Shell isolated nanoparticle enhanced Raman spectroscopy for mechanistic investigation of electrochemical reactions
Abstract Electrochemical conversion of abundant resources, such as carbon dioxide, water, nitrogen, and nitrate, is a remarkable strategy for replacing fossil fuel-based processes and achieving a sustainable energy future. Designing an efficient and selective electrocatalysis system for electrochemi...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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SpringerOpen
2022-02-01
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| Series: | Nano Convergence |
| Subjects: | |
| Online Access: | https://doi.org/10.1186/s40580-022-00301-1 |
| _version_ | 1819277339389853696 |
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| author | Andi Haryanto Chan Woo Lee |
| author_facet | Andi Haryanto Chan Woo Lee |
| author_sort | Andi Haryanto |
| collection | DOAJ |
| description | Abstract Electrochemical conversion of abundant resources, such as carbon dioxide, water, nitrogen, and nitrate, is a remarkable strategy for replacing fossil fuel-based processes and achieving a sustainable energy future. Designing an efficient and selective electrocatalysis system for electrochemical conversion reactions remains a challenge due to a lack of understanding of the reaction mechanism. Shell-isolated nanoparticle-enhanced Raman spectroscopy (SHINERS) is a promising strategy for experimentally unraveling a reaction pathway and rate-limiting step by detecting intermediate species and catalytically active sites that occur during the reaction regardless of substrate. In this review, we introduce the SHINERS principle and its historical developments. Furthermore, we discuss recent SHINERS applications and developments for investigating intermediate species involved in a variety of electrocatalytic reactions. |
| first_indexed | 2024-12-23T23:54:32Z |
| format | Article |
| id | doaj.art-1c2c3a7e2bf54e2b873e1e9f0b0ed6e0 |
| institution | Directory Open Access Journal |
| issn | 2196-5404 |
| language | English |
| last_indexed | 2024-12-23T23:54:32Z |
| publishDate | 2022-02-01 |
| publisher | SpringerOpen |
| record_format | Article |
| series | Nano Convergence |
| spelling | doaj.art-1c2c3a7e2bf54e2b873e1e9f0b0ed6e02022-12-21T17:25:17ZengSpringerOpenNano Convergence2196-54042022-02-019111410.1186/s40580-022-00301-1Shell isolated nanoparticle enhanced Raman spectroscopy for mechanistic investigation of electrochemical reactionsAndi Haryanto0Chan Woo Lee1Department of Chemistry, Kookmin UniversityDepartment of Chemistry, Kookmin UniversityAbstract Electrochemical conversion of abundant resources, such as carbon dioxide, water, nitrogen, and nitrate, is a remarkable strategy for replacing fossil fuel-based processes and achieving a sustainable energy future. Designing an efficient and selective electrocatalysis system for electrochemical conversion reactions remains a challenge due to a lack of understanding of the reaction mechanism. Shell-isolated nanoparticle-enhanced Raman spectroscopy (SHINERS) is a promising strategy for experimentally unraveling a reaction pathway and rate-limiting step by detecting intermediate species and catalytically active sites that occur during the reaction regardless of substrate. In this review, we introduce the SHINERS principle and its historical developments. Furthermore, we discuss recent SHINERS applications and developments for investigating intermediate species involved in a variety of electrocatalytic reactions.https://doi.org/10.1186/s40580-022-00301-1ElectrocatalysisIn situ spectroscopyRaman scatteringReaction mechanismsShell-isolated nanoparticle-enhanced Raman spectroscopy |
| spellingShingle | Andi Haryanto Chan Woo Lee Shell isolated nanoparticle enhanced Raman spectroscopy for mechanistic investigation of electrochemical reactions Nano Convergence Electrocatalysis In situ spectroscopy Raman scattering Reaction mechanisms Shell-isolated nanoparticle-enhanced Raman spectroscopy |
| title | Shell isolated nanoparticle enhanced Raman spectroscopy for mechanistic investigation of electrochemical reactions |
| title_full | Shell isolated nanoparticle enhanced Raman spectroscopy for mechanistic investigation of electrochemical reactions |
| title_fullStr | Shell isolated nanoparticle enhanced Raman spectroscopy for mechanistic investigation of electrochemical reactions |
| title_full_unstemmed | Shell isolated nanoparticle enhanced Raman spectroscopy for mechanistic investigation of electrochemical reactions |
| title_short | Shell isolated nanoparticle enhanced Raman spectroscopy for mechanistic investigation of electrochemical reactions |
| title_sort | shell isolated nanoparticle enhanced raman spectroscopy for mechanistic investigation of electrochemical reactions |
| topic | Electrocatalysis In situ spectroscopy Raman scattering Reaction mechanisms Shell-isolated nanoparticle-enhanced Raman spectroscopy |
| url | https://doi.org/10.1186/s40580-022-00301-1 |
| work_keys_str_mv | AT andiharyanto shellisolatednanoparticleenhancedramanspectroscopyformechanisticinvestigationofelectrochemicalreactions AT chanwoolee shellisolatednanoparticleenhancedramanspectroscopyformechanisticinvestigationofelectrochemicalreactions |