Poly[dibromidobis[μ-1-(pyridin-4-ylmethyl)-1H-1,2,4-triazole-κ2N:N′]cadmium]
The title coordination polymer, [CdBr2(C8H8N4)2]n, arose from a layer-separated diffusion synthesis at room temperature. The title compound is isotypic with the I and Cl analogues. The Cd atom, located on an inversion center, is coordinated by two bromide ions and four N atoms (two from triazole rin...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-02-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811000535 |
| _version_ | 1818284748322111488 |
|---|---|
| author | Xiu-Zhi Xu Zhu-Lai Li Wen-Jin Yan Hui-Li Chi |
| author_facet | Xiu-Zhi Xu Zhu-Lai Li Wen-Jin Yan Hui-Li Chi |
| author_sort | Xiu-Zhi Xu |
| collection | DOAJ |
| description | The title coordination polymer, [CdBr2(C8H8N4)2]n, arose from a layer-separated diffusion synthesis at room temperature. The title compound is isotypic with the I and Cl analogues. The Cd atom, located on an inversion center, is coordinated by two bromide ions and four N atoms (two from triazole rings and two from pyridyl rings) in a distorted trans-CdBr2N4 octahedral arrangement. The bridging 1-(4-pyridylmethyl)-1H-1,2,4-triazole ligands are twisted [dihedral angle between the triazole and pyridine rings = 72.56 (13)°], affording a two-dimensional 44 sheet structure in the crystal. |
| first_indexed | 2024-12-13T00:57:44Z |
| format | Article |
| id | doaj.art-1c576d2e0f1a40dd85dbea2e78d75021 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T00:57:44Z |
| publishDate | 2011-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-1c576d2e0f1a40dd85dbea2e78d750212022-12-22T00:04:45ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-02-01672m190m19010.1107/S1600536811000535Poly[dibromidobis[μ-1-(pyridin-4-ylmethyl)-1H-1,2,4-triazole-κ2N:N′]cadmium]Xiu-Zhi XuZhu-Lai LiWen-Jin YanHui-Li ChiThe title coordination polymer, [CdBr2(C8H8N4)2]n, arose from a layer-separated diffusion synthesis at room temperature. The title compound is isotypic with the I and Cl analogues. The Cd atom, located on an inversion center, is coordinated by two bromide ions and four N atoms (two from triazole rings and two from pyridyl rings) in a distorted trans-CdBr2N4 octahedral arrangement. The bridging 1-(4-pyridylmethyl)-1H-1,2,4-triazole ligands are twisted [dihedral angle between the triazole and pyridine rings = 72.56 (13)°], affording a two-dimensional 44 sheet structure in the crystal.http://scripts.iucr.org/cgi-bin/paper?S1600536811000535 |
| spellingShingle | Xiu-Zhi Xu Zhu-Lai Li Wen-Jin Yan Hui-Li Chi Poly[dibromidobis[μ-1-(pyridin-4-ylmethyl)-1H-1,2,4-triazole-κ2N:N′]cadmium] Acta Crystallographica Section E |
| title | Poly[dibromidobis[μ-1-(pyridin-4-ylmethyl)-1H-1,2,4-triazole-κ2N:N′]cadmium] |
| title_full | Poly[dibromidobis[μ-1-(pyridin-4-ylmethyl)-1H-1,2,4-triazole-κ2N:N′]cadmium] |
| title_fullStr | Poly[dibromidobis[μ-1-(pyridin-4-ylmethyl)-1H-1,2,4-triazole-κ2N:N′]cadmium] |
| title_full_unstemmed | Poly[dibromidobis[μ-1-(pyridin-4-ylmethyl)-1H-1,2,4-triazole-κ2N:N′]cadmium] |
| title_short | Poly[dibromidobis[μ-1-(pyridin-4-ylmethyl)-1H-1,2,4-triazole-κ2N:N′]cadmium] |
| title_sort | poly dibromidobis amp 956 1 pyridin 4 ylmethyl 1h 1 2 4 triazole amp 954 2n n amp 8242 cadmium |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811000535 |
| work_keys_str_mv | AT xiuzhixu polydibromidobisamp9561pyridin4ylmethyl1h124triazoleamp9542nnamp8242cadmium AT zhulaili polydibromidobisamp9561pyridin4ylmethyl1h124triazoleamp9542nnamp8242cadmium AT wenjinyan polydibromidobisamp9561pyridin4ylmethyl1h124triazoleamp9542nnamp8242cadmium AT huilichi polydibromidobisamp9561pyridin4ylmethyl1h124triazoleamp9542nnamp8242cadmium |