Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol–yne reaction

Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol–yne reaction

Herein we report the syntheses of two porous hyper-crosslinked polymers (HCPs) via thiol–yne reaction with rigid tetrahedral and pseudo-octahedral core structures. Sorption measurements with nitrogen gas at 77 K revealed BET-surface areas up to 650 m²/g. Those networks also showed a high thermal sta...

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Bibliographic Details
Main Authors: Mathias Lang, Alexandra Schade, Stefan Bräse
Format: Article
Language:English
Published: Beilstein-Institut 2016-11-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
three-dimensional
porous hyper-crosslinked polymers
thiol–yne
Online Access:https://doi.org/10.3762/bjoc.12.252

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