The Impact of Measurement Scale on the Univariate Statistics of K, Th, and U in the Earth Crust

Abstract The univariate statistics of Potassium (K), thorium (Th), and uranium (U) concentrations, in the Earth’s oceanic and continental crust are examined by different techniques. The frequency distributions of the concentrations of these elements in the oceanic crust are derived from a global cat...

Full description

Bibliographic Details
Main Authors: D. Baratoux, M. Fall, P.‐Y. Meslin, M. W. Jessell, O. Vanderhaeghe, J.‐F. Moyen, P. M. Ndiaye, K. Boamah, L. Baratoux, A.‐S. André‐Mayer
Format: Article
Language:English
Published: American Geophysical Union (AGU) 2021-09-01
Series:Earth and Space Science
Subjects:
Online Access:https://doi.org/10.1029/2021EA001786
_version_ 1811305190338330624
author D. Baratoux
M. Fall
P.‐Y. Meslin
M. W. Jessell
O. Vanderhaeghe
J.‐F. Moyen
P. M. Ndiaye
K. Boamah
L. Baratoux
A.‐S. André‐Mayer
author_facet D. Baratoux
M. Fall
P.‐Y. Meslin
M. W. Jessell
O. Vanderhaeghe
J.‐F. Moyen
P. M. Ndiaye
K. Boamah
L. Baratoux
A.‐S. André‐Mayer
author_sort D. Baratoux
collection DOAJ
description Abstract The univariate statistics of Potassium (K), thorium (Th), and uranium (U) concentrations, in the Earth’s oceanic and continental crust are examined by different techniques. The frequency distributions of the concentrations of these elements in the oceanic crust are derived from a global catalog of mid‐ocean ridge basalts. Their frequency distributions of concentrations in the continental crust are illustrated by the North Pilbara Craton, and the West Africa Craton. For these two cratons, the distributions of K, Th, and U derived from geochemical analyses of several thousand whole rock samples differ significantly from those derived from airborne radiometric surveys. The distributions from airborne surveys tends to be more symmetric with smaller standard deviations than the right‐skewed distributions inferred from whole rock geochemical analyses. Hypothetic causes of these differences include (a) bias in rock sampling or in airborne surveys, (b) the differences between the chemistry of superficial material and rocks, and (c) the differences in scales of measurements. The scale factor, viewed as consequence of the central limit theorem applied to K, Th, and U concentrations, appears to account for most of the observed differences in the distributions of K, Th, and U. It suggests that the three scales of auto‐correlation of K, Th, and U concentrations are of the same order of magnitude as the resolution of the airborne radiometric surveys (50–200 m). Concentrations of K, Th, and U are therefore generally heterogenous at smaller scales.
first_indexed 2024-04-13T08:22:03Z
format Article
id doaj.art-1ced2cc140af4d5a89726f3d7ff7f688
institution Directory Open Access Journal
issn 2333-5084
language English
last_indexed 2024-04-13T08:22:03Z
publishDate 2021-09-01
publisher American Geophysical Union (AGU)
record_format Article
series Earth and Space Science
spelling doaj.art-1ced2cc140af4d5a89726f3d7ff7f6882022-12-22T02:54:37ZengAmerican Geophysical Union (AGU)Earth and Space Science2333-50842021-09-0189n/an/a10.1029/2021EA001786The Impact of Measurement Scale on the Univariate Statistics of K, Th, and U in the Earth CrustD. Baratoux0M. Fall1P.‐Y. Meslin2M. W. Jessell3O. Vanderhaeghe4J.‐F. Moyen5P. M. Ndiaye6K. Boamah7L. Baratoux8A.‐S. André‐Mayer9Géosciences Environnement Toulouse University of Toulouse CNRS & IRD Toulouse FranceGeology Department University Cheikh Anta Diop Dakar SenegalInstitut de Recherche en Astrophysique et Planétologie University of Toulouse CNRS & IRD Toulouse FranceSchool of Earth Sciences Center for Exploration Targeting The University of Western Australia Crawley WA AustraliaGéosciences Environnement Toulouse University of Toulouse CNRS & IRD Toulouse FranceLGL‐TPE UJM‐UCLB‐ENSL‐CNRS Saint Etienne FranceGeology Department University Cheikh Anta Diop Dakar SenegalGeological Survey Department of Ghana Accra GhanaGéosciences Environnement Toulouse University of Toulouse CNRS & IRD Toulouse FranceGeoRessources Université de Lorraine CNRS Nancy FranceAbstract The univariate statistics of Potassium (K), thorium (Th), and uranium (U) concentrations, in the Earth’s oceanic and continental crust are examined by different techniques. The frequency distributions of the concentrations of these elements in the oceanic crust are derived from a global catalog of mid‐ocean ridge basalts. Their frequency distributions of concentrations in the continental crust are illustrated by the North Pilbara Craton, and the West Africa Craton. For these two cratons, the distributions of K, Th, and U derived from geochemical analyses of several thousand whole rock samples differ significantly from those derived from airborne radiometric surveys. The distributions from airborne surveys tends to be more symmetric with smaller standard deviations than the right‐skewed distributions inferred from whole rock geochemical analyses. Hypothetic causes of these differences include (a) bias in rock sampling or in airborne surveys, (b) the differences between the chemistry of superficial material and rocks, and (c) the differences in scales of measurements. The scale factor, viewed as consequence of the central limit theorem applied to K, Th, and U concentrations, appears to account for most of the observed differences in the distributions of K, Th, and U. It suggests that the three scales of auto‐correlation of K, Th, and U concentrations are of the same order of magnitude as the resolution of the airborne radiometric surveys (50–200 m). Concentrations of K, Th, and U are therefore generally heterogenous at smaller scales.https://doi.org/10.1029/2021EA001786potassiumuraniumthoriumgeostatisticsradiometrics
spellingShingle D. Baratoux
M. Fall
P.‐Y. Meslin
M. W. Jessell
O. Vanderhaeghe
J.‐F. Moyen
P. M. Ndiaye
K. Boamah
L. Baratoux
A.‐S. André‐Mayer
The Impact of Measurement Scale on the Univariate Statistics of K, Th, and U in the Earth Crust
Earth and Space Science
potassium
uranium
thorium
geostatistics
radiometrics
title The Impact of Measurement Scale on the Univariate Statistics of K, Th, and U in the Earth Crust
title_full The Impact of Measurement Scale on the Univariate Statistics of K, Th, and U in the Earth Crust
title_fullStr The Impact of Measurement Scale on the Univariate Statistics of K, Th, and U in the Earth Crust
title_full_unstemmed The Impact of Measurement Scale on the Univariate Statistics of K, Th, and U in the Earth Crust
title_short The Impact of Measurement Scale on the Univariate Statistics of K, Th, and U in the Earth Crust
title_sort impact of measurement scale on the univariate statistics of k th and u in the earth crust
topic potassium
uranium
thorium
geostatistics
radiometrics
url https://doi.org/10.1029/2021EA001786
work_keys_str_mv AT dbaratoux theimpactofmeasurementscaleontheunivariatestatisticsofkthanduintheearthcrust
AT mfall theimpactofmeasurementscaleontheunivariatestatisticsofkthanduintheearthcrust
AT pymeslin theimpactofmeasurementscaleontheunivariatestatisticsofkthanduintheearthcrust
AT mwjessell theimpactofmeasurementscaleontheunivariatestatisticsofkthanduintheearthcrust
AT ovanderhaeghe theimpactofmeasurementscaleontheunivariatestatisticsofkthanduintheearthcrust
AT jfmoyen theimpactofmeasurementscaleontheunivariatestatisticsofkthanduintheearthcrust
AT pmndiaye theimpactofmeasurementscaleontheunivariatestatisticsofkthanduintheearthcrust
AT kboamah theimpactofmeasurementscaleontheunivariatestatisticsofkthanduintheearthcrust
AT lbaratoux theimpactofmeasurementscaleontheunivariatestatisticsofkthanduintheearthcrust
AT asandremayer theimpactofmeasurementscaleontheunivariatestatisticsofkthanduintheearthcrust
AT dbaratoux impactofmeasurementscaleontheunivariatestatisticsofkthanduintheearthcrust
AT mfall impactofmeasurementscaleontheunivariatestatisticsofkthanduintheearthcrust
AT pymeslin impactofmeasurementscaleontheunivariatestatisticsofkthanduintheearthcrust
AT mwjessell impactofmeasurementscaleontheunivariatestatisticsofkthanduintheearthcrust
AT ovanderhaeghe impactofmeasurementscaleontheunivariatestatisticsofkthanduintheearthcrust
AT jfmoyen impactofmeasurementscaleontheunivariatestatisticsofkthanduintheearthcrust
AT pmndiaye impactofmeasurementscaleontheunivariatestatisticsofkthanduintheearthcrust
AT kboamah impactofmeasurementscaleontheunivariatestatisticsofkthanduintheearthcrust
AT lbaratoux impactofmeasurementscaleontheunivariatestatisticsofkthanduintheearthcrust
AT asandremayer impactofmeasurementscaleontheunivariatestatisticsofkthanduintheearthcrust