Copper-Catalyzed Redox Coupling of Nitroarenes with Sodium Sulfinates
A simple copper-catalyzed redox coupling of sodium sulfinates and nitroarenes is described. In this process, abundant and stable nitroarenes serve as both the nitrogen sources and oxidants, and sodium sulfinates act as both reactants and reductants. A variety of aromatic sulfonamides were obtained i...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2019-04-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/24/7/1407 |
| _version_ | 1818008989954211840 |
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| author | Saiwen Liu Ru Chen Jin Zhang |
| author_facet | Saiwen Liu Ru Chen Jin Zhang |
| author_sort | Saiwen Liu |
| collection | DOAJ |
| description | A simple copper-catalyzed redox coupling of sodium sulfinates and nitroarenes is described. In this process, abundant and stable nitroarenes serve as both the nitrogen sources and oxidants, and sodium sulfinates act as both reactants and reductants. A variety of aromatic sulfonamides were obtained in moderate to good yields with broad substrate scope. No external additive is employed for this kind of transformation. |
| first_indexed | 2024-04-14T05:36:18Z |
| format | Article |
| id | doaj.art-1c1db5b462194fbdbe68b82ad6d9ff65 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-04-14T05:36:18Z |
| publishDate | 2019-04-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-1c1db5b462194fbdbe68b82ad6d9ff652022-12-22T02:09:37ZengMDPI AGMolecules1420-30492019-04-01247140710.3390/molecules24071407molecules24071407Copper-Catalyzed Redox Coupling of Nitroarenes with Sodium SulfinatesSaiwen Liu0Ru Chen1Jin Zhang2College of Materials and Chemical Engineering, Hunan City University, Yiyang 413000, ChinaYiyang Agriculture Products Quality Detect Center, Yiyang 413000, ChinaCollege of Materials and Chemical Engineering, Hunan City University, Yiyang 413000, ChinaA simple copper-catalyzed redox coupling of sodium sulfinates and nitroarenes is described. In this process, abundant and stable nitroarenes serve as both the nitrogen sources and oxidants, and sodium sulfinates act as both reactants and reductants. A variety of aromatic sulfonamides were obtained in moderate to good yields with broad substrate scope. No external additive is employed for this kind of transformation.https://www.mdpi.com/1420-3049/24/7/1407copperredoxadditive-free |
| spellingShingle | Saiwen Liu Ru Chen Jin Zhang Copper-Catalyzed Redox Coupling of Nitroarenes with Sodium Sulfinates Molecules copper redox additive-free |
| title | Copper-Catalyzed Redox Coupling of Nitroarenes with Sodium Sulfinates |
| title_full | Copper-Catalyzed Redox Coupling of Nitroarenes with Sodium Sulfinates |
| title_fullStr | Copper-Catalyzed Redox Coupling of Nitroarenes with Sodium Sulfinates |
| title_full_unstemmed | Copper-Catalyzed Redox Coupling of Nitroarenes with Sodium Sulfinates |
| title_short | Copper-Catalyzed Redox Coupling of Nitroarenes with Sodium Sulfinates |
| title_sort | copper catalyzed redox coupling of nitroarenes with sodium sulfinates |
| topic | copper redox additive-free |
| url | https://www.mdpi.com/1420-3049/24/7/1407 |
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