9-Vinyl-9<i>H</i>-carbazole-3,6-dicarbonitrile
Carbazole polymers attract significant attention as promising luminophores, organic electronic and photovoltaic materials, photo/electrocatalysts, energy storage materials, redox mediators and catalysts. However, the oxidation potential of the commercially available poly(vinylcarbazole) is insuffici...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2024-02-01
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| Series: | Molbank |
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| Online Access: | https://www.mdpi.com/1422-8599/2024/1/M1768 |
| _version_ | 1827305491338887168 |
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| author | Kristina Svetlova Alexander Kazantsev Oleg Levin Sofia Filippova Elena Alekseeva |
| author_facet | Kristina Svetlova Alexander Kazantsev Oleg Levin Sofia Filippova Elena Alekseeva |
| author_sort | Kristina Svetlova |
| collection | DOAJ |
| description | Carbazole polymers attract significant attention as promising luminophores, organic electronic and photovoltaic materials, photo/electrocatalysts, energy storage materials, redox mediators and catalysts. However, the oxidation potential of the commercially available poly(vinylcarbazole) is insufficient for some applications such as high-voltage Li-Ion batteries. We have proposed a monomer for the novel polycarbazole with an increased oxidation potential, which will be compatible with high-voltage cathode materials for Li-Ion. In addition, the proposed polymer is an interesting substrate for the further carbonization to obtain N-doped carbons with a high electrocatalytic activity level. |
| first_indexed | 2024-04-24T17:59:01Z |
| format | Article |
| id | doaj.art-1c1ee7ae4b054a5d924d0cc91bb1b3a3 |
| institution | Directory Open Access Journal |
| issn | 1422-8599 |
| language | English |
| last_indexed | 2024-04-24T17:59:01Z |
| publishDate | 2024-02-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj.art-1c1ee7ae4b054a5d924d0cc91bb1b3a32024-03-27T13:56:36ZengMDPI AGMolbank1422-85992024-02-0120241M176810.3390/M17689-Vinyl-9<i>H</i>-carbazole-3,6-dicarbonitrileKristina Svetlova0Alexander Kazantsev1Oleg Levin2Sofia Filippova3Elena Alekseeva4Institute of Chemistry, St. Petersburg University, 199034 St. Petersburg, RussiaInstitute of Chemistry, St. Petersburg University, 199034 St. Petersburg, RussiaInstitute of Chemistry, St. Petersburg University, 199034 St. Petersburg, RussiaInstitute of Chemistry, St. Petersburg University, 199034 St. Petersburg, RussiaInstitute of Chemistry, St. Petersburg University, 199034 St. Petersburg, RussiaCarbazole polymers attract significant attention as promising luminophores, organic electronic and photovoltaic materials, photo/electrocatalysts, energy storage materials, redox mediators and catalysts. However, the oxidation potential of the commercially available poly(vinylcarbazole) is insufficient for some applications such as high-voltage Li-Ion batteries. We have proposed a monomer for the novel polycarbazole with an increased oxidation potential, which will be compatible with high-voltage cathode materials for Li-Ion. In addition, the proposed polymer is an interesting substrate for the further carbonization to obtain N-doped carbons with a high electrocatalytic activity level.https://www.mdpi.com/1422-8599/2024/1/M1768carbazolevinylationone potcyanation |
| spellingShingle | Kristina Svetlova Alexander Kazantsev Oleg Levin Sofia Filippova Elena Alekseeva 9-Vinyl-9<i>H</i>-carbazole-3,6-dicarbonitrile Molbank carbazole vinylation one pot cyanation |
| title | 9-Vinyl-9<i>H</i>-carbazole-3,6-dicarbonitrile |
| title_full | 9-Vinyl-9<i>H</i>-carbazole-3,6-dicarbonitrile |
| title_fullStr | 9-Vinyl-9<i>H</i>-carbazole-3,6-dicarbonitrile |
| title_full_unstemmed | 9-Vinyl-9<i>H</i>-carbazole-3,6-dicarbonitrile |
| title_short | 9-Vinyl-9<i>H</i>-carbazole-3,6-dicarbonitrile |
| title_sort | 9 vinyl 9 i h i carbazole 3 6 dicarbonitrile |
| topic | carbazole vinylation one pot cyanation |
| url | https://www.mdpi.com/1422-8599/2024/1/M1768 |
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