K-Ar geochronology for hydrothermal K-feldspar within plagioclase in a granitic pluton: constraints on timing and thermal condition for hydrothermal alteration

This study presents the K-Ar geochronology for hydrothermal K-feldspar in plagioclase alteration, including methodology and application to the Toki granite, in central Japan. Borehole samples from the Toki granite were collected and mechanically and chemically processed to separate plagioclase from...

Full description

Bibliographic Details
Main Authors: Takashi Yuguchi, Koshi Yagi, Eiji Sasao, Tadao Nishiyama
Format: Article
Language:English
Published: Elsevier 2021-04-01
Series:Heliyon
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2405844021008537
_version_ 1819140452155129856
author Takashi Yuguchi
Koshi Yagi
Eiji Sasao
Tadao Nishiyama
author_facet Takashi Yuguchi
Koshi Yagi
Eiji Sasao
Tadao Nishiyama
author_sort Takashi Yuguchi
collection DOAJ
description This study presents the K-Ar geochronology for hydrothermal K-feldspar in plagioclase alteration, including methodology and application to the Toki granite, in central Japan. Borehole samples from the Toki granite were collected and mechanically and chemically processed to separate plagioclase from the rock and remove bulk impurities. The sample fraction of cleaned plagioclase powder was further processed to a smaller size fraction, allowing separation of the altered K-feldspar from the plagioclase host. The resulting K-feldspar represented the hydrothermal alteration product and was characterized crystallographically as microcline, and its K-Ar ages were measured. The results of the K-Ar dating and petrographic characterization indicated that in this setting, plagioclase alteration occurred through a combination of solid-state replacement and dissolution–precipitation processes. The K-feldspathization age enables constraint of the temporal conditions of the solid-state replacement process to 62.2 ± 1.4 Ma. The time-temperature (t-T) path of the sampling site is an effective tool for determining both the timing and thermal conditions of the hydrothermal microcline formation in plagioclase alteration. The combination of the t-T path and the microcline K-Ar age provides formation temperatures of about 307–325 °C. The timing and thermal conditions of solid-state replacement (62.2 ± 1.4 Ma and 325–307 °C) indicate an older age and a higher temperature than those of dissolution–precipitation (59.2 ± 1.4 Ma and 305–290 °C: Yuguchi et al., 2019A). The plagioclase alteration consists of serial processes from solid-state replacement to dissolution–precipitation. Addition of the thermal conditions and timing into petrography have implications for the sequential phenomenal variation in granite.
first_indexed 2024-12-22T11:38:47Z
format Article
id doaj.art-1d52db8a61ac4087ae39fcb789d47760
institution Directory Open Access Journal
issn 2405-8440
language English
last_indexed 2024-12-22T11:38:47Z
publishDate 2021-04-01
publisher Elsevier
record_format Article
series Heliyon
spelling doaj.art-1d52db8a61ac4087ae39fcb789d477602022-12-21T18:27:20ZengElsevierHeliyon2405-84402021-04-0174e06750K-Ar geochronology for hydrothermal K-feldspar within plagioclase in a granitic pluton: constraints on timing and thermal condition for hydrothermal alterationTakashi Yuguchi0Koshi Yagi1Eiji Sasao2Tadao Nishiyama3Faculty of Science, Yamagata University, 1-4-12 Kojirakawa, Yamagata, 990-8560, Japan; Corresponding author.Hiruzen Institute for Geology and Chronology Co., Ltd., 2-5, Nakashima, Naka-ku, Okayama, 703-8252, JapanJapan Atomic Energy Agency, 1-64, Yamanouchi, Akiyo, Mizunami, Gifu, 509-6132, JapanGraduate School of Science and Technology, Kumamoto University, 2-39-1, Kurokami, Chuo-ku, Kumamoto, 860-8555, JapanThis study presents the K-Ar geochronology for hydrothermal K-feldspar in plagioclase alteration, including methodology and application to the Toki granite, in central Japan. Borehole samples from the Toki granite were collected and mechanically and chemically processed to separate plagioclase from the rock and remove bulk impurities. The sample fraction of cleaned plagioclase powder was further processed to a smaller size fraction, allowing separation of the altered K-feldspar from the plagioclase host. The resulting K-feldspar represented the hydrothermal alteration product and was characterized crystallographically as microcline, and its K-Ar ages were measured. The results of the K-Ar dating and petrographic characterization indicated that in this setting, plagioclase alteration occurred through a combination of solid-state replacement and dissolution–precipitation processes. The K-feldspathization age enables constraint of the temporal conditions of the solid-state replacement process to 62.2 ± 1.4 Ma. The time-temperature (t-T) path of the sampling site is an effective tool for determining both the timing and thermal conditions of the hydrothermal microcline formation in plagioclase alteration. The combination of the t-T path and the microcline K-Ar age provides formation temperatures of about 307–325 °C. The timing and thermal conditions of solid-state replacement (62.2 ± 1.4 Ma and 325–307 °C) indicate an older age and a higher temperature than those of dissolution–precipitation (59.2 ± 1.4 Ma and 305–290 °C: Yuguchi et al., 2019A). The plagioclase alteration consists of serial processes from solid-state replacement to dissolution–precipitation. Addition of the thermal conditions and timing into petrography have implications for the sequential phenomenal variation in granite.http://www.sciencedirect.com/science/article/pii/S2405844021008537K-feldspar K-Ar agePlagioclase alterationSolid-state replacementDissolution and precipitationK-feldspathization and illitizationToki granitic pluton
spellingShingle Takashi Yuguchi
Koshi Yagi
Eiji Sasao
Tadao Nishiyama
K-Ar geochronology for hydrothermal K-feldspar within plagioclase in a granitic pluton: constraints on timing and thermal condition for hydrothermal alteration
Heliyon
K-feldspar K-Ar age
Plagioclase alteration
Solid-state replacement
Dissolution and precipitation
K-feldspathization and illitization
Toki granitic pluton
title K-Ar geochronology for hydrothermal K-feldspar within plagioclase in a granitic pluton: constraints on timing and thermal condition for hydrothermal alteration
title_full K-Ar geochronology for hydrothermal K-feldspar within plagioclase in a granitic pluton: constraints on timing and thermal condition for hydrothermal alteration
title_fullStr K-Ar geochronology for hydrothermal K-feldspar within plagioclase in a granitic pluton: constraints on timing and thermal condition for hydrothermal alteration
title_full_unstemmed K-Ar geochronology for hydrothermal K-feldspar within plagioclase in a granitic pluton: constraints on timing and thermal condition for hydrothermal alteration
title_short K-Ar geochronology for hydrothermal K-feldspar within plagioclase in a granitic pluton: constraints on timing and thermal condition for hydrothermal alteration
title_sort k ar geochronology for hydrothermal k feldspar within plagioclase in a granitic pluton constraints on timing and thermal condition for hydrothermal alteration
topic K-feldspar K-Ar age
Plagioclase alteration
Solid-state replacement
Dissolution and precipitation
K-feldspathization and illitization
Toki granitic pluton
url http://www.sciencedirect.com/science/article/pii/S2405844021008537
work_keys_str_mv AT takashiyuguchi kargeochronologyforhydrothermalkfeldsparwithinplagioclaseinagraniticplutonconstraintsontimingandthermalconditionforhydrothermalalteration
AT koshiyagi kargeochronologyforhydrothermalkfeldsparwithinplagioclaseinagraniticplutonconstraintsontimingandthermalconditionforhydrothermalalteration
AT eijisasao kargeochronologyforhydrothermalkfeldsparwithinplagioclaseinagraniticplutonconstraintsontimingandthermalconditionforhydrothermalalteration
AT tadaonishiyama kargeochronologyforhydrothermalkfeldsparwithinplagioclaseinagraniticplutonconstraintsontimingandthermalconditionforhydrothermalalteration