Downsizing Sustainable Aviation Fuel Production with Additive Manufacturing—An Experimental Study on a 3D printed Reactor for Fischer-Tropsch Synthesis

Sustainable aviation fuels (SAF) are needed in large quantities to reduce the negative impact of flying on the climate. So-called power-to-liquid (PtL) plants can produce SAF from renewable electricity, water, and carbon dioxide. Reactors for these processes that are suitable for flexible operation...

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Main Authors: David F. Metzger, Christoph Klahn, Roland Dittmeyer
Format: Article
Language:English
Published: MDPI AG 2023-09-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/16/19/6798
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author David F. Metzger
Christoph Klahn
Roland Dittmeyer
author_facet David F. Metzger
Christoph Klahn
Roland Dittmeyer
author_sort David F. Metzger
collection DOAJ
description Sustainable aviation fuels (SAF) are needed in large quantities to reduce the negative impact of flying on the climate. So-called power-to-liquid (PtL) plants can produce SAF from renewable electricity, water, and carbon dioxide. Reactors for these processes that are suitable for flexible operation are difficult to manufacture. Metal 3D printing, also known as additive manufacturing (AM), enables the fabrication of process equipment, such as chemical reactors, with highly optimized functions. In this publication, we present an AM reactor design and conduct experiments for Fischer-Tropsch synthesis (FTS) under challenging conditions. The design includes heating, cooling, and sensing, among others, and can be easily fabricated without welding. We confirm that our reactor has excellent temperature control and high productivity of FTS products up to 800 kg<sub>C5+</sub> m<sub>cat</sub><sup>−3</sup> h<sup>−1</sup> (mass flow rate of hydrocarbons, liquid or solid at ambient conditions, per catalyst volume). The typical space-time yield for conventional multi-tubular Fischer-Tropsch reactors is ~100 kg<sub>C5+</sub> m<sub>cat</sub><sup>−3</sup> h<sup>−1</sup>. The increased productivity is achieved by designing reactor structures in which the channels for catalyst and cooling/heating fluid are in the millimeter range. With the effective control of heat release, we observe neither the formation of hot spots nor catalyst deactivation.
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spelling doaj.art-1c2e954f81574616a5f0eeec81ee0a822023-11-19T14:19:05ZengMDPI AGEnergies1996-10732023-09-011619679810.3390/en16196798Downsizing Sustainable Aviation Fuel Production with Additive Manufacturing—An Experimental Study on a 3D printed Reactor for Fischer-Tropsch SynthesisDavid F. Metzger0Christoph Klahn1Roland Dittmeyer2Institute for Micro Process Engineering (IMVT), Karlsruhe Institute of Technology (KIT), Herrmann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, GermanyInstitute of Mechanical Process Engineering and Mechanics (MVM), Karlsruhe Institute of Technology (KIT), Strasse am Forum 8, 76131 Karlsruhe, GermanyInstitute for Micro Process Engineering (IMVT), Karlsruhe Institute of Technology (KIT), Herrmann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, GermanySustainable aviation fuels (SAF) are needed in large quantities to reduce the negative impact of flying on the climate. So-called power-to-liquid (PtL) plants can produce SAF from renewable electricity, water, and carbon dioxide. Reactors for these processes that are suitable for flexible operation are difficult to manufacture. Metal 3D printing, also known as additive manufacturing (AM), enables the fabrication of process equipment, such as chemical reactors, with highly optimized functions. In this publication, we present an AM reactor design and conduct experiments for Fischer-Tropsch synthesis (FTS) under challenging conditions. The design includes heating, cooling, and sensing, among others, and can be easily fabricated without welding. We confirm that our reactor has excellent temperature control and high productivity of FTS products up to 800 kg<sub>C5+</sub> m<sub>cat</sub><sup>−3</sup> h<sup>−1</sup> (mass flow rate of hydrocarbons, liquid or solid at ambient conditions, per catalyst volume). The typical space-time yield for conventional multi-tubular Fischer-Tropsch reactors is ~100 kg<sub>C5+</sub> m<sub>cat</sub><sup>−3</sup> h<sup>−1</sup>. The increased productivity is achieved by designing reactor structures in which the channels for catalyst and cooling/heating fluid are in the millimeter range. With the effective control of heat release, we observe neither the formation of hot spots nor catalyst deactivation.https://www.mdpi.com/1996-1073/16/19/6798power-to-liquidheterogeneous catalysiscompact reactoradditive manufacturingFischer-Tropsch synthesis
spellingShingle David F. Metzger
Christoph Klahn
Roland Dittmeyer
Downsizing Sustainable Aviation Fuel Production with Additive Manufacturing—An Experimental Study on a 3D printed Reactor for Fischer-Tropsch Synthesis
Energies
power-to-liquid
heterogeneous catalysis
compact reactor
additive manufacturing
Fischer-Tropsch synthesis
title Downsizing Sustainable Aviation Fuel Production with Additive Manufacturing—An Experimental Study on a 3D printed Reactor for Fischer-Tropsch Synthesis
title_full Downsizing Sustainable Aviation Fuel Production with Additive Manufacturing—An Experimental Study on a 3D printed Reactor for Fischer-Tropsch Synthesis
title_fullStr Downsizing Sustainable Aviation Fuel Production with Additive Manufacturing—An Experimental Study on a 3D printed Reactor for Fischer-Tropsch Synthesis
title_full_unstemmed Downsizing Sustainable Aviation Fuel Production with Additive Manufacturing—An Experimental Study on a 3D printed Reactor for Fischer-Tropsch Synthesis
title_short Downsizing Sustainable Aviation Fuel Production with Additive Manufacturing—An Experimental Study on a 3D printed Reactor for Fischer-Tropsch Synthesis
title_sort downsizing sustainable aviation fuel production with additive manufacturing an experimental study on a 3d printed reactor for fischer tropsch synthesis
topic power-to-liquid
heterogeneous catalysis
compact reactor
additive manufacturing
Fischer-Tropsch synthesis
url https://www.mdpi.com/1996-1073/16/19/6798
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AT rolanddittmeyer downsizingsustainableaviationfuelproductionwithadditivemanufacturinganexperimentalstudyona3dprintedreactorforfischertropschsynthesis