis in the research was placed on environmental aspects and those related to the practical use of ceramic materials. The goal was to analyze the environmental loads associated with the manufacturing of Al<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub> composites, as well as to determine the coefficient of thermal expansion of the obtained materials, classified as technical ceramics. This parameter is crucial in terms of their practical applications in high-temperature working conditions, e.g., as parts of industrial machines. The study reports on the four series of Al<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub> materials differing in the volume content of ZrO<sub>2</sub>. The sintering process was preceded by thermogravimetric measurements. The fabricated and sintered materials were characterized by dilatometric study, scanning electron microscopy, X-ray diffraction, and stereological analysis. Further, life cycle assessment was supplied. Based on dilatometric tests, it was observed that Al<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub> composites show a higher coefficient of thermal expansion than that resulting from the content of individual phases. The results of the life cycle analysis showed that the environmental loads (carbon footprint) resulting from the acquisition and processing of raw materials necessary for the production of sinters from Al<sub>2</sub>O<sub>3</sub> and ZrO<sub>2</sub> are comparable to those associated with the production of plastic products such as polypropylene or polyvinyl chloride.https://www.mdpi.com/1996-1944/14/12/3365Al<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub>thermal expansionsintering behaviorlife cycle analysisslip casting
spellingShingle Justyna Zygmuntowicz
Magdalena Gizowska
Justyna Tomaszewska
Paulina Piotrkiewicz
Radosław Żurowski
Marcin Wachowski
Katarzyna Konopka
Sintering Behavior, Thermal Expansion, and Environmental Impacts Accompanying Materials of the Al<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub> System Fabricated via Slip Casting
Materials
Al<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub>
thermal expansion
sintering behavior
life cycle analysis
slip casting
title Sintering Behavior, Thermal Expansion, and Environmental Impacts Accompanying Materials of the Al<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub> System Fabricated via Slip Casting
title_full Sintering Behavior, Thermal Expansion, and Environmental Impacts Accompanying Materials of the Al<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub> System Fabricated via Slip Casting
title_fullStr Sintering Behavior, Thermal Expansion, and Environmental Impacts Accompanying Materials of the Al<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub> System Fabricated via Slip Casting
title_full_unstemmed Sintering Behavior, Thermal Expansion, and Environmental Impacts Accompanying Materials of the Al<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub> System Fabricated via Slip Casting
title_short Sintering Behavior, Thermal Expansion, and Environmental Impacts Accompanying Materials of the Al<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub> System Fabricated via Slip Casting
title_sort sintering behavior thermal expansion and environmental impacts accompanying materials of the al sub 2 sub o sub 3 sub zro sub 2 sub system fabricated via slip casting
topic Al<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub>
thermal expansion
sintering behavior
life cycle analysis
slip casting
url https://www.mdpi.com/1996-1944/14/12/3365
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