Towards Red Emissive Systems Based on Carbon Dots

Carbon dots (C-dots) represent an emerging class of nontoxic nanoemitters that show excitation wavelength-dependent photoluminescence (PL) with high quantum yield (QY) and minimal photobleaching. The vast majority of studies focus on C-dots that exhibit the strongest PL emissions in the blue/green r...

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Main Authors: Spyridon Gavalas, Antonios Kelarakis
Format: Article
Language:English
Published: MDPI AG 2021-08-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/11/8/2089
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author Spyridon Gavalas
Antonios Kelarakis
author_facet Spyridon Gavalas
Antonios Kelarakis
author_sort Spyridon Gavalas
collection DOAJ
description Carbon dots (C-dots) represent an emerging class of nontoxic nanoemitters that show excitation wavelength-dependent photoluminescence (PL) with high quantum yield (QY) and minimal photobleaching. The vast majority of studies focus on C-dots that exhibit the strongest PL emissions in the blue/green region of the spectrum, while longer wavelength emissions are ideal for applications such as bioimaging, photothermal and photodynamic therapy and light-emitting diodes. Effective strategies to modulate the PL emission of C-dot-based systems towards the red end of the spectrum rely on extensive conjugation of sp<sup>2</sup> domains, heteroatom doping, solvatochromism, surface functionalization and passivation. Those approaches are systematically presented in this review, while emphasis is given on important applications of red-emissive suspensions, nanopowders and polymer nanocomposites.
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spelling doaj.art-1c8468af69314ac9bd3fdc55772ec4be2023-11-22T09:00:21ZengMDPI AGNanomaterials2079-49912021-08-01118208910.3390/nano11082089Towards Red Emissive Systems Based on Carbon DotsSpyridon Gavalas0Antonios Kelarakis1UCLan Research Centre for Smart Materials, School of Natural Sciences, University of Central Lancashire, Preston PR1 2HE, UKUCLan Research Centre for Smart Materials, School of Natural Sciences, University of Central Lancashire, Preston PR1 2HE, UKCarbon dots (C-dots) represent an emerging class of nontoxic nanoemitters that show excitation wavelength-dependent photoluminescence (PL) with high quantum yield (QY) and minimal photobleaching. The vast majority of studies focus on C-dots that exhibit the strongest PL emissions in the blue/green region of the spectrum, while longer wavelength emissions are ideal for applications such as bioimaging, photothermal and photodynamic therapy and light-emitting diodes. Effective strategies to modulate the PL emission of C-dot-based systems towards the red end of the spectrum rely on extensive conjugation of sp<sup>2</sup> domains, heteroatom doping, solvatochromism, surface functionalization and passivation. Those approaches are systematically presented in this review, while emphasis is given on important applications of red-emissive suspensions, nanopowders and polymer nanocomposites.https://www.mdpi.com/2079-4991/11/8/2089fluorescencecarbon dotsred-emittingbioimaginglight-emitting diodes
spellingShingle Spyridon Gavalas
Antonios Kelarakis
Towards Red Emissive Systems Based on Carbon Dots
Nanomaterials
fluorescence
carbon dots
red-emitting
bioimaging
light-emitting diodes
title Towards Red Emissive Systems Based on Carbon Dots
title_full Towards Red Emissive Systems Based on Carbon Dots
title_fullStr Towards Red Emissive Systems Based on Carbon Dots
title_full_unstemmed Towards Red Emissive Systems Based on Carbon Dots
title_short Towards Red Emissive Systems Based on Carbon Dots
title_sort towards red emissive systems based on carbon dots
topic fluorescence
carbon dots
red-emitting
bioimaging
light-emitting diodes
url https://www.mdpi.com/2079-4991/11/8/2089
work_keys_str_mv AT spyridongavalas towardsredemissivesystemsbasedoncarbondots
AT antonioskelarakis towardsredemissivesystemsbasedoncarbondots