Halide Pb-Free Double–Perovskites: Ternary vs. Quaternary Stoichiometry
In view of their applicability in optoelectronics, we review here the relevant structural, electronic, and optical features of the inorganic Pb-free halide perovskite class. In particular, after discussing the reasons that have motivated their introduction in opposition to their more widely investig...
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| Format: | Article |
| Language: | English |
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MDPI AG
2020-07-01
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| Series: | Energies |
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| Online Access: | https://www.mdpi.com/1996-1073/13/14/3516 |
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| author | Maurizia Palummo Daniele Varsano Eduardo Berríos Koichi Yamashita Giacomo Giorgi |
| author_facet | Maurizia Palummo Daniele Varsano Eduardo Berríos Koichi Yamashita Giacomo Giorgi |
| author_sort | Maurizia Palummo |
| collection | DOAJ |
| description | In view of their applicability in optoelectronics, we review here the relevant structural, electronic, and optical features of the inorganic Pb-free halide perovskite class. In particular, after discussing the reasons that have motivated their introduction in opposition to their more widely investigated organic-inorganic counterparts, we highlight milestones already achieved in their synthesis and characterization and show how the use of ab initio ground and excited state methods is relevant in predicting their properties and in disclosing yet unsolved issues which characterize both ternary and quaternary stoichiometry double-perovskites. |
| first_indexed | 2024-03-10T18:37:13Z |
| format | Article |
| id | doaj.art-1c3ebcf66bbe4ff39709445bf4123bd5 |
| institution | Directory Open Access Journal |
| issn | 1996-1073 |
| language | English |
| last_indexed | 2024-03-10T18:37:13Z |
| publishDate | 2020-07-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Energies |
| spelling | doaj.art-1c3ebcf66bbe4ff39709445bf4123bd52023-11-20T06:09:12ZengMDPI AGEnergies1996-10732020-07-011314351610.3390/en13143516Halide Pb-Free Double–Perovskites: Ternary vs. Quaternary StoichiometryMaurizia Palummo0Daniele Varsano1Eduardo Berríos2Koichi Yamashita3Giacomo Giorgi4Dipartimento di Fisica and INFN, Universitá di Roma “Tor Vergata”, Via della Ricerca Scientifica 1, 00133 Roma, ItalyCentro S3, Istituto Nanoscienze-Consiglio Nazionale delle Ricerche (CNR-NANO), Via Campi 213/A, 41125 Modena, ItalyInstituto de Química y Bioquímica, Facultad de Ciencias, Universidad de Valparaíso, Avenida Gran Bretaña, 1111 Playa Ancha, Valparaíso 2360102, ChileElement Strategy Initiative for Catalysts and Batteries (ESICB), Kyoto University, Nishikyo-ku, Kyoto 615-8245, Japan Department of Civil and Environmental Engineering, University of Perugia (DICA), Via G. Duranti, 93, 06125 Perugia, ItalyIn view of their applicability in optoelectronics, we review here the relevant structural, electronic, and optical features of the inorganic Pb-free halide perovskite class. In particular, after discussing the reasons that have motivated their introduction in opposition to their more widely investigated organic-inorganic counterparts, we highlight milestones already achieved in their synthesis and characterization and show how the use of ab initio ground and excited state methods is relevant in predicting their properties and in disclosing yet unsolved issues which characterize both ternary and quaternary stoichiometry double-perovskites.https://www.mdpi.com/1996-1073/13/14/3516lead-free inorganic halide perovskites<i>ab-initio</i> ground and excited state analysisphotovoltaicsoptoelectronic applications |
| spellingShingle | Maurizia Palummo Daniele Varsano Eduardo Berríos Koichi Yamashita Giacomo Giorgi Halide Pb-Free Double–Perovskites: Ternary vs. Quaternary Stoichiometry Energies lead-free inorganic halide perovskites <i>ab-initio</i> ground and excited state analysis photovoltaics optoelectronic applications |
| title | Halide Pb-Free Double–Perovskites: Ternary vs. Quaternary Stoichiometry |
| title_full | Halide Pb-Free Double–Perovskites: Ternary vs. Quaternary Stoichiometry |
| title_fullStr | Halide Pb-Free Double–Perovskites: Ternary vs. Quaternary Stoichiometry |
| title_full_unstemmed | Halide Pb-Free Double–Perovskites: Ternary vs. Quaternary Stoichiometry |
| title_short | Halide Pb-Free Double–Perovskites: Ternary vs. Quaternary Stoichiometry |
| title_sort | halide pb free double perovskites ternary vs quaternary stoichiometry |
| topic | lead-free inorganic halide perovskites <i>ab-initio</i> ground and excited state analysis photovoltaics optoelectronic applications |
| url | https://www.mdpi.com/1996-1073/13/14/3516 |
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