Light-soaking tests of zinc oxide photoanodes sensitized with an indoline dye on different transparent conductive substrates

Dye-sensitized solar cells (DSCs) were prepared using porous zinc oxide (ZnO) films on aluminum-doped zinc oxide (AZO) and fluorine-doped tin oxide (FTO) transparent conductive glass substrates. X-ray diffraction measurements revealed that, the porous ZnO films were crystallographically oriented dif...

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Main Authors: B. Onwona-Agyeman, A. Yaya, G. R. A. Kumara, M. Nakao
Format: Article
Language:English
Published: AIMS Press 2018-10-01
Series:AIMS Energy
Subjects:
Online Access:http://www.aimspress.com/energy/article/3167/fulltext.html
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author B. Onwona-Agyeman
A. Yaya
G. R. A. Kumara
M. Nakao
author_facet B. Onwona-Agyeman
A. Yaya
G. R. A. Kumara
M. Nakao
author_sort B. Onwona-Agyeman
collection DOAJ
description Dye-sensitized solar cells (DSCs) were prepared using porous zinc oxide (ZnO) films on aluminum-doped zinc oxide (AZO) and fluorine-doped tin oxide (FTO) transparent conductive glass substrates. X-ray diffraction measurements revealed that, the porous ZnO films were crystallographically oriented differently on the two transparent substrates. The two DSCs were prepared using metal-free indoline dye as the sensitizer and a liquid electrolyte as the hole conductor. Measurements of the power conversion efficiency of the two DSCs over a period of time showed deterioration in the conversion efficiency of the DSCs with the deterioration being faster in ZnO/FTO than ZnO/AZO. The deterioration is attributed mainly to the decrease in light-harvesting ability of the sensitizer and recombination of photo-excited electrons resulting in the decrease in the short-circuit photocurrent densities and the open-circuit voltages in both DSCs during the light-soaking process.
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spelling doaj.art-1d0bce4b26294728a0c5e3c13becbd9e2022-12-22T02:33:21ZengAIMS PressAIMS Energy2333-83342018-10-016694995810.3934/energy.2018.6.949energy-06-06-949Light-soaking tests of zinc oxide photoanodes sensitized with an indoline dye on different transparent conductive substratesB. Onwona-Agyeman0A. Yaya1G. R. A. Kumara2M. Nakao3Department of Materials Science and Engineering, School of Engineering Sciences, University of Ghana, Legon, GhanaDepartment of Materials Science and Engineering, School of Engineering Sciences, University of Ghana, Legon, GhanaInstitute of Fundamental Studies, Hantana Road, Kandy, Sri LankaDepartment of Basic Sciences, Kyushu Institute of Technology, Kitakyushu, JapanDye-sensitized solar cells (DSCs) were prepared using porous zinc oxide (ZnO) films on aluminum-doped zinc oxide (AZO) and fluorine-doped tin oxide (FTO) transparent conductive glass substrates. X-ray diffraction measurements revealed that, the porous ZnO films were crystallographically oriented differently on the two transparent substrates. The two DSCs were prepared using metal-free indoline dye as the sensitizer and a liquid electrolyte as the hole conductor. Measurements of the power conversion efficiency of the two DSCs over a period of time showed deterioration in the conversion efficiency of the DSCs with the deterioration being faster in ZnO/FTO than ZnO/AZO. The deterioration is attributed mainly to the decrease in light-harvesting ability of the sensitizer and recombination of photo-excited electrons resulting in the decrease in the short-circuit photocurrent densities and the open-circuit voltages in both DSCs during the light-soaking process.http://www.aimspress.com/energy/article/3167/fulltext.htmlcrystallographic orientation; photovoltaic; transparent conductor; thin film; spray deposition; semiconductor
spellingShingle B. Onwona-Agyeman
A. Yaya
G. R. A. Kumara
M. Nakao
Light-soaking tests of zinc oxide photoanodes sensitized with an indoline dye on different transparent conductive substrates
AIMS Energy
crystallographic orientation; photovoltaic; transparent conductor; thin film; spray deposition; semiconductor
title Light-soaking tests of zinc oxide photoanodes sensitized with an indoline dye on different transparent conductive substrates
title_full Light-soaking tests of zinc oxide photoanodes sensitized with an indoline dye on different transparent conductive substrates
title_fullStr Light-soaking tests of zinc oxide photoanodes sensitized with an indoline dye on different transparent conductive substrates
title_full_unstemmed Light-soaking tests of zinc oxide photoanodes sensitized with an indoline dye on different transparent conductive substrates
title_short Light-soaking tests of zinc oxide photoanodes sensitized with an indoline dye on different transparent conductive substrates
title_sort light soaking tests of zinc oxide photoanodes sensitized with an indoline dye on different transparent conductive substrates
topic crystallographic orientation; photovoltaic; transparent conductor; thin film; spray deposition; semiconductor
url http://www.aimspress.com/energy/article/3167/fulltext.html
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AT grakumara lightsoakingtestsofzincoxidephotoanodessensitizedwithanindolinedyeondifferenttransparentconductivesubstrates
AT mnakao lightsoakingtestsofzincoxidephotoanodessensitizedwithanindolinedyeondifferenttransparentconductivesubstrates