Separation and Efficient Recovery of Lithium from Spent Lithium-Ion Batteries

The consumption of lithium has increased dramatically in recent years. This can be primarily attributed to its use in lithium-ion batteries for the operation of hybrid and electric vehicles. Due to its specific properties, lithium will also continue to be an indispensable key component for rechargea...

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Main Authors: Eva Gerold, Stefan Luidold, Helmut Antrekowitsch
Format: Article
Language:English
Published: MDPI AG 2021-07-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/11/7/1091
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author Eva Gerold
Stefan Luidold
Helmut Antrekowitsch
author_facet Eva Gerold
Stefan Luidold
Helmut Antrekowitsch
author_sort Eva Gerold
collection DOAJ
description The consumption of lithium has increased dramatically in recent years. This can be primarily attributed to its use in lithium-ion batteries for the operation of hybrid and electric vehicles. Due to its specific properties, lithium will also continue to be an indispensable key component for rechargeable batteries in the next decades. An average lithium-ion battery contains 5–7% of lithium. These values indicate that used rechargeable batteries are a high-quality raw material for lithium recovery. Currently, the feasibility and reasonability of the hydrometallurgical recycling of lithium from spent lithium-ion batteries is still a field of research. This work is intended to compare the classic method of the precipitation of lithium from synthetic and real pregnant leaching liquors gained from spent lithium-ion batteries with sodium carbonate (state of the art) with alternative precipitation agents such as sodium phosphate and potassium phosphate. Furthermore, the correlation of the obtained product to the used type of phosphate is comprised. In addition, the influence of the process temperature (room temperature to boiling point), as well as the stoichiometric factor of the precipitant, is investigated in order to finally enable a statement about an efficient process, its parameter and the main dependencies.
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spelling doaj.art-1c17be66b9c44337b3f35c7aa25fe4522023-11-22T04:23:38ZengMDPI AGMetals2075-47012021-07-01117109110.3390/met11071091Separation and Efficient Recovery of Lithium from Spent Lithium-Ion BatteriesEva Gerold0Stefan Luidold1Helmut Antrekowitsch2Chair of Nonferrous Metallurgy of Montuniversitaet Leoben, 8700 Leoben, AustriaChair of Nonferrous Metallurgy of Montuniversitaet Leoben, 8700 Leoben, AustriaChair of Nonferrous Metallurgy of Montuniversitaet Leoben, 8700 Leoben, AustriaThe consumption of lithium has increased dramatically in recent years. This can be primarily attributed to its use in lithium-ion batteries for the operation of hybrid and electric vehicles. Due to its specific properties, lithium will also continue to be an indispensable key component for rechargeable batteries in the next decades. An average lithium-ion battery contains 5–7% of lithium. These values indicate that used rechargeable batteries are a high-quality raw material for lithium recovery. Currently, the feasibility and reasonability of the hydrometallurgical recycling of lithium from spent lithium-ion batteries is still a field of research. This work is intended to compare the classic method of the precipitation of lithium from synthetic and real pregnant leaching liquors gained from spent lithium-ion batteries with sodium carbonate (state of the art) with alternative precipitation agents such as sodium phosphate and potassium phosphate. Furthermore, the correlation of the obtained product to the used type of phosphate is comprised. In addition, the influence of the process temperature (room temperature to boiling point), as well as the stoichiometric factor of the precipitant, is investigated in order to finally enable a statement about an efficient process, its parameter and the main dependencies.https://www.mdpi.com/2075-4701/11/7/1091recyclinglithium-ion batterieslithium recoveryprecipitationhydrometallurgycritical element
spellingShingle Eva Gerold
Stefan Luidold
Helmut Antrekowitsch
Separation and Efficient Recovery of Lithium from Spent Lithium-Ion Batteries
Metals
recycling
lithium-ion batteries
lithium recovery
precipitation
hydrometallurgy
critical element
title Separation and Efficient Recovery of Lithium from Spent Lithium-Ion Batteries
title_full Separation and Efficient Recovery of Lithium from Spent Lithium-Ion Batteries
title_fullStr Separation and Efficient Recovery of Lithium from Spent Lithium-Ion Batteries
title_full_unstemmed Separation and Efficient Recovery of Lithium from Spent Lithium-Ion Batteries
title_short Separation and Efficient Recovery of Lithium from Spent Lithium-Ion Batteries
title_sort separation and efficient recovery of lithium from spent lithium ion batteries
topic recycling
lithium-ion batteries
lithium recovery
precipitation
hydrometallurgy
critical element
url https://www.mdpi.com/2075-4701/11/7/1091
work_keys_str_mv AT evagerold separationandefficientrecoveryoflithiumfromspentlithiumionbatteries
AT stefanluidold separationandefficientrecoveryoflithiumfromspentlithiumionbatteries
AT helmutantrekowitsch separationandefficientrecoveryoflithiumfromspentlithiumionbatteries