Flame-Retardant and Washable Finishing of Lyocell/Cotton Blended Fabrics Using Eco-Friendly Creatinine O-Phosphate

Creatinine O-phosphate (COP) containing phosphorus and nitrogen elements was used as eco-friendly flame-retardant for lyocell/cotton blended fabric (L/C fabric). The flame retardant fabrics are prepared by a simple and effective dip-dry-cure method. Fourier infrared spectroscopy (FTIR), scanning ele...

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Main Authors: Xuan Yang, Yunbo Zheng, Xiaohui Liu, Yuanlin Ren, Xianwen Yang, Qiuyan Zhang
Format: Article
Language:English
Published: Taylor & Francis Group 2023-04-01
Series:Journal of Natural Fibers
Subjects:
Online Access:http://dx.doi.org/10.1080/15440478.2022.2145405
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author Xuan Yang
Yunbo Zheng
Xiaohui Liu
Yuanlin Ren
Xianwen Yang
Qiuyan Zhang
author_facet Xuan Yang
Yunbo Zheng
Xiaohui Liu
Yuanlin Ren
Xianwen Yang
Qiuyan Zhang
author_sort Xuan Yang
collection DOAJ
description Creatinine O-phosphate (COP) containing phosphorus and nitrogen elements was used as eco-friendly flame-retardant for lyocell/cotton blended fabric (L/C fabric). The flame retardant fabrics are prepared by a simple and effective dip-dry-cure method. Fourier infrared spectroscopy (FTIR), scanning electron microscope (SEM), and X-ray photoelectron spectroscopy (XPS) analyses certified that COP has been successfully grafted onto the surface of the L/C fabric and distributed evenly. Compared with the control fabric, the thermogravimetric analysis (TG) results showed that the char residue rate of the flame-retardant fabric at 800°C increased by 229% (air atmosphere), indicating that it has excellent char-forming ability. Besides, cone calorimetry results showed that the PHRR and THR values of the treated L/C fabric were reduced by 88.83% and 76.65%, respectively. The volatile pyrolysis products of the treated L/C fabric were determined by thermogravimetric analysis coupled with Fourier transform infrared analysis (TG-IR). In general, these results indicated that the L/C fabric treated with COP had high flame retardancy, excellent washing resistance and thermal stability.
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spelling doaj.art-1d44e4d57a764e959335697bb8efdfd42023-09-25T10:28:57ZengTaylor & Francis GroupJournal of Natural Fibers1544-04781544-046X2023-04-0120110.1080/15440478.2022.21454052145405Flame-Retardant and Washable Finishing of Lyocell/Cotton Blended Fabrics Using Eco-Friendly Creatinine O-PhosphateXuan Yang0Yunbo Zheng1Xiaohui Liu2Yuanlin Ren3Xianwen Yang4Qiuyan Zhang5Tiangong UniversityQuanzhou College of TechnologyTiangong UniversityTiangong UniversityTiangong UniversityTiangong UniversityCreatinine O-phosphate (COP) containing phosphorus and nitrogen elements was used as eco-friendly flame-retardant for lyocell/cotton blended fabric (L/C fabric). The flame retardant fabrics are prepared by a simple and effective dip-dry-cure method. Fourier infrared spectroscopy (FTIR), scanning electron microscope (SEM), and X-ray photoelectron spectroscopy (XPS) analyses certified that COP has been successfully grafted onto the surface of the L/C fabric and distributed evenly. Compared with the control fabric, the thermogravimetric analysis (TG) results showed that the char residue rate of the flame-retardant fabric at 800°C increased by 229% (air atmosphere), indicating that it has excellent char-forming ability. Besides, cone calorimetry results showed that the PHRR and THR values of the treated L/C fabric were reduced by 88.83% and 76.65%, respectively. The volatile pyrolysis products of the treated L/C fabric were determined by thermogravimetric analysis coupled with Fourier transform infrared analysis (TG-IR). In general, these results indicated that the L/C fabric treated with COP had high flame retardancy, excellent washing resistance and thermal stability.http://dx.doi.org/10.1080/15440478.2022.2145405lyocell/cotton blended fabricflame retardanteco-friendly materialcreatinine o-phosphatethermal decompositioncombustion behavior
spellingShingle Xuan Yang
Yunbo Zheng
Xiaohui Liu
Yuanlin Ren
Xianwen Yang
Qiuyan Zhang
Flame-Retardant and Washable Finishing of Lyocell/Cotton Blended Fabrics Using Eco-Friendly Creatinine O-Phosphate
Journal of Natural Fibers
lyocell/cotton blended fabric
flame retardant
eco-friendly material
creatinine o-phosphate
thermal decomposition
combustion behavior
title Flame-Retardant and Washable Finishing of Lyocell/Cotton Blended Fabrics Using Eco-Friendly Creatinine O-Phosphate
title_full Flame-Retardant and Washable Finishing of Lyocell/Cotton Blended Fabrics Using Eco-Friendly Creatinine O-Phosphate
title_fullStr Flame-Retardant and Washable Finishing of Lyocell/Cotton Blended Fabrics Using Eco-Friendly Creatinine O-Phosphate
title_full_unstemmed Flame-Retardant and Washable Finishing of Lyocell/Cotton Blended Fabrics Using Eco-Friendly Creatinine O-Phosphate
title_short Flame-Retardant and Washable Finishing of Lyocell/Cotton Blended Fabrics Using Eco-Friendly Creatinine O-Phosphate
title_sort flame retardant and washable finishing of lyocell cotton blended fabrics using eco friendly creatinine o phosphate
topic lyocell/cotton blended fabric
flame retardant
eco-friendly material
creatinine o-phosphate
thermal decomposition
combustion behavior
url http://dx.doi.org/10.1080/15440478.2022.2145405
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