Heterogeneous WO3/H2O2 system for degradation of Indigo Carmin dye from aqueous solution

In this work, tungsten oxide crystals (WO3), with different sizes and morphologies were prepared using the reflux condensation method. Tungsten oxide crystals were characterized by X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy and X-ray photoelectron spectr...

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Main Authors: Sévérin N'goran Eroi, Aimé Serge Ello, Donourou Diabaté, Diby Benjamin Ossonon
Format: Article
Language:English
Published: Elsevier 2021-07-01
Series:South African Journal of Chemical Engineering
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1026918521000160
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author Sévérin N'goran Eroi
Aimé Serge Ello
Donourou Diabaté
Diby Benjamin Ossonon
author_facet Sévérin N'goran Eroi
Aimé Serge Ello
Donourou Diabaté
Diby Benjamin Ossonon
author_sort Sévérin N'goran Eroi
collection DOAJ
description In this work, tungsten oxide crystals (WO3), with different sizes and morphologies were prepared using the reflux condensation method. Tungsten oxide crystals were characterized by X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. Then, the particles were used as a heterogeneous Fenton-like catalyst in the presence of green oxidant H2O2 for Indigo Carmin (IC) dye degradation. The efficiency of the coupling WO3/H2O2 showed at 600 °C, that it was possible to remove about 90% of the initial color of IC after 120 min in a batch reaction at 65 °C. Moreover, the coupling maintained high activity after four continuous cycles when tungsten oxide particles were recorvered.
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spelling doaj.art-1d128b66798a4c828dad69908f2b318f2022-12-21T18:42:34ZengElsevierSouth African Journal of Chemical Engineering1026-91852021-07-01375360Heterogeneous WO3/H2O2 system for degradation of Indigo Carmin dye from aqueous solutionSévérin N'goran Eroi0Aimé Serge Ello1Donourou Diabaté2Diby Benjamin Ossonon3Laboratoire de Constitution et Réaction de la Matière, 22bp 582 Abidjan 22, Université Felix Houphouët-Boigny (Côte d'ivoire)Laboratoire de Constitution et Réaction de la Matière, 22bp 582 Abidjan 22, Université Felix Houphouët-Boigny (Côte d'ivoire); Corresponding author.Laboratoire de Constitution et Réaction de la Matière, 22bp 582 Abidjan 22, Université Felix Houphouët-Boigny (Côte d'ivoire)Institut National de Recherche Scientifique-Énergie, Matériaux et Télécommunications (INRS-EMT) 1650, boulevard Lionel-Boulet Varennes (Québec) J3 × 1S2 CanadaIn this work, tungsten oxide crystals (WO3), with different sizes and morphologies were prepared using the reflux condensation method. Tungsten oxide crystals were characterized by X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. Then, the particles were used as a heterogeneous Fenton-like catalyst in the presence of green oxidant H2O2 for Indigo Carmin (IC) dye degradation. The efficiency of the coupling WO3/H2O2 showed at 600 °C, that it was possible to remove about 90% of the initial color of IC after 120 min in a batch reaction at 65 °C. Moreover, the coupling maintained high activity after four continuous cycles when tungsten oxide particles were recorvered.http://www.sciencedirect.com/science/article/pii/S1026918521000160Tungsten oxideIndigo carminHydrogen peroxideDye
spellingShingle Sévérin N'goran Eroi
Aimé Serge Ello
Donourou Diabaté
Diby Benjamin Ossonon
Heterogeneous WO3/H2O2 system for degradation of Indigo Carmin dye from aqueous solution
South African Journal of Chemical Engineering
Tungsten oxide
Indigo carmin
Hydrogen peroxide
Dye
title Heterogeneous WO3/H2O2 system for degradation of Indigo Carmin dye from aqueous solution
title_full Heterogeneous WO3/H2O2 system for degradation of Indigo Carmin dye from aqueous solution
title_fullStr Heterogeneous WO3/H2O2 system for degradation of Indigo Carmin dye from aqueous solution
title_full_unstemmed Heterogeneous WO3/H2O2 system for degradation of Indigo Carmin dye from aqueous solution
title_short Heterogeneous WO3/H2O2 system for degradation of Indigo Carmin dye from aqueous solution
title_sort heterogeneous wo3 h2o2 system for degradation of indigo carmin dye from aqueous solution
topic Tungsten oxide
Indigo carmin
Hydrogen peroxide
Dye
url http://www.sciencedirect.com/science/article/pii/S1026918521000160
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