Application of silica–alumina oxides of different compositions for removal of C.I. Reactive Black 5 dye from wastewaters

In this paper adsorptive removal of hazardous dye C.I. Reactive Black 5 from aqueous solutions was investigated using the mixed silica–alumina oxides including of 4% SiO 2 and 96% Al 2 O 3 as well as 97% SiO 2 and 3% Al 2 O 3 . The kinetic studies revealed that with the increasing initial dye concen...

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Main Authors: Monika Wawrzkiewicz, Małgorzata Wiśniewska, Vladimir M Gun'ko
Format: Article
Language:English
Published: SAGE Publications 2017-06-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1177/0263617417695271
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author Monika Wawrzkiewicz
Małgorzata Wiśniewska
Vladimir M Gun'ko
author_facet Monika Wawrzkiewicz
Małgorzata Wiśniewska
Vladimir M Gun'ko
author_sort Monika Wawrzkiewicz
collection DOAJ
description In this paper adsorptive removal of hazardous dye C.I. Reactive Black 5 from aqueous solutions was investigated using the mixed silica–alumina oxides including of 4% SiO 2 and 96% Al 2 O 3 as well as 97% SiO 2 and 3% Al 2 O 3 . The kinetic studies revealed that with the increasing initial dye concentration from 10 to 30 mg/l and contact time from 1 to 240 min, the sorption capacities ( q t ) increased and the equilibrium was observed after 240 min. Sorption of C.I. Reactive Black 5 on 4% SiO 2 and 96% Al 2 O 3 and 97% SiO 2 and 3% Al 2 O 3 takes place through the pseudo-second-order mechanism rather than the pseudo-first-order one. The experimental data were fitted using the Langmuir and Freundlich isotherm models. The effect of the auxiliaries such as anionic surfactant (sodium dodecyl sulphate) and sodium chloride on C.I. Reactive Black 5 removal was investigated in the 10 mg/l C.I. Reactive Black 5–0.1–1 g/l sodium dodecyl sulphate or 5–20 g/l NaCl systems. The potentiometric titrations indicated that the presence of C.I. Reactive Black 5 changed the surface charge density of silica–alumina mixed oxides, especially in the case of 4% SiO 2 and 96% Al 2 O 3 system.
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spelling doaj.art-1d29ae0574d14b4fa9079141eec065ff2024-03-02T01:48:51ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40382017-06-013510.1177/0263617417695271Application of silica–alumina oxides of different compositions for removal of C.I. Reactive Black 5 dye from wastewatersMonika WawrzkiewiczMałgorzata WiśniewskaVladimir M Gun'koIn this paper adsorptive removal of hazardous dye C.I. Reactive Black 5 from aqueous solutions was investigated using the mixed silica–alumina oxides including of 4% SiO 2 and 96% Al 2 O 3 as well as 97% SiO 2 and 3% Al 2 O 3 . The kinetic studies revealed that with the increasing initial dye concentration from 10 to 30 mg/l and contact time from 1 to 240 min, the sorption capacities ( q t ) increased and the equilibrium was observed after 240 min. Sorption of C.I. Reactive Black 5 on 4% SiO 2 and 96% Al 2 O 3 and 97% SiO 2 and 3% Al 2 O 3 takes place through the pseudo-second-order mechanism rather than the pseudo-first-order one. The experimental data were fitted using the Langmuir and Freundlich isotherm models. The effect of the auxiliaries such as anionic surfactant (sodium dodecyl sulphate) and sodium chloride on C.I. Reactive Black 5 removal was investigated in the 10 mg/l C.I. Reactive Black 5–0.1–1 g/l sodium dodecyl sulphate or 5–20 g/l NaCl systems. The potentiometric titrations indicated that the presence of C.I. Reactive Black 5 changed the surface charge density of silica–alumina mixed oxides, especially in the case of 4% SiO 2 and 96% Al 2 O 3 system.https://doi.org/10.1177/0263617417695271
spellingShingle Monika Wawrzkiewicz
Małgorzata Wiśniewska
Vladimir M Gun'ko
Application of silica–alumina oxides of different compositions for removal of C.I. Reactive Black 5 dye from wastewaters
Adsorption Science & Technology
title Application of silica–alumina oxides of different compositions for removal of C.I. Reactive Black 5 dye from wastewaters
title_full Application of silica–alumina oxides of different compositions for removal of C.I. Reactive Black 5 dye from wastewaters
title_fullStr Application of silica–alumina oxides of different compositions for removal of C.I. Reactive Black 5 dye from wastewaters
title_full_unstemmed Application of silica–alumina oxides of different compositions for removal of C.I. Reactive Black 5 dye from wastewaters
title_short Application of silica–alumina oxides of different compositions for removal of C.I. Reactive Black 5 dye from wastewaters
title_sort application of silica alumina oxides of different compositions for removal of c i reactive black 5 dye from wastewaters
url https://doi.org/10.1177/0263617417695271
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AT małgorzatawisniewska applicationofsilicaaluminaoxidesofdifferentcompositionsforremovalofcireactiveblack5dyefromwastewaters
AT vladimirmgunko applicationofsilicaaluminaoxidesofdifferentcompositionsforremovalofcireactiveblack5dyefromwastewaters