(E)-2-(4-Benzyloxy-2-hydroxybenzylidene)-N-methylhydrazinecarbothioamide
The molecule of the title compound, C16H17N3O2S, adopts an E conformation with respect to the azomethine C=N bond. The hydrazinecarbothioamide fragment is close to planar, with a largest deviation from the least-squares plane of 0.079 (2) Å for the hydrazide N atom. This fragment forms a dihedral an...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813034892 |
| _version_ | 1818083312471638016 |
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| author | N. R. Sajitha M. Sithambaresan M. R. Prathapachandra Kurup |
| author_facet | N. R. Sajitha M. Sithambaresan M. R. Prathapachandra Kurup |
| author_sort | N. R. Sajitha |
| collection | DOAJ |
| description | The molecule of the title compound, C16H17N3O2S, adopts an E conformation with respect to the azomethine C=N bond. The hydrazinecarbothioamide fragment is close to planar, with a largest deviation from the least-squares plane of 0.079 (2) Å for the hydrazide N atom. This fragment forms a dihedral angle of 9.43 (9)° with the central benzene ring. The benzene rings are inclined to one another by 67.55 (12)°. The molecular conformation is stabilized by an intramolecular O—H...N hydrogen bond involving the azomethine N atom. In the crystal, molecules are linked through weak N—H...S and N—H...O hydrogen bonds into double ribbons along [010]. The crystal packing also features C—H...π interactions. |
| first_indexed | 2024-12-10T19:36:00Z |
| format | Article |
| id | doaj.art-1ca5d0b2f0f948679a61152d683de279 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T19:36:00Z |
| publishDate | 2014-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-1ca5d0b2f0f948679a61152d683de2792022-12-22T01:36:07ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-02-01702o112o11310.1107/S1600536813034892yk2101(E)-2-(4-Benzyloxy-2-hydroxybenzylidene)-N-methylhydrazinecarbothioamideN. R. Sajitha0M. Sithambaresan1M. R. Prathapachandra Kurup2Department of Applied Chemistry, Cochin University of Science and Technology, Kochi 682 022, IndiaDepartment of Chemistry, Faculty of Science, Eastern University, Sri Lanka, Chenkalady, Sri LankaDepartment of Applied Chemistry, Cochin University of Science and Technology, Kochi 682 022, IndiaThe molecule of the title compound, C16H17N3O2S, adopts an E conformation with respect to the azomethine C=N bond. The hydrazinecarbothioamide fragment is close to planar, with a largest deviation from the least-squares plane of 0.079 (2) Å for the hydrazide N atom. This fragment forms a dihedral angle of 9.43 (9)° with the central benzene ring. The benzene rings are inclined to one another by 67.55 (12)°. The molecular conformation is stabilized by an intramolecular O—H...N hydrogen bond involving the azomethine N atom. In the crystal, molecules are linked through weak N—H...S and N—H...O hydrogen bonds into double ribbons along [010]. The crystal packing also features C—H...π interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536813034892 |
| spellingShingle | N. R. Sajitha M. Sithambaresan M. R. Prathapachandra Kurup (E)-2-(4-Benzyloxy-2-hydroxybenzylidene)-N-methylhydrazinecarbothioamide Acta Crystallographica Section E |
| title | (E)-2-(4-Benzyloxy-2-hydroxybenzylidene)-N-methylhydrazinecarbothioamide |
| title_full | (E)-2-(4-Benzyloxy-2-hydroxybenzylidene)-N-methylhydrazinecarbothioamide |
| title_fullStr | (E)-2-(4-Benzyloxy-2-hydroxybenzylidene)-N-methylhydrazinecarbothioamide |
| title_full_unstemmed | (E)-2-(4-Benzyloxy-2-hydroxybenzylidene)-N-methylhydrazinecarbothioamide |
| title_short | (E)-2-(4-Benzyloxy-2-hydroxybenzylidene)-N-methylhydrazinecarbothioamide |
| title_sort | e 2 4 benzyloxy 2 hydroxybenzylidene n methylhydrazinecarbothioamide |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813034892 |
| work_keys_str_mv | AT nrsajitha e24benzyloxy2hydroxybenzylidenenmethylhydrazinecarbothioamide AT msithambaresan e24benzyloxy2hydroxybenzylidenenmethylhydrazinecarbothioamide AT mrprathapachandrakurup e24benzyloxy2hydroxybenzylidenenmethylhydrazinecarbothioamide |