Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol–yne reaction
Herein we report the syntheses of two porous hyper-crosslinked polymers (HCPs) via thiol–yne reaction with rigid tetrahedral and pseudo-octahedral core structures. Sorption measurements with nitrogen gas at 77 K revealed BET-surface areas up to 650 m²/g. Those networks also showed a high thermal sta...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Beilstein-Institut
2016-11-01
|
| Series: | Beilstein Journal of Organic Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.3762/bjoc.12.252 |
| _version_ | 1818954353041473536 |
|---|---|
| author | Mathias Lang Alexandra Schade Stefan Bräse |
| author_facet | Mathias Lang Alexandra Schade Stefan Bräse |
| author_sort | Mathias Lang |
| collection | DOAJ |
| description | Herein we report the syntheses of two porous hyper-crosslinked polymers (HCPs) via thiol–yne reaction with rigid tetrahedral and pseudo-octahedral core structures. Sorption measurements with nitrogen gas at 77 K revealed BET-surface areas up to 650 m²/g. Those networks also showed a high thermal stability as well as insolubility in common organic solvents. |
| first_indexed | 2024-12-20T10:20:49Z |
| format | Article |
| id | doaj.art-1c8381f106d54e748d1bc4c9f24e4dbf |
| institution | Directory Open Access Journal |
| issn | 1860-5397 |
| language | English |
| last_indexed | 2024-12-20T10:20:49Z |
| publishDate | 2016-11-01 |
| publisher | Beilstein-Institut |
| record_format | Article |
| series | Beilstein Journal of Organic Chemistry |
| spelling | doaj.art-1c8381f106d54e748d1bc4c9f24e4dbf2022-12-21T19:43:56ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972016-11-011212570257610.3762/bjoc.12.2521860-5397-12-252Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol–yne reactionMathias Lang0Alexandra Schade1Stefan Bräse2Institute of Organic Chemistry, Karlsruhe Institute of Technology – Campus South, Fritz-Haber-Weg 6, 76131 Karlsruhe, GermanyInstitute of Organic Chemistry, Karlsruhe Institute of Technology – Campus South, Fritz-Haber-Weg 6, 76131 Karlsruhe, GermanyInstitute of Organic Chemistry, Karlsruhe Institute of Technology – Campus South, Fritz-Haber-Weg 6, 76131 Karlsruhe, GermanyHerein we report the syntheses of two porous hyper-crosslinked polymers (HCPs) via thiol–yne reaction with rigid tetrahedral and pseudo-octahedral core structures. Sorption measurements with nitrogen gas at 77 K revealed BET-surface areas up to 650 m²/g. Those networks also showed a high thermal stability as well as insolubility in common organic solvents.https://doi.org/10.3762/bjoc.12.252three-dimensionalporous hyper-crosslinked polymersthiol–yne |
| spellingShingle | Mathias Lang Alexandra Schade Stefan Bräse Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol–yne reaction Beilstein Journal of Organic Chemistry three-dimensional porous hyper-crosslinked polymers thiol–yne |
| title | Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol–yne reaction |
| title_full | Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol–yne reaction |
| title_fullStr | Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol–yne reaction |
| title_full_unstemmed | Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol–yne reaction |
| title_short | Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol–yne reaction |
| title_sort | synthesis of three dimensional porous hyper crosslinked polymers via thiol yne reaction |
| topic | three-dimensional porous hyper-crosslinked polymers thiol–yne |
| url | https://doi.org/10.3762/bjoc.12.252 |
| work_keys_str_mv | AT mathiaslang synthesisofthreedimensionalporoushypercrosslinkedpolymersviathiolynereaction AT alexandraschade synthesisofthreedimensionalporoushypercrosslinkedpolymersviathiolynereaction AT stefanbrase synthesisofthreedimensionalporoushypercrosslinkedpolymersviathiolynereaction |