Enhanced photocatalytic activity of wool-ball-like TiO2 microspheres on carbon fabric and FTO substrates

The wool-ball-like TiO2 microspheres on carbon fabric (TiO2-CF) and FTO substrates (TiO2-FTO) have been synthesized by a facile hydrothermal method in alkali environment, using commercial TiO2 (P25) as precursors. The XRD results indicate that the as-prepared TiO2 have good crystallinity. And the SE...

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Main Authors: Zhang Yu, Gu Jian, Zhang Mengqi
Format: Article
Language:English
Published: EDP Sciences 2018-01-01
Series:E3S Web of Conferences
Online Access:https://doi.org/10.1051/e3sconf/20183802014
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author Zhang Yu
Gu Jian
Zhang Mengqi
author_facet Zhang Yu
Gu Jian
Zhang Mengqi
author_sort Zhang Yu
collection DOAJ
description The wool-ball-like TiO2 microspheres on carbon fabric (TiO2-CF) and FTO substrates (TiO2-FTO) have been synthesized by a facile hydrothermal method in alkali environment, using commercial TiO2 (P25) as precursors. The XRD results indicate that the as-prepared TiO2 have good crystallinity. And the SEM images show that the wool-ball-like TiO2 microspheres with a diameter of 2-3 μm are composed of TiO2 nanowires, which have a diameter of ~50 nm. The photocatalytic behavior of the wool-ball-like TiO2 microspheres, TiO2-CF and TiO2-FTO under ultraviolet light was investigated by a pseudo first-order kinetic model, using methyl orange (MO) as pollutant. The wool-ball-like TiO2 microspheres obtained a degradation rate constant (Kap) of 6.91×10-3 min-1 . The Kap values of TiO2-FTO and TiO2-CF reach 13.97×10-3 min-1 and 11.80×10-3 min-1, which are 2.0 and 1.7 times higher than that of pristine wool-ball-like TiO2 microspheres due to the “sum effect” between TiO2 and substrates. This study offers a facile hydrothermal method to prepare wool-ball-like TiO2 microspheres on CF and FTO substrates, which will improve the recyclability of phtocatalysts and can be extended to other fields.
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spelling doaj.art-1c6f560eecbd4ed3a0e67b2c9699e11e2022-12-21T21:26:58ZengEDP SciencesE3S Web of Conferences2267-12422018-01-01380201410.1051/e3sconf/20183802014e3sconf_icemee2018_02014Enhanced photocatalytic activity of wool-ball-like TiO2 microspheres on carbon fabric and FTO substratesZhang YuGu JianZhang MengqiThe wool-ball-like TiO2 microspheres on carbon fabric (TiO2-CF) and FTO substrates (TiO2-FTO) have been synthesized by a facile hydrothermal method in alkali environment, using commercial TiO2 (P25) as precursors. The XRD results indicate that the as-prepared TiO2 have good crystallinity. And the SEM images show that the wool-ball-like TiO2 microspheres with a diameter of 2-3 μm are composed of TiO2 nanowires, which have a diameter of ~50 nm. The photocatalytic behavior of the wool-ball-like TiO2 microspheres, TiO2-CF and TiO2-FTO under ultraviolet light was investigated by a pseudo first-order kinetic model, using methyl orange (MO) as pollutant. The wool-ball-like TiO2 microspheres obtained a degradation rate constant (Kap) of 6.91×10-3 min-1 . The Kap values of TiO2-FTO and TiO2-CF reach 13.97×10-3 min-1 and 11.80×10-3 min-1, which are 2.0 and 1.7 times higher than that of pristine wool-ball-like TiO2 microspheres due to the “sum effect” between TiO2 and substrates. This study offers a facile hydrothermal method to prepare wool-ball-like TiO2 microspheres on CF and FTO substrates, which will improve the recyclability of phtocatalysts and can be extended to other fields.https://doi.org/10.1051/e3sconf/20183802014
spellingShingle Zhang Yu
Gu Jian
Zhang Mengqi
Enhanced photocatalytic activity of wool-ball-like TiO2 microspheres on carbon fabric and FTO substrates
E3S Web of Conferences
title Enhanced photocatalytic activity of wool-ball-like TiO2 microspheres on carbon fabric and FTO substrates
title_full Enhanced photocatalytic activity of wool-ball-like TiO2 microspheres on carbon fabric and FTO substrates
title_fullStr Enhanced photocatalytic activity of wool-ball-like TiO2 microspheres on carbon fabric and FTO substrates
title_full_unstemmed Enhanced photocatalytic activity of wool-ball-like TiO2 microspheres on carbon fabric and FTO substrates
title_short Enhanced photocatalytic activity of wool-ball-like TiO2 microspheres on carbon fabric and FTO substrates
title_sort enhanced photocatalytic activity of wool ball like tio2 microspheres on carbon fabric and fto substrates
url https://doi.org/10.1051/e3sconf/20183802014
work_keys_str_mv AT zhangyu enhancedphotocatalyticactivityofwoolballliketio2microspheresoncarbonfabricandftosubstrates
AT gujian enhancedphotocatalyticactivityofwoolballliketio2microspheresoncarbonfabricandftosubstrates
AT zhangmengqi enhancedphotocatalyticactivityofwoolballliketio2microspheresoncarbonfabricandftosubstrates