Synthesis and structure study of new manganese and indium based phosphate: (Ca,Ba)1.222Mn0.923In1.570(PO4)3
Phosphates are an important class of materials which are well-known due to their structural diversity and their important potential application in many fields of sciences. A member of this family, represented by transition metal phosphates, is in the forefront of important researchers. A new mangane...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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EDP Sciences
2018-01-01
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| Series: | MATEC Web of Conferences |
| Online Access: | https://doi.org/10.1051/matecconf/201814901085 |
| _version_ | 1829530574315847680 |
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| author | Benhsina Elhassan Assani Abderrazzak Saadi Mohamed El Ammari Lahcen |
| author_facet | Benhsina Elhassan Assani Abderrazzak Saadi Mohamed El Ammari Lahcen |
| author_sort | Benhsina Elhassan |
| collection | DOAJ |
| description | Phosphates are an important class of materials which are well-known due to their structural diversity and their important potential application in many fields of sciences. A member of this family, represented by transition metal phosphates, is in the forefront of important researchers. A new manganese and indium based phosphate is successfully isolated by means of solid state reaction. Its corresponding crystal structure is isotypic to the alluaudite and crystallizes in the monoclinic system with the space group C2/c and cell parameters a=12.4697(5)Å ; b=12.9365(5)Å ; c=6.5625(3)Å and β=115.603(1)°. The framework of this phosphate is built up on the basis of MnO6, InO6 and PO4 polyhedra. The InO6 octahedra are linked together via common edge, leading to the formation of In2O10 dimers. The In2O10 dimers share edge with MnO6 octahedra, generating chains along the [101] direction. The PO4 tetrahedra connect two chains giving arise to a three-dimensional framework with hexagonal tunnels where the barium and calcium are located. |
| first_indexed | 2024-12-16T18:06:58Z |
| format | Article |
| id | doaj.art-1cd930fc166e407683d0d6e7552f6ff5 |
| institution | Directory Open Access Journal |
| issn | 2261-236X |
| language | English |
| last_indexed | 2024-12-16T18:06:58Z |
| publishDate | 2018-01-01 |
| publisher | EDP Sciences |
| record_format | Article |
| series | MATEC Web of Conferences |
| spelling | doaj.art-1cd930fc166e407683d0d6e7552f6ff52022-12-21T22:21:53ZengEDP SciencesMATEC Web of Conferences2261-236X2018-01-011490108510.1051/matecconf/201814901085matecconf_cmss2018_01085Synthesis and structure study of new manganese and indium based phosphate: (Ca,Ba)1.222Mn0.923In1.570(PO4)3Benhsina ElhassanAssani AbderrazzakSaadi MohamedEl Ammari LahcenPhosphates are an important class of materials which are well-known due to their structural diversity and their important potential application in many fields of sciences. A member of this family, represented by transition metal phosphates, is in the forefront of important researchers. A new manganese and indium based phosphate is successfully isolated by means of solid state reaction. Its corresponding crystal structure is isotypic to the alluaudite and crystallizes in the monoclinic system with the space group C2/c and cell parameters a=12.4697(5)Å ; b=12.9365(5)Å ; c=6.5625(3)Å and β=115.603(1)°. The framework of this phosphate is built up on the basis of MnO6, InO6 and PO4 polyhedra. The InO6 octahedra are linked together via common edge, leading to the formation of In2O10 dimers. The In2O10 dimers share edge with MnO6 octahedra, generating chains along the [101] direction. The PO4 tetrahedra connect two chains giving arise to a three-dimensional framework with hexagonal tunnels where the barium and calcium are located.https://doi.org/10.1051/matecconf/201814901085 |
| spellingShingle | Benhsina Elhassan Assani Abderrazzak Saadi Mohamed El Ammari Lahcen Synthesis and structure study of new manganese and indium based phosphate: (Ca,Ba)1.222Mn0.923In1.570(PO4)3 MATEC Web of Conferences |
| title | Synthesis and structure study of new manganese and indium based phosphate: (Ca,Ba)1.222Mn0.923In1.570(PO4)3 |
| title_full | Synthesis and structure study of new manganese and indium based phosphate: (Ca,Ba)1.222Mn0.923In1.570(PO4)3 |
| title_fullStr | Synthesis and structure study of new manganese and indium based phosphate: (Ca,Ba)1.222Mn0.923In1.570(PO4)3 |
| title_full_unstemmed | Synthesis and structure study of new manganese and indium based phosphate: (Ca,Ba)1.222Mn0.923In1.570(PO4)3 |
| title_short | Synthesis and structure study of new manganese and indium based phosphate: (Ca,Ba)1.222Mn0.923In1.570(PO4)3 |
| title_sort | synthesis and structure study of new manganese and indium based phosphate ca ba 1 222mn0 923in1 570 po4 3 |
| url | https://doi.org/10.1051/matecconf/201814901085 |
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