Crystal structure of {μ-6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}(methanol)(nitrato)nickel(II)sodium
In the molecular structure of the title compound, [NaNi(C18H18N2O4)(NO3)(CH3OH)], the Ni2+ ion has a slightly distorted square-planar coordination environment defined by two N and two O atoms which belong to a Schiff base ligand, viz. 6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]d...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-11-01
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| Series: | Acta Crystallographica Section E |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681402159X |
| _version_ | 1828130464061194240 |
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| author | Olesia V. Moroz Viktor A. Trush Tatiana Yu. Sliva Irina S. Konovalova Vladimir M. Amirkhanov |
| author_facet | Olesia V. Moroz Viktor A. Trush Tatiana Yu. Sliva Irina S. Konovalova Vladimir M. Amirkhanov |
| author_sort | Olesia V. Moroz |
| collection | DOAJ |
| description | In the molecular structure of the title compound, [NaNi(C18H18N2O4)(NO3)(CH3OH)], the Ni2+ ion has a slightly distorted square-planar coordination environment defined by two N and two O atoms which belong to a Schiff base ligand, viz. 6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolate. Seven O atoms form the coordination environment of the Na+ ion: four from the Schiff base ligand, two from a bidentate chelating nitrate anion and one O atom from a coordinating methanol molecule. In the crystal, the bimetallic complexes are assembled into chains along the b-axis direction via weak C—H...O hydrogen-bond interactions. Neighbouring chains are in turn connected through bifurcated O—H...O hydrogen bonds that involve the coordinating methanol molecules and the nitrate anions, and through π–π stacking interactions between phenyl rings of neighbouring molecules. |
| first_indexed | 2024-04-11T16:33:22Z |
| format | Article |
| id | doaj.art-1ce4f2b5cc2c430f9e9baae37467c67a |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:33:22Z |
| publishDate | 2014-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-1ce4f2b5cc2c430f9e9baae37467c67a2022-12-22T04:13:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-11-01701130530810.1107/S160053681402159Xzl2599Crystal structure of {μ-6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}(methanol)(nitrato)nickel(II)sodiumOlesia V. Moroz0Viktor A. Trush1Tatiana Yu. Sliva2Irina S. Konovalova3Vladimir M. Amirkhanov4Taras Shevchenko National University of Kyiv, Department of Chemistry, 64/13 Volodymyrska Street, Kyiv 01601, UkraineTaras Shevchenko National University of Kyiv, Department of Chemistry, 64/13 Volodymyrska Street, Kyiv 01601, UkraineTaras Shevchenko National University of Kyiv, Department of Chemistry, 64/13 Volodymyrska Street, Kyiv 01601, UkraineSTC "Institute for Single Crystals", National Academy of Science of Ukraine, 60 Lenina Avenue, Kharkiv 61001, UkraineTaras Shevchenko National University of Kyiv, Department of Chemistry, 64/13 Volodymyrska Street, Kyiv 01601, UkraineIn the molecular structure of the title compound, [NaNi(C18H18N2O4)(NO3)(CH3OH)], the Ni2+ ion has a slightly distorted square-planar coordination environment defined by two N and two O atoms which belong to a Schiff base ligand, viz. 6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolate. Seven O atoms form the coordination environment of the Na+ ion: four from the Schiff base ligand, two from a bidentate chelating nitrate anion and one O atom from a coordinating methanol molecule. In the crystal, the bimetallic complexes are assembled into chains along the b-axis direction via weak C—H...O hydrogen-bond interactions. Neighbouring chains are in turn connected through bifurcated O—H...O hydrogen bonds that involve the coordinating methanol molecules and the nitrate anions, and through π–π stacking interactions between phenyl rings of neighbouring molecules.http://scripts.iucr.org/cgi-bin/paper?S160053681402159Xcrystal structurehydrogen bondsπ–π stackingNiII–Na heterometallic complexSchiff base |
| spellingShingle | Olesia V. Moroz Viktor A. Trush Tatiana Yu. Sliva Irina S. Konovalova Vladimir M. Amirkhanov Crystal structure of {μ-6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}(methanol)(nitrato)nickel(II)sodium Acta Crystallographica Section E crystal structure hydrogen bonds π–π stacking NiII–Na heterometallic complex Schiff base |
| title | Crystal structure of {μ-6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}(methanol)(nitrato)nickel(II)sodium |
| title_full | Crystal structure of {μ-6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}(methanol)(nitrato)nickel(II)sodium |
| title_fullStr | Crystal structure of {μ-6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}(methanol)(nitrato)nickel(II)sodium |
| title_full_unstemmed | Crystal structure of {μ-6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}(methanol)(nitrato)nickel(II)sodium |
| title_short | Crystal structure of {μ-6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}(methanol)(nitrato)nickel(II)sodium |
| title_sort | crystal structure of μ 6 6 dimethoxy 2 2 ethane 1 2 diylbis nitrilomethanylylidene diphenolato methanol nitrato nickel ii sodium |
| topic | crystal structure hydrogen bonds π–π stacking NiII–Na heterometallic complex Schiff base |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681402159X |
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